2-Butene, 1-chloro-3-methyl-
- Formula: C5H9Cl
- Molecular weight: 104.578
- IUPAC Standard InChI: InChI=1S/C5H9Cl/c1-5(2)3-4-6/h3H,4H2,1-2H3
- IUPAC Standard InChIKey: JKXQKGNGJVZKFA-UHFFFAOYSA-N
- CAS Registry Number: 503-60-6
- Chemical structure:
This structure is also available as a 2d Mol file or as a computed 3d SD file
The 3d structure may be viewed using Java or Javascript. - Other names: γ,γ-Dimethylallyl chloride; Prenyl chloride; 3-Methyl-2-butenyl chloride; 3-Methylcrotyl chloride; 3,3-Dimethylallyl chloride; 1-Chloro-3-methyl-2-butene; Isoprenyl chloride; 1-chloro-3-methylbut-2-ene
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Reaction thermochemistry data
Go To: Top, Gas Chromatography, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.
Individual Reactions
=
+
By formula: C5H10Cl2 = C5H9Cl + HCl
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 62.3 ± 4.6 | kJ/mol | Eqk | Meged, Levanova, et al., 1980 | gas phase |
Gas Chromatography
Go To: Top, Reaction thermochemistry data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director
Van Den Dool and Kratz RI, non-polar column, temperature ramp
| Column type | Active phase | I | Reference | Comment |
|---|---|---|---|---|
| Capillary | Petrocol DH | 751. | White, Hackett, et al., 1992 | 100. m/0.25 mm/0.5 μm, He, 1. K/min; Tstart: 30. C; Tend: 220. C |
Normal alkane RI, non-polar column, isothermal
| Column type | Active phase | Temperature (C) | I | Reference | Comment |
|---|---|---|---|---|---|
| Capillary | Squalane | 30. | 724. | Tourres, 1968 | Nitrogen; Column length: 50. m; Column diameter: 0.25 mm |
| Capillary | Squalane | 50. | 726. | Tourres, 1968 | Nitrogen; Column length: 50. m; Column diameter: 0.25 mm |
Normal alkane RI, non-polar column, temperature ramp
| Column type | Active phase | I | Reference | Comment |
|---|---|---|---|---|
| Capillary | OV-101 | 760. | Zenkevich, 2005 | 25. m/0.20 mm/0.10 μm, N2/He, 6. K/min; Tstart: 50. C; Tend: 250. C |
References
Go To: Top, Reaction thermochemistry data, Gas Chromatography, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Meged, Levanova, et al., 1980
Meged, V.M.; Levanova, S.V.; Rozhnov, A.M.,
Dehydrohalogenation of dihalomethylbutanes. 2.,
Izv. Vyssh. Uchebn. Zaved., Khim. Khim. Tekhnol., 1980, 23, 149-151. [all data]
White, Hackett, et al., 1992
White, C.M.; Hackett, J.; Anderson, R.R.; Kail, S.; Spock, P.S.,
Linear temperature programmed retention indices of gasoline range hydrocarbons and chlorinated hydrocarbons on cross-linked polydimethylsiloxane,
J. Hi. Res. Chromatogr., 1992, 15, 2, 105-120, https://doi.org/10.1002/jhrc.1240150211
. [all data]
Tourres, 1968
Tourres, D.A.,
Separation of mono- and dichloro-methyl butanes and of monochloro-methyl butenes by preparative gas chromatography,
Chromatographia, 1968, 1, 11-12, 437-442, https://doi.org/10.1007/BF02255759
. [all data]
Zenkevich, 2005
Zenkevich, I.G.,
Experimentally measured retention indices., 2005. [all data]
Notes
Go To: Top, Reaction thermochemistry data, Gas Chromatography, References
- Symbols used in this document:
ΔrH° Enthalpy of reaction at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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