p,p'-DDT

• Formula: C₁₄H₉Cl₅
• Molecular weight: 354.486
• IUPAC Standard InChI: InChI=1S/C14H9Cl5/c15-11-5-1-9(2-6-11)13(14(17,18)19)10-3-7-12(16)8-4-10/h1-8,13H Copy

  
• IUPAC Standard InChIKey: YVGGHNCTFXOJCH-UHFFFAOYSA-N Copy
• CAS Registry Number: 50-29-3
• Chemical structure:
  This structure is also available as a 2d Mol file or as a computed 3d SD file
  The 3d structure may be viewed using Java or Javascript.
• Other names: Benzene, 1,1'-(2,2,2-trichloroethylidene)bis[4-chloro-; Chlorophenothane; α,α-Bis(p-chlorophenyl)-β,β,β-trichlorethane; p,p'-Dichlorodiphenyltrichloroethane; Aavero-extra; Agritan; Arkotine; Azotox; Azotox M-33; Bosan supra; Bovidermol; Chlorphenothan; Chlorphenotoxum; Citox; Clofenotan; Clofenotane; Deoval; Detox; Detoxan; Dibovin; Dicophane; Dodat; Dykol; DDT; Estonate; Ethane, 1,1,1-Trichloro-2,2-bis(p-chlorophenyl)-; Ethane, 1,1,1-trichloro-2,2-bis(4-chlorophenyl)-; ENT-1506; Gesafid; Gesarol; Ivoran; Mutoxan; Neocid; Neocidol, Solid; Parachlorocidum; Pentachlorin; Penticidum; PEB1; Trichlorobis(4'-Chlorophenyl)ethane; Zerdane; 1,1,1-Trichloro-2,2-bis(p-chlorophenyl)ethane; 1,1,1-Trichloro-2,2-bis(4,4'-dichlorodiphenyl)ethane; 2,2-Bis(p-chlorophenyl)-1,1,1-trichloroethane; 4,4'-Dichlorodiphenyltrichloroethane; 4,4'-DDT; 1,1-Bis(4-chlorophenyl)-2,2,2-trichloroethane; 1,1,1-trichloro-2-2-bis(4-chlorophenyl)ethane; Anofex; Didigam; Didimac; Genitox; Guesarol; Gyron; Ixodex; Kopsol; Neocidol; NCI-C00464; Pentech; pPzeidan; Rukseam; Santobane; Tafidex; Trichlorobis(4-chlorophenyl)ethane; Zeidane; 1,1,1-Trichloor-2,2-bis(4-chloor fenyl)-ethaan; 1,1,1-Trichlor-2,2-bis(4-chlor-phenyl)-aethan; 1,1,1-Trichloro-2,2-di(4-chlorophenyl)ethane; 1,1,1-Tricloro-2,2-bis(4-cloro-fenil)-etano; Chlorophenothan; Chlorophenotoxum; Dedelo; Dibovan; ENT 1,506; Gesapon; Gesarex; Guesapon; Havero-extra; Hildit; Micro DDT 75; Mutoxin; OMS 16; R50; RCRA Waste number U061; Penticide; 2,2,2-Trichloro-1,1-bis(4-chlorophenyl)ethane; p,p'-Dichlorodiphenyltrichloromethylmethane; 1,1'-(2,2,2,-Trichloroethylidene)bis[4-chlorobenzene]; Geusapon; 1,1-bis(p-Chlorophenyl)-2,2,2-trichIoroethane; DDT(p,p'); Dicophaner; Benzochloryl; p,p-DDT; 1,1,1-Trichloro-2,2-bis(4-chlorophenyl)ethane (pp'DDT)
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• Information on this page:
  • Phase change data
  • IR Spectrum
  • UV/Visible spectrum
  • References
  • Notes
• Other data available:
  • Henry's Law data
  • Mass spectrum (electron ionization)
  • Gas Chromatography
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Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny director
AC - William E. Acree, Jr., James S. Chickos

Enthalpy of vaporization

Enthalpy of sublimation

Enthalpy of fusion

IR Spectrum

Go To: Top, Phase change data, UV/Visible spectrum, References, Notes

Data compiled by: Coblentz Society, Inc.

• SOLUTION (10% IN CCl4 FOR 3800-1330, 10% IN CS2 FOR 1330-450 CM^-1); DOW KBr FOREPRISM-GRATING; DIGITIZED BY NIST FROM HARD COPY (FROM TWO SEGMENTS); 4 cm^-1 resolution

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

• gas; HP-GC/MS/IRD

UV/Visible spectrum

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Victor Talrose, Eugeny B. Stern, Antonina A. Goncharova, Natalia A. Messineva, Natalia V. Trusova, Margarita V. Efimkina

Spectrum

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Additional Data

References

Go To: Top, Phase change data, IR Spectrum, UV/Visible spectrum, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Donnelly, Drewes, et al., 1990
Donnelly, J.R.; Drewes, L.A.; Johnson, R.L.; Munslow, W.D.; Knapp, K.K.; Sovocool, G.W., Purity and heat of fusion data for environmental standards as determined by differential scanning calorimetry, Thermochim. Acta, 1990, 167, 2, 155, https://doi.org/10.1016/0040-6031(90)80476-F . [all data]

Plato and Glasgow, 1969
Plato, C.; Glasgow, A.R., Jr., Differential scanning calorimetry as a general method for determining the purity and heat of fusion of high-purity organic chemicals. Application to 95 compounds, Anal. Chem., 1969, 41, 2, 330, https://doi.org/10.1021/ac60271a041 . [all data]

Dickinson, 1956
Dickinson, W., The vapour pressure of 1:1:p:p? dichlorodiphenyl trichloroethane (D.D.T.), Trans. Faraday Soc., 1956, 52, 31, https://doi.org/10.1039/tf9565200031 . [all data]

Puri, Chickos, et al., 2001
Puri, Swati; Chickos, James S.; Welsh, William J., Determination of Vaporization Enthalpies of Polychlorinated Biphenyls by Correlation Gas Chromatography, Anal. Chem., 2001, 73, 7, 1480-1484, https://doi.org/10.1021/ac001246p . [all data]

Hinckley, Bidleman, et al., 1990
Hinckley, Daniel A.; Bidleman, Terry F.; Foreman, William T.; Tuschall, Jack R., Determination of vapor pressures for nonpolar and semipolar organic compounds from gas chromatograhic retention data, J. Chem. Eng. Data, 1990, 35, 3, 232-237, https://doi.org/10.1021/je00061a003 . [all data]

Kuhn and Massini, 1949
Kuhn, Werner; Massini, Peter, Temperaturabh«65533»ngigkeit des Dampfdrucks sowie der Verdampfungsgeschwindigkeit von Dichlorodiphenyltrichlor«65533»than, Helv. Chim. Acta, 1949, 32, 5, 1530-1542, https://doi.org/10.1002/hlca.19490320520 . [all data]

Wania, Shiu, et al., 1994
Wania, Frank; Shiu, Wan-Ying; Mackay, Donald, Measurement of the Vapor Pressure of Several Low-Volatility Organochlorine Chemicals at Low Temperatures with a Gas Saturation Method, J. Chem. Eng. Data, 1994, 39, 3, 572-577, https://doi.org/10.1021/je00015a039 . [all data]

Stephenson and Malanowski, 1987
Stephenson, Richard M.; Malanowski, Stanislaw, Handbook of the Thermodynamics of Organic Compounds, 1987, https://doi.org/10.1007/978-94-009-3173-2 . [all data]

Rothman, 1980
Rothman, Alan M., Low vapor pressure determination by the radiotracer transpiration method, J. Agric. Food Chem., 1980, 28, 6, 1225-1228, https://doi.org/10.1021/jf60232a033 . [all data]

Spencer and Cliath, 1972
Spencer, William F.; Cliath, Mark M., Volatility of DDT and related compounds, J. Agric. Food Chem., 1972, 20, 3, 645-649, https://doi.org/10.1021/jf60181a057 . [all data]

Jones, 1960
Jones, A.H., Sublimation Pressure Data for Organic Compounds., J. Chem. Eng. Data, 1960, 5, 2, 196-200, https://doi.org/10.1021/je60006a019 . [all data]

Balson, 1947
Balson, E.W., Studies in vapour pressure measurement, Part III.?An effusion manometer sensitive to 5 «65533» 10?6 millimetres of mercury: vapour pressure of D.D.T. and other slightly volatile substances, Trans. Faraday Soc., 1947, 43, 54, https://doi.org/10.1039/tf9474300054 . [all data]

Acree, 1991
Acree, William E., Thermodynamic properties of organic compounds: enthalpy of fusion and melting point temperature compilation, Thermochimica Acta, 1991, 189, 1, 37-56, https://doi.org/10.1016/0040-6031(91)87098-H . [all data]

Donnelly, Drewes, et al., 1990, 2
Donnelly, J.R.; Drewes, L.A.; Johnson, R.L.; Munslow, W.D.; Knapp, K.K.; Sovocool, G.W., Purity and heat of fusion data for environmental standards as determined by differential scanning calorimetry, Thermochimica Acta, 1990, 167, 2, 155-187, https://doi.org/10.1016/0040-6031(90)80476-F . [all data]

Bartecki, Szoke, et al., 1965
Bartecki, A.; Szoke, J.; Varasanyi, G.; Vizesy, M., Absorption spectra in the ultraviolet and visible region. Volume 6, Academic Press Inc., New York, 1965, 84. [all data]

Notes

Go To: Top, Phase change data, IR Spectrum, UV/Visible spectrum, References

• Symbols used in this document:
  

  Tfus	Fusion (melting) point
  ΔfusH	Enthalpy of fusion
  ΔsubH	Enthalpy of sublimation
  ΔvapH	Enthalpy of vaporization

• Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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