(+)-3-Carene

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Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
BS - Robert L. Brown and Stephen E. Stein
AC - William E. Acree, Jr., James S. Chickos

Quantity Value Units Method Reference Comment
Δvap11.6kcal/molGCHoskovec, Grygarová, et al., 2005Based on data from 313. to 413. K.; AC

Reduced pressure boiling point

Tboil (K) Pressure (atm) Reference Comment
396.70.263Weast and Grasselli, 1989BS

Enthalpy of vaporization

ΔvapH (kcal/mol) Temperature (K) Method Reference Comment
10.2374.AStephenson and Malanowski, 1987Based on data from 359. to 443. K.; AC

Mass spectrum (electron ionization)

Go To: Top, Phase change data, Gas Chromatography, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Spectrum

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Additional Data

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Owner NIST Mass Spectrometry Data Center
Collection (C) 2014 copyright by the U.S. Secretary of Commerce
on behalf of the United States of America. All rights reserved.
Origin Japan AIST/NIMC Database- Spectrum MS-NW-3994
NIST MS number 232337

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Gas Chromatography

Go To: Top, Phase change data, Mass spectrum (electron ionization), References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Kovats' RI, non-polar column, isothermal

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Column type Active phase Temperature (C) I Reference Comment
CapillaryZB-1100.1012.09Hoskovec, Grygarová, et al., 200530. m/0.32 mm/0.25 μm, He
CapillaryZB-1110.1015.29Hoskovec, Grygarová, et al., 200530. m/0.32 mm/0.25 μm, He
CapillaryZB-1120.1018.6Hoskovec, Grygarová, et al., 200530. m/0.32 mm/0.25 μm, He
CapillaryZB-1130.1021.88Hoskovec, Grygarová, et al., 200530. m/0.32 mm/0.25 μm, He
CapillaryZB-1140.1025.31Hoskovec, Grygarová, et al., 200530. m/0.32 mm/0.25 μm, He
CapillaryZB-140.994.21Hoskovec, Grygarová, et al., 200530. m/0.32 mm/0.25 μm, He
CapillaryZB-150.996.99Hoskovec, Grygarová, et al., 200530. m/0.32 mm/0.25 μm, He
CapillaryZB-160.1000.Hoskovec, Grygarová, et al., 200530. m/0.32 mm/0.25 μm, He
CapillaryZB-170.1002.83Hoskovec, Grygarová, et al., 200530. m/0.32 mm/0.25 μm, He
CapillaryZB-180.1005.88Hoskovec, Grygarová, et al., 200530. m/0.32 mm/0.25 μm, He
CapillaryZB-190.1008.96Hoskovec, Grygarová, et al., 200530. m/0.32 mm/0.25 μm, He

Van Den Dool and Kratz RI, non-polar column, custom temperature program

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Column type Active phase I Reference Comment
CapillaryDB-1995.Suliman F.E.O., Fatope M.O., et al., 200630. m/0.25 mm/0.25 μm, He; Program: 35C => 2C/min => 200C => 5C/min => 240C

Normal alkane RI, non-polar column, temperature ramp

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Column type Active phase I Reference Comment
CapillaryOV-1011002.Orav, Kailas, et al., 200250. m/0.2 mm/0.5 μm, He, 2. K/min; Tstart: 50. C; Tend: 250. C

Normal alkane RI, non-polar column, custom temperature program

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Column type Active phase I Reference Comment
CapillaryCBP-51010.Cheriti, Saad, et al., 200730. m/0.25 mm/0.25 μm, He; Program: 60C(2min) => 3C/min => 240C => 10C/min => 300C

Normal alkane RI, polar column, temperature ramp

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Column type Active phase I Reference Comment
CapillarySupelcowax-101148.Orav, Kailas, et al., 200260. m/0.2 mm/0.5 μm, He, 2. K/min; Tstart: 70. C; Tend: 220. C

References

Go To: Top, Phase change data, Mass spectrum (electron ionization), Gas Chromatography, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Hoskovec, Grygarová, et al., 2005
Hoskovec, Michal; Grygarová, Dana; Cvacka, Josef; Streinz, Ludvík; Zima, Jirí; Verevkin, Sergey P.; Koutek, Bohumír, Determining the vapour pressures of plant volatiles from gas chromatographic retention data, Journal of Chromatography A, 2005, 1083, 1-2, 161-172, https://doi.org/10.1016/j.chroma.2005.06.006 . [all data]

Weast and Grasselli, 1989
CRC Handbook of Data on Organic Compounds, 2nd Editon, Weast,R.C and Grasselli, J.G., ed(s)., CRC Press, Inc., Boca Raton, FL, 1989, 1. [all data]

Stephenson and Malanowski, 1987
Stephenson, Richard M.; Malanowski, Stanislaw, Handbook of the Thermodynamics of Organic Compounds, 1987, https://doi.org/10.1007/978-94-009-3173-2 . [all data]

Suliman F.E.O., Fatope M.O., et al., 2006
Suliman F.E.O.; Fatope M.O.; Al-Saidi S.H.; Al-Kindy S.M.Z.; Marwah R.G., Composition and antimicrobial activity of the essential oil of Pluchea arabica from Oman, Flavour Fragr. J., 2006, 21, 3, 469-471, https://doi.org/10.1002/ffj.1616 . [all data]

Orav, Kailas, et al., 2002
Orav, A.; Kailas, T.; Müürisepp, M., Composition of blackcurrant aroma isolated from leaves, buds, and berries of Ribes nigrum L., Proc. Est. Acad. Sci. Chem., 2002, 51, 4, 225-234. [all data]

Cheriti, Saad, et al., 2007
Cheriti, A.; Saad, A.; Belboukhari, N.; Ghezali, S., The essential oil composition of Bubonium graveolens (Forssk.) Maire from the algerian Sahara, Flavour Fragr. J., 2007, 22, 4, 286-288, https://doi.org/10.1002/ffj.1794 . [all data]


Notes

Go To: Top, Phase change data, Mass spectrum (electron ionization), Gas Chromatography, References