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p,p'-DDT

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Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny, director
AC - William E. Acree, Jr., James S. Chickos

Quantity Value Units Method Reference Comment
Tfus383.17KN/ADonnelly, Drewes, et al., 1990Uncertainty assigned by TRC = 0.2 K; TRC
Tfus383.0KN/APlato and Glasgow, 1969Uncertainty assigned by TRC = 0.2 K; TRC
Tfus382.25KN/ADickinson, 1956Uncertainty assigned by TRC = 1. K; TRC

Enthalpy of vaporization

DeltavapH (kJ/mol) Temperature (K) Method Reference Comment
106.1 ± 1.3398.GSPuri, Chickos, et al., 2001AC
93.2398.GCHinckley, Bidleman, et al., 1990Based on data from 343. - 453. K.; AC
338.83.7N/AKuhn and Massini, 1949Based on data from 313. - 363. K.; AC

Enthalpy of sublimation

DeltasubH (kJ/mol) Temperature (K) Method Reference Comment
120.2 ± 1.0293.GSWania, Shiu, et al., 1994Based on data from 273. - 313. K.; AC
115.338.AStephenson and Malanowski, 1987Based on data from 323. - 363. K.; AC
110.304.GSRothman, 1980Based on data from 293. - 353. K.; AC
117.8303.GSSpencer and Cliath, 1972Based on data from 293. - 313. K.; AC
117.5338.GSDickinson, 1956Based on data from 323. - 363. K. See also Jones, 1960.; AC
84.338.GSKuhn and Massini, 1949Based on data from 313. - 363. K.; AC
118.356.TEBalson, 1947Based on data from 339. - 373. K.; AC

Enthalpy of fusion

DeltafusH (kJ/mol) Temperature (K) Method Reference Comment
26.28382.1DSCAcree, 1991See also Donnelly, Drewes, et al., 1990, 2.; AC

In addition to the Thermodynamics Research Center (TRC) data available from this site, much more physical and chemical property data is available from the following TRC products:


References

Go To: Top, Phase change data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Donnelly, Drewes, et al., 1990
Donnelly, J.R.; Drewes, L.A.; Johnson, R.L.; Munslow, W.D.; Knapp, K.K.; Sovocool, G.W., Purity and heat of fusion data for environmental standards as determined by differential scanning calorimetry, Thermochim. Acta, 1990, 167, 2, 155, https://doi.org/10.1016/0040-6031(90)80476-F . [all data]

Plato and Glasgow, 1969
Plato, C.; Glasgow, A.R., Jr., Differential scanning calorimetry as a general method for determining the purity and heat of fusion of high-purity organic chemicals. Application to 95 compounds, Anal. Chem., 1969, 41, 2, 330, https://doi.org/10.1021/ac60271a041 . [all data]

Dickinson, 1956
Dickinson, W., The vapour pressure of 1:1:p:p? dichlorodiphenyl trichloroethane (D.D.T.), Trans. Faraday Soc., 1956, 52, 31, https://doi.org/10.1039/tf9565200031 . [all data]

Puri, Chickos, et al., 2001
Puri, Swati; Chickos, James S.; Welsh, William J., Determination of Vaporization Enthalpies of Polychlorinated Biphenyls by Correlation Gas Chromatography, Anal. Chem., 2001, 73, 7, 1480-1484, https://doi.org/10.1021/ac001246p . [all data]

Hinckley, Bidleman, et al., 1990
Hinckley, Daniel A.; Bidleman, Terry F.; Foreman, William T.; Tuschall, Jack R., Determination of vapor pressures for nonpolar and semipolar organic compounds from gas chromatograhic retention data, J. Chem. Eng. Data, 1990, 35, 3, 232-237, https://doi.org/10.1021/je00061a003 . [all data]

Kuhn and Massini, 1949
Kuhn, Werner; Massini, Peter, Temperaturabh«65533»ngigkeit des Dampfdrucks sowie der Verdampfungsgeschwindigkeit von Dichlorodiphenyltrichlor«65533»than, Helv. Chim. Acta, 1949, 32, 5, 1530-1542, https://doi.org/10.1002/hlca.19490320520 . [all data]

Wania, Shiu, et al., 1994
Wania, Frank; Shiu, Wan-Ying; Mackay, Donald, Measurement of the Vapor Pressure of Several Low-Volatility Organochlorine Chemicals at Low Temperatures with a Gas Saturation Method, J. Chem. Eng. Data, 1994, 39, 3, 572-577, https://doi.org/10.1021/je00015a039 . [all data]

Stephenson and Malanowski, 1987
Stephenson, Richard M.; Malanowski, Stanislaw, Handbook of the Thermodynamics of Organic Compounds, 1987, https://doi.org/10.1007/978-94-009-3173-2 . [all data]

Rothman, 1980
Rothman, Alan M., Low vapor pressure determination by the radiotracer transpiration method, J. Agric. Food Chem., 1980, 28, 6, 1225-1228, https://doi.org/10.1021/jf60232a033 . [all data]

Spencer and Cliath, 1972
Spencer, William F.; Cliath, Mark M., Volatility of DDT and related compounds, J. Agric. Food Chem., 1972, 20, 3, 645-649, https://doi.org/10.1021/jf60181a057 . [all data]

Jones, 1960
Jones, A.H., Sublimation Pressure Data for Organic Compounds., J. Chem. Eng. Data, 1960, 5, 2, 196-200, https://doi.org/10.1021/je60006a019 . [all data]

Balson, 1947
Balson, E.W., Studies in vapour pressure measurement, Part III.?An effusion manometer sensitive to 5 «65533» 10?6 millimetres of mercury: vapour pressure of D.D.T. and other slightly volatile substances, Trans. Faraday Soc., 1947, 43, 54, https://doi.org/10.1039/tf9474300054 . [all data]

Acree, 1991
Acree, William E., Thermodynamic properties of organic compounds: enthalpy of fusion and melting point temperature compilation, Thermochimica Acta, 1991, 189, 1, 37-56, https://doi.org/10.1016/0040-6031(91)87098-H . [all data]

Donnelly, Drewes, et al., 1990, 2
Donnelly, J.R.; Drewes, L.A.; Johnson, R.L.; Munslow, W.D.; Knapp, K.K.; Sovocool, G.W., Purity and heat of fusion data for environmental standards as determined by differential scanning calorimetry, Thermochimica Acta, 1990, 167, 2, 155-187, https://doi.org/10.1016/0040-6031(90)80476-F . [all data]


Notes

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