Carbon anion
- Formula: C2-
- Molecular weight: 24.0219
- IUPAC Standard InChI: InChI=1S/CH3/h1H3/q-1
- IUPAC Standard InChIKey: LGRLWUINFJPLSH-UHFFFAOYSA-N
- CAS Registry Number: 50802-47-6
- Chemical structure:
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Gas phase thermochemistry data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
B - John E. Bartmess
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔfH°gas | 119.3 ± 3.8 | kcal/mol | R-EA | Ervin, Gronert, et al., 1990 | B |
| ΔfH°gas | <197.5 ± 4.6 | kcal/mol | EIAE | Collin and Locht, 1970 | From ketene; B |
| Quantity | Value | Units | Method | Reference | Comment |
| S°gas,1 bar | 46.989 | cal/mol*K | Review | Chase, 1998 | Data last reviewed in December, 1969 |
Gas phase ion energetics data
Go To: Top, Gas phase thermochemistry data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: John E. Bartmess
Protonation reactions
+
= C2H
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | >349.0 ± 3.6 | kcal/mol | D-EA | Arnold, Bradforth, et al., 1991 | gas phase |
| ΔrH° | <375.8 ± 2.3 | kcal/mol | G+TS | Schiff and Bohme, 1975 | gas phase; No reaction with acetylene |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrG° | >341.7 ± 3.8 | kcal/mol | H-TS | Arnold, Bradforth, et al., 1991 | gas phase |
| ΔrG° | <368.5 ± 2.0 | kcal/mol | IMRB | Schiff and Bohme, 1975 | gas phase; No reaction with acetylene |
References
Go To: Top, Gas phase thermochemistry data, Gas phase ion energetics data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Ervin, Gronert, et al., 1990
Ervin, K.M.; Gronert, S.; Barlow, S.E.; Gilles, M.K.; Harrison, A.G.; Bierbaum, V.M.; DePuy, C.H.; Lin, W.C.,
Bonds Strengths of Ethylene and Acetylene,
J. Am. Chem. Soc., 1990, 112, 15, 5750, https://doi.org/10.1021/ja00171a013
. [all data]
Collin and Locht, 1970
Collin, J.E.; Locht, R.,
Positive and negative ion formation in ketene by electron impact,
Intern. J. Mass Spectrom. Ion Phys., 1970, 3, 465. [all data]
Chase, 1998
Chase, M.W., Jr.,
NIST-JANAF Themochemical Tables, Fourth Edition,
J. Phys. Chem. Ref. Data, Monograph 9, 1998, 1-1951. [all data]
Arnold, Bradforth, et al., 1991
Arnold, D.W.; Bradforth, S.E.; Kitsopoulos, T.N.; Neumark, D.M.,
Vibrationally Resolved Spectra of C2-C11 by Anion Photoelectron Spectroscopy,
J. Chem. Phys., 1991, 95, 12, 8753, https://doi.org/10.1063/1.461211
. [all data]
Schiff and Bohme, 1975
Schiff, H.I.; Bohme, D.K.,
Flowing afterglow studies at York University,
Int. J. Mass Spectrom. Ion Phys., 1975, 16, 167. [all data]
Notes
Go To: Top, Gas phase thermochemistry data, Gas phase ion energetics data, References
- Symbols used in this document:
S°gas,1 bar Entropy of gas at standard conditions (1 bar) ΔfH°gas Enthalpy of formation of gas at standard conditions ΔrG° Free energy of reaction at standard conditions ΔrH° Enthalpy of reaction at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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