Phenol, 2,4-dinitro-

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Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Quantity Value Units Method Reference Comment
Δfsolid-235.5kJ/molCcbFinch and Smith, 1983 
Δfsolid-223.0kJ/molCcbRinkenbach, 1930Author hf298_condensed[kcal/mol]=-55.57
Quantity Value Units Method Reference Comment
Δcsolid-2697.2 ± 3.2kJ/molCcbFinch and Smith, 1983 
Δcsolid-2696.9 ± 2.7kJ/molCcbBadoche, 1942Reanalyzed by Cox and Pilcher, 1970, Original value = -2699.8 kJ/mol
Δcsolid-2703.1 ± 2.7kJ/molCcbBurlot, 1939Reanalyzed by Cox and Pilcher, 1970, Original value = -2714.6 kJ/mol
Δcsolid-2709.68kJ/molCcbRinkenbach, 1930Author hf298_condensed[kcal/mol]=-55.57
Δcsolid-2720.kJ/molCcbGarner and Abernethy, 1921 

Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

C6H3N2O5- + Hydrogen cation = Phenol, 2,4-dinitro-

By formula: C6H3N2O5- + H+ = C6H4N2O5

Quantity Value Units Method Reference Comment
Δr1322. ± 8.8kJ/molG+TSKoppel, Taft, et al., 1994gas phase
Quantity Value Units Method Reference Comment
Δr1291. ± 8.4kJ/molIMREKoppel, Taft, et al., 1994gas phase

References

Go To: Top, Condensed phase thermochemistry data, Reaction thermochemistry data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Finch and Smith, 1983
Finch, A.; Smith, A.E., Thermochemistry of nitrophenols. V. Enthalpies of formation of 2,4- and 2,6-dinitrophenols, Thermochim. Acta, 1983, 69, 375-378. [all data]

Rinkenbach, 1930
Rinkenbach, W.H., The heats of combustion and formation of aromatic nitro compounds, J. Am. Chem. Soc., 1930, 52, 115-120. [all data]

Badoche, 1942
Badoche, M., Chaleurs de combustion de derives nitres phenoliques, Bull. Soc. Chim. France, 1942, 9, 86-95. [all data]

Cox and Pilcher, 1970
Cox, J.D.; Pilcher, G., Thermochemistry of Organic and Organometallic Compounds, Academic Press, New York, 1970, 1-636. [all data]

Burlot, 1939
Burlot, E., Etude relative a la calorimetrie des explosifs, Mem. Poudres, 1939, 29, 226-260. [all data]

Garner and Abernethy, 1921
Garner, W.E.; Abernethy, C.L., Heats of combustion and formation of nitro-compounds. Part I. - Benzene, toluene, phenol and methylaniline series, Proc. Roy. Soc. London A, 1921, 213-235. [all data]

Koppel, Taft, et al., 1994
Koppel, I.A.; Taft, R.W.; Anvia, F.; Zhu, S.Z.; Hu, L.Q.; Sung, K.S.; Desmarteau, D.D.; Yagupolskii, L.M., The Gas-Phase Acidities of Very Strong Neutral Bronsted Acids, J. Am. Chem. Soc., 1994, 116, 7, 3047, https://doi.org/10.1021/ja00086a038 . [all data]


Notes

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