Tricyclo[2.2.1.0(2,6)]heptane, 1,7,7-trimethyl-
- Formula: C10H16
- Molecular weight: 136.2340
- IUPAC Standard InChI: InChI=1S/C10H16/c1-9(2)6-4-7-8(5-6)10(7,9)3/h6-8H,4-5H2,1-3H3
- IUPAC Standard InChIKey: RRBYUSWBLVXTQN-UHFFFAOYSA-N
- CAS Registry Number: 508-32-7
- Chemical structure:
This structure is also available as a 2d Mol file or as a computed 3d SD file
The 3d structure may be viewed using Java or Javascript. - Species with the same structure:
- Other names: Tricyclene; 1,7,7-Trimethyltricyclo[2.2.1.0,2,6]heptane; Cyclene; NSC 86978; 1,7,7-Trimethyl-tricyclo[2.2.1.0*2,6*]heptane; α-Tricyclene; Tricyclo[2.2.1.02,6]heptane, 1,7,7-trimethyl-; 1,7,7-Trimethyltricyclo[2.2.1(2.6)]heptane; 1,7,7-trimethyltricyclo[2.2.1.02,6]heptane
- Information on this page:
- Other data available:
- Data at other public NIST sites:
- Options:
Kovats' RI, non-polar column, temperature ramp
Go To: Top, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director
| Column type | Capillary | Capillary | Capillary | Capillary | Capillary |
|---|---|---|---|---|---|
| Active phase | DB-5 | DB-5 | DB-5 | DB-5 | DB-5 |
| Column length (m) | 30. | 30. | 30. | 30. | 30. |
| Carrier gas | He | He | He | He | Helium |
| Substrate | |||||
| Column diameter (mm) | 0.26 | 0.25 | 0.26 | 0.26 | 0.25 |
| Phase thickness (μm) | 0.25 | 0.25 | 0.25 | 0.25 | 0.25 |
| Tstart (C) | 60. | 60. | 60. | 60. | 60. |
| Tend (C) | 246. | 246. | 246. | 255. | |
| Heat rate (K/min) | 3. | 3. | 3. | 3. | 3. |
| Initial hold (min) | |||||
| Final hold (min) | |||||
| I | 926. | 928. | 927. | 926. | 928. |
| Reference | Adams, González Elizondo, et al., 2006 | Lucero, Fredrickson, et al., 2006 | Adams, Morris, et al., 2005 | Adams and Nguyen, 2005 | Medina, Lucero, et al., 2005 |
| Comment | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI |
| Column type | Capillary | Capillary | Capillary | Capillary | Capillary |
|---|---|---|---|---|---|
| Active phase | BPX-5 | HP-5MS | DB-5 | CP Sil 5 CB | HP-5 |
| Column length (m) | 25. | 30. | 30. | 25. | 30. |
| Carrier gas | He | He | He | H2 | He |
| Substrate | |||||
| Column diameter (mm) | 0.22 | 0.25 | 0.25 | 0.25 | 0.25 |
| Phase thickness (μm) | 0.25 | 0.25 | 0.25 | 0.15 | 0.25 |
| Tstart (C) | 60. | 50. | 60. | 50. | 60. |
| Tend (C) | 240. | 280. | 230. | 280. | |
| Heat rate (K/min) | 3. | 4. | 3. | 3. | 3. |
| Initial hold (min) | 2. | ||||
| Final hold (min) | 10. | ||||
| I | 927. | 926. | 927. | 928. | 914. |
| Reference | El-Ghorab, Mansour, et al., 2004 | Baranauskiene, Venskutonis, et al., 2003 | Lucero, Estell, et al., 2003 | Ogunwande, Olawore, et al., 2003 | Özcan, Tzakou, et al., 2003 |
| Comment | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI |
| Column type | Capillary | Capillary | Capillary | Capillary | Capillary |
|---|---|---|---|---|---|
| Active phase | DB-5 | DB-5 | DB-5 | HP-5 | SE-30 |
| Column length (m) | 60. | 25. | 30. | 30. | 25. |
| Carrier gas | He | He | He | He | |
| Substrate | |||||
| Column diameter (mm) | 0.32 | 0.22 | 0.25 | 0.25 | 0.22 |
| Phase thickness (μm) | 1. | 0.25 | 0.5 | 0.25 | 0.25 |
| Tstart (C) | 40. | 60. | 50. | 60. | 70. |
| Tend (C) | 230. | 240. | 250. | 240. | 220. |
| Heat rate (K/min) | 3. | 3. | 7. | 3. | 4. |
| Initial hold (min) | 5. | 3. | |||
| Final hold (min) | 2. | 10. | 20. | ||
| I | 931. | 940. | 930.3 | 926. | 915. |
| Reference | Buchin, Salmon, et al., 2002 | El-Ghorab, Fadel, et al., 2002 | El-Massry, El-Ghorab, et al., 2002 | Mita, Tsitsimpikou, et al., 2002 | Palá-Paúl, Velasco-Negueruela, et al., 2002 |
| Comment | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI |
| Column type | Capillary | Capillary | Capillary | Capillary | Capillary |
|---|---|---|---|---|---|
| Active phase | BP-1 | BP-1 | HP-5MS | HP-5 | PTE-5 |
| Column length (m) | 60. | 25. | 30. | 50. | 60. |
| Carrier gas | N2 | N2 | He | He | H2 |
| Substrate | |||||
| Column diameter (mm) | 0.32 | 0.32 | 0.25 | 0.25 | 0.32 |
| Phase thickness (μm) | 0.25 | 0.25 | 0.25 | 0.25 | 0.39 |
| Tstart (C) | 60. | 60. | 50. | 50. | 60. |
| Tend (C) | 220. | 220. | 250. | 250. | 285. |
| Heat rate (K/min) | 5. | 5. | 3. | 2.5 | 4.3 |
| Initial hold (min) | 5. | ||||
| Final hold (min) | 15. | ||||
| I | 920. | 922. | 924. | 924. | 928. |
| Reference | Raina, Lal, et al., 2002 | Raina, Srivastava, et al., 2002 | Salido, Altarejos, et al., 2002 | Yáñez, Pinzón, et al., 2002 | Gudzic, Dordevic, et al., 2001 |
| Comment | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI |
| Column type | Capillary | Capillary | Capillary | Capillary | Capillary |
|---|---|---|---|---|---|
| Active phase | SE-54 | DB-5 | SE-54 | DB-5 | DB-5 |
| Column length (m) | 30. | 30. | 30. | 30. | 30. |
| Carrier gas | He | He | He | He | |
| Substrate | |||||
| Column diameter (mm) | 0.26 | 0.26 | 0.26 | 0.26 | 0.26 |
| Phase thickness (μm) | 0.25 | 0.25 | 0.25 | 0.25 | 0.25 |
| Tstart (C) | 60. | 60. | 60. | 60. | 60. |
| Tend (C) | 246. | 240. | 246. | 246. | 246. |
| Heat rate (K/min) | 3. | 3. | 3. | 3. | 3. |
| Initial hold (min) | |||||
| Final hold (min) | |||||
| I | 926. | 926. | 926. | 926. | 926. |
| Reference | Adams, 2000 | Adams, 2000, 2 | Adams, 2000, 3 | Adams, 2000, 4 | Adams, 1999 |
| Comment | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI |
| Column type | Capillary | Capillary | Capillary | Capillary | Capillary |
|---|---|---|---|---|---|
| Active phase | SE-30 | CP Sil 5 CB | Methyl Silicone | DB-5 | DB-1 |
| Column length (m) | 25. | 25. | 25. | 30. | 60. |
| Carrier gas | He | N2 | He | He | |
| Substrate | |||||
| Column diameter (mm) | 0.2 | 0.25 | 0.5 | 0.25 | 0.25 |
| Phase thickness (μm) | 0.25 | 1. | |||
| Tstart (C) | 60. | 60. | 60. | 60. | 40. |
| Tend (C) | 180. | 280. | 220. | 240. | 250. |
| Heat rate (K/min) | 3. | 5. | 5. | 3. | 4. |
| Initial hold (min) | 10. | ||||
| Final hold (min) | |||||
| I | 923. | 915. | 920. | 926. | 942. |
| Reference | Jantan I. and Ahmad A.S., 1999 | Kaul and Vats, 1998 | Mallavarapu, Rao, et al., 1998 | Tellez, Estell, et al., 1997 | Burns and Tingey, 1983 |
| Comment | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI |
References
Go To: Top, Kovats' RI, non-polar column, temperature ramp, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Adams, González Elizondo, et al., 2006
Adams, R.P.; González Elizondo, M.S.; González Elizondo, M.; Slinkman, E.,
DNA fingerprinting and terpenoid analysis of Juniperus blancoi var. huehuentensis (Cupressaceae), a new subalpine variety from Durango, Mexico,
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Lucero, Fredrickson, et al., 2006
Lucero, M.E.; Fredrickson, E.L.; Estell, R.E.; Morrison, A.A.; Richman, D.B.,
Volatile Composition of Gutierrezia sarothrae (Broom Snakeweed) as Determined by Steam Distillation and Solid Phase Microextraction,
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Adams, Morris, et al., 2005
Adams, R.P.; Morris, J.A.; Pandey, R.N.; Schwarzbach, A.E.,
Cryptic speciation between Juniperus deltoides and Juniperus oxycedrus (Cupressaceae) in the Mediterranean,
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Adams and Nguyen, 2005
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Infra-specific variation in Juniperus deppeana and F. Sperryi in the Davis Mountains of Texas: variation in leaf essential oils and random amplified polymorphic DNAS (RAPDS),
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Medina, Lucero, et al., 2005
Medina, A.L.; Lucero, M.E.; Holguin, F.O.; Estell, R.E.; Posakony, J.J.; Simon, J.; O'Connell, M.A.,
Composition and antimicrobial activity of Anemopsis californica leaf oil,
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El-Ghorab, Mansour, et al., 2004
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Effect of extraction methods on the chemical composition and antioxidant activity of Egyptian marjoram (Majorana hortensis Moench),
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Influence of nitrogen fertilizers on the yield and composition of thyme (Thymus vulgaris),
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Lucero, Estell, et al., 2003
Lucero, M.E.; Estell, R.E.; Frederickson, E.L.,
The essential oil composition of Psorothamnus scoparius (A. Gray) Rydb.,
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Ogunwande, Olawore, et al., 2003
Ogunwande, I.A.; Olawore, N.O.; Kasali, A.A.; König, W.A.,
Chemical composition of the leaf volatile oils of Callitris intratropica R.T. Baker H.G. Smith from Nigeria,
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Özcan, Tzakou, et al., 2003
Özcan, M.; Tzakou, O.; Couladis, M.,
Essential oil composition of Turkish herbal tea (Salvia aucheri Bentham var. canescens Boiss. Heldr.),
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Buchin, Salmon, et al., 2002
Buchin, S.; Salmon, J.-C.; Carnat, A.-P.; Berger, T.; Bugaud, C.; Bosset, J.O.,
Identification de composés monoterpéniques, sesquiterpéniques et benzéniques dans un lait d'alpage très riche en ces substances,
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El-Ghorab, Fadel, et al., 2002
El-Ghorab, A.H.; Fadel, H.M.; El-Massry, K.F.,
The Egyptian Eucalyptus camaldulensis var. brevirostris: chemical compositions of the fruit volatile oil and antioxidant activity,
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El-Massry, El-Ghorab, et al., 2002
El-Massry, K.F.; El-Ghorab, A.H.; Farouk, A.,
Antioxidant activity and volatile components of Egyptian Artemisia judaica L.,
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Mita, Tsitsimpikou, et al., 2002
Mita, E.; Tsitsimpikou, C.; Tsiveleka, L.; Petrakis, P.V.; Ortiz, A.; Vagias, C.; Roussis, V.,
Seasonal Variation of Oleoresin Terpenoids from Pinus halepensis and Pinus pinea and Host Selection of the Scale Insect Marchalina hellenica (Homoptera, Coccoidea, Margarodidae, Coelostonidiinae),
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Palá-Paúl, Velasco-Negueruela, et al., 2002
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Essential oil composition of the aerial parts of Cachrys sicula L.,
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Raina, Lal, et al., 2002
Raina, V.K.; Lal, R.K.; Tripathi, S.; Khan, M.; Syamasundar, K.V.; Srivastava, S.K.,
Erratum. Essential oil composition of genetically diverse stocks of Murraya koenigii from India,
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Raina, Srivastava, et al., 2002
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The essential oil of 'greater galangal' [Alpinia galanga (L.) Willd.] from the lower Himalayan region of India,
Flavour Fragr. J., 2002, 17, 5, 358-360, https://doi.org/10.1002/ffj.1105
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Salido, Altarejos, et al., 2002
Salido, S.; Altarejos, J.; Nogueras, M.; Sánchez, A.; Pannecouque, C.; Witvrouw, M.; De Clercq, E.,
Chemical studies of essential oils of Juniperus oxycedrus ssp. badia,
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Yáñez, Pinzón, et al., 2002
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Chemical composition of the essential oil of Psidium caudatum McVaugh,
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Gudzic, Dordevic, et al., 2001
Gudzic, B.; Dordevic, S.; Palic, R.; Stojanovic, G.,
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Adams, 2000
Adams, R.P.,
Systematics of smooth leaf margin Juniperus of the western hemisphere based on leaf essential oils and RAPD DNA fingerprinting,
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Adams, 2000, 2
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Systematics of Juniperus section Juniperus based on leaf essential oils and random amplified polymorphic DNAs (RAPDs),
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Adams, 2000, 3
Adams, R.P.,
Systematics of the one seeded Juniperus of the eastern hemisphere based on leaf essential oils and random amplified polymorphic DNAs (RAPDs),
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Adams, 2000, 4
Adams, R.P.,
The serrate leaf margined Juniperus (Section Sabina) of the western hemisphere: systematics and evolution based on leaf essential oils and Random Amplified Polymorphic DNAs (RAPDs),
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Adams, 1999
Adams, R.P.,
Systematics of multi-seeded eastern hemisphere Juniperus based on leaf essential oils and RAPD DNA fingerprinting,
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Jantan I. and Ahmad A.S., 1999
Jantan I.; Ahmad A.S.,
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Kaul, V.K.; Vats, S.K.,
Essential oil composition of Bothriochloa pertusa and phyletic relationship in aromatic grasses,
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Mallavarapu, Rao, et al., 1998
Mallavarapu, G.R.; Rao, B.R.R.; Kaul, P.N.; Ramesh, S.; Bhattacharya, A.K.,
Volatile constituents of the essential oils of the seeds and the herb of palmarosa (Cymbopogon martinii (Roxb.) Wats. var. motia Burk.),
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Tellez, Estell, et al., 1997
Tellez, M.R.; Estell, R.E.; Fredrickson, E.L.; Havstad, K.M.,
Essential oil of Dyssodia acerosa DC.,
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Burns and Tingey, 1983
Burns, W.F.; Tingey, D.T.,
GC/MS Analysis of biogenic volatile hydrocarbons on a chemically-bonded fused silica column,
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Notes
Go To: Top, Kovats' RI, non-polar column, temperature ramp, References
- Symbols used in this document:
Tend Final temperature Tstart Initial temperature - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
- The National Institute of Standards and Technology (NIST) uses its best efforts to deliver a high quality copy of the Database and to verify that the data contained therein have been selected on the basis of sound scientific judgment. However, NIST makes no warranties to that effect, and NIST shall not be liable for any damage that may result from errors or omissions in the Database.
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