p,p'-DDT

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Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny director
AC - William E. Acree, Jr., James S. Chickos

Quantity Value Units Method Reference Comment
Tfus383.17KN/ADonnelly, Drewes, et al., 1990Uncertainty assigned by TRC = 0.2 K; TRC
Tfus383.0KN/APlato and Glasgow, 1969Uncertainty assigned by TRC = 0.2 K; TRC
Tfus382.25KN/ADickinson, 1956Uncertainty assigned by TRC = 1. K; TRC

Enthalpy of vaporization

ΔvapH (kJ/mol) Temperature (K) Method Reference Comment
106.1 ± 1.3398.GSPuri, Chickos, et al., 2001AC
93.2398.GCHinckley, Bidleman, et al., 1990Based on data from 343. to 453. K.; AC
338.83.7N/AKuhn and Massini, 1949Based on data from 313. to 363. K.; AC

Enthalpy of sublimation

ΔsubH (kJ/mol) Temperature (K) Method Reference Comment
120.2 ± 1.0293.GSWania, Shiu, et al., 1994Based on data from 273. to 313. K.; AC
115.338.AStephenson and Malanowski, 1987Based on data from 323. to 363. K.; AC
110.304.GSRothman, 1980Based on data from 293. to 353. K.; AC
117.8303.GSSpencer and Cliath, 1972Based on data from 293. to 313. K.; AC
117.5338.GSDickinson, 1956Based on data from 323. to 363. K. See also Jones, 1960.; AC
84.338.GSKuhn and Massini, 1949Based on data from 313. to 363. K.; AC
118.356.TEBalson, 1947Based on data from 339. to 373. K.; AC

Enthalpy of fusion

ΔfusH (kJ/mol) Temperature (K) Method Reference Comment
26.28382.1DSCAcree, 1991See also Donnelly, Drewes, et al., 1990, 2.; AC

In addition to the Thermodynamics Research Center (TRC) data available from this site, much more physical and chemical property data is available from the following TRC products:


IR Spectrum

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Data compiled by: Coblentz Society, Inc.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director


UV/Visible spectrum

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Victor Talrose, Eugeny B. Stern, Antonina A. Goncharova, Natalia A. Messineva, Natalia V. Trusova, Margarita V. Efimkina

Spectrum

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Additional Data

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Source Bartecki, Szoke, et al., 1965
Owner INEP CP RAS, NIST OSRD
Collection (C) 2007 copyright by the U.S. Secretary of Commerce
on behalf of the United States of America. All rights reserved.
Origin INSTITUTE OF ENERGY PROBLEMS OF CHEMICAL PHYSICS, RAS
Source reference RAS UV No. 9035
Instrument Zeiss VSU-1
Melting point 108.5
Boiling point 260; 186(0.05)

References

Go To: Top, Phase change data, IR Spectrum, UV/Visible spectrum, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Donnelly, Drewes, et al., 1990
Donnelly, J.R.; Drewes, L.A.; Johnson, R.L.; Munslow, W.D.; Knapp, K.K.; Sovocool, G.W., Purity and heat of fusion data for environmental standards as determined by differential scanning calorimetry, Thermochim. Acta, 1990, 167, 2, 155, https://doi.org/10.1016/0040-6031(90)80476-F . [all data]

Plato and Glasgow, 1969
Plato, C.; Glasgow, A.R., Jr., Differential scanning calorimetry as a general method for determining the purity and heat of fusion of high-purity organic chemicals. Application to 95 compounds, Anal. Chem., 1969, 41, 2, 330, https://doi.org/10.1021/ac60271a041 . [all data]

Dickinson, 1956
Dickinson, W., The vapour pressure of 1:1:p:p? dichlorodiphenyl trichloroethane (D.D.T.), Trans. Faraday Soc., 1956, 52, 31, https://doi.org/10.1039/tf9565200031 . [all data]

Puri, Chickos, et al., 2001
Puri, Swati; Chickos, James S.; Welsh, William J., Determination of Vaporization Enthalpies of Polychlorinated Biphenyls by Correlation Gas Chromatography, Anal. Chem., 2001, 73, 7, 1480-1484, https://doi.org/10.1021/ac001246p . [all data]

Hinckley, Bidleman, et al., 1990
Hinckley, Daniel A.; Bidleman, Terry F.; Foreman, William T.; Tuschall, Jack R., Determination of vapor pressures for nonpolar and semipolar organic compounds from gas chromatograhic retention data, J. Chem. Eng. Data, 1990, 35, 3, 232-237, https://doi.org/10.1021/je00061a003 . [all data]

Kuhn and Massini, 1949
Kuhn, Werner; Massini, Peter, Temperaturabh«65533»ngigkeit des Dampfdrucks sowie der Verdampfungsgeschwindigkeit von Dichlorodiphenyltrichlor«65533»than, Helv. Chim. Acta, 1949, 32, 5, 1530-1542, https://doi.org/10.1002/hlca.19490320520 . [all data]

Wania, Shiu, et al., 1994
Wania, Frank; Shiu, Wan-Ying; Mackay, Donald, Measurement of the Vapor Pressure of Several Low-Volatility Organochlorine Chemicals at Low Temperatures with a Gas Saturation Method, J. Chem. Eng. Data, 1994, 39, 3, 572-577, https://doi.org/10.1021/je00015a039 . [all data]

Stephenson and Malanowski, 1987
Stephenson, Richard M.; Malanowski, Stanislaw, Handbook of the Thermodynamics of Organic Compounds, 1987, https://doi.org/10.1007/978-94-009-3173-2 . [all data]

Rothman, 1980
Rothman, Alan M., Low vapor pressure determination by the radiotracer transpiration method, J. Agric. Food Chem., 1980, 28, 6, 1225-1228, https://doi.org/10.1021/jf60232a033 . [all data]

Spencer and Cliath, 1972
Spencer, William F.; Cliath, Mark M., Volatility of DDT and related compounds, J. Agric. Food Chem., 1972, 20, 3, 645-649, https://doi.org/10.1021/jf60181a057 . [all data]

Jones, 1960
Jones, A.H., Sublimation Pressure Data for Organic Compounds., J. Chem. Eng. Data, 1960, 5, 2, 196-200, https://doi.org/10.1021/je60006a019 . [all data]

Balson, 1947
Balson, E.W., Studies in vapour pressure measurement, Part III.?An effusion manometer sensitive to 5 «65533» 10?6 millimetres of mercury: vapour pressure of D.D.T. and other slightly volatile substances, Trans. Faraday Soc., 1947, 43, 54, https://doi.org/10.1039/tf9474300054 . [all data]

Acree, 1991
Acree, William E., Thermodynamic properties of organic compounds: enthalpy of fusion and melting point temperature compilation, Thermochimica Acta, 1991, 189, 1, 37-56, https://doi.org/10.1016/0040-6031(91)87098-H . [all data]

Donnelly, Drewes, et al., 1990, 2
Donnelly, J.R.; Drewes, L.A.; Johnson, R.L.; Munslow, W.D.; Knapp, K.K.; Sovocool, G.W., Purity and heat of fusion data for environmental standards as determined by differential scanning calorimetry, Thermochimica Acta, 1990, 167, 2, 155-187, https://doi.org/10.1016/0040-6031(90)80476-F . [all data]

Bartecki, Szoke, et al., 1965
Bartecki, A.; Szoke, J.; Varasanyi, G.; Vizesy, M., Absorption spectra in the ultraviolet and visible region. Volume 6, Academic Press Inc., New York, 1965, 84. [all data]


Notes

Go To: Top, Phase change data, IR Spectrum, UV/Visible spectrum, References