N,N'-dinitroethylenediamine

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Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Quantity Value Units Method Reference Comment
Δfsolid-24.1 ± 0.4kcal/molCcbKrien, Licht, et al., 1973Author's hf298_condensed=-25. kcal/mol
Δfsolid-24.58 ± 0.37kcal/molCcbMedard and Thomas, 1955Heat of combustion corrected for pressure
Quantity Value Units Method Reference Comment
Δcsolid-369. ± 0.40kcal/molCcbKrien, Licht, et al., 1973Author's hf298_condensed=-25. kcal/mol
Δcsolid-368.1kcal/molCcbHandrick, 1956Naval Powder Factory Report 88, 1954
Δcsolid-370.9kcal/molCcbYoung, Keith, et al., 1956 
Δcsolid-368.47 ± 0.37kcal/molCcbMedard and Thomas, 1955Heat of combustion corrected for pressure

Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: William E. Acree, Jr., James S. Chickos

Enthalpy of fusion

ΔfusH (kcal/mol) Temperature (K) Reference
7.05450.Oyumi and Brill, 1987

References

Go To: Top, Condensed phase thermochemistry data, Phase change data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Krien, Licht, et al., 1973
Krien, G.; Licht, H.H.; Zierath, J., Thermochemical investigation of nitramines, Thermochim. Acta, 1973, 6, 465-472. [all data]

Medard and Thomas, 1955
Medard, L.; Thomas, M., Chaleurs de combustion de sept substances explosives ou apparentees a des explosifs, Mem. Poudres, 1955, 37, 129-138. [all data]

Handrick, 1956
Handrick, G.R., Report of the study of pure explosive compounds. Part IV. Calculation of heat of combustion of organic compounds from structural features and calculation of power of high explosives, Rpt. C-58247 for the Office of the Chief of Ordnance, contract DA-19-020-ORD-47 by the Arthur D. Little, Inc., Cambridge, MA, 1956, 467-573. [all data]

Young, Keith, et al., 1956
Young, J.A.; Keith, J.E.; Stehle, P.; Dzombak, W.C.; Hunt, H., Heats of combustion of some organic nitrogen compounds, Ind. Eng. Chem., 1956, 48, 1375-1378. [all data]

Oyumi and Brill, 1987
Oyumi, Y.; Brill, T.B., Thermal decomposition of energetic materials. 23. Thermochemical differentiation of cyclic and acyclic nitramines by their phase transitions, Thermochim. Acta, 1987, 116, 125-130. [all data]


Notes

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