Methanediylium anion
- Formula: CH2-
- Molecular weight: 14.0271
- CAS Registry Number: 50928-07-9
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Reaction thermochemistry data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: John E. Bartmess
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Individual Reactions
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 409.11 ± 0.41 | kcal/mol | D-EA | Leopold, Murray, et al., 1985 | gas phase; Singlet-triplet splitting of CH2 = 9.0 kcal |
Quantity | Value | Units | Method | Reference | Comment |
ΔrG° | 401.42 ± 0.48 | kcal/mol | H-TS | Leopold, Murray, et al., 1985 | gas phase; Singlet-triplet splitting of CH2 = 9.0 kcal |
Gas phase ion energetics data
Go To: Top, Reaction thermochemistry data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: John E. Bartmess
Protonation reactions
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 409.11 ± 0.41 | kcal/mol | D-EA | Leopold, Murray, et al., 1985 | gas phase; Singlet-triplet splitting of CH2 = 9.0 kcal |
Quantity | Value | Units | Method | Reference | Comment |
ΔrG° | 401.42 ± 0.48 | kcal/mol | H-TS | Leopold, Murray, et al., 1985 | gas phase; Singlet-triplet splitting of CH2 = 9.0 kcal |
References
Go To: Top, Reaction thermochemistry data, Gas phase ion energetics data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Leopold, Murray, et al., 1985
Leopold, D.G.; Murray, K.K.; Miller, A.E.S.; Lineberger, W.C.,
Methylene: A study of the X3B1 and the 1A1 states by photoelectron spectroscopy of CH2- and CD2-,
J. Chem. Phys., 1985, 83, 4849. [all data]
Notes
Go To: Top, Reaction thermochemistry data, Gas phase ion energetics data, References
- Symbols used in this document:
ΔrG° Free energy of reaction at standard conditions ΔrH° Enthalpy of reaction at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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