Indane

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Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
DRB - Donald R. Burgess, Jr.
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DH - Eugene S. Domalski and Elizabeth D. Hearing

Quantity Value Units Method Reference Comment
Δfliquid2.80 ± 0.43kcal/molReviewRoux, Temprado, et al., 2008There are sufficient high-quality literature values to make a good evaluation with a high degree of confidence. In general, the evaluated uncertainty limits are on the order of (0.5 to 2.5) kJ/mol.; DRB
Δfliquid2.80 ± 0.35kcal/molCcbGood, 1971ALS
Δfliquid2.56 ± 0.47kcal/molCcbStull, Sinke, et al., 1961see Stull, Sinke, et al., 1959; ALS
Quantity Value Units Method Reference Comment
Δcliquid-1190.84 ± 0.33kcal/molCcbGood, 1971Corresponding Δfliquid = 2.80 kcal/mol (simple calculation by NIST; no Washburn corrections); ALS
Δcliquid-1190.63 ± 0.47kcal/molCcbStull, Sinke, et al., 1961see Stull, Sinke, et al., 1959; Corresponding Δfliquid = 2.59 kcal/mol (simple calculation by NIST; no Washburn corrections); ALS
Quantity Value Units Method Reference Comment
liquid56.011cal/mol*KN/AStull, Sinke, et al., 1961DH
liquid56.009cal/mol*KN/AStull, Sinke, et al., 1959, 2DH

Constant pressure heat capacity of liquid

Cp,liquid (cal/mol*K) Temperature (K) Reference Comment
45.471298.15Stull, Sinke, et al., 1961T = 15 to 320 K. Premelting occurs at 170 K to melting.; DH
45.471298.15Stull, Sinke, et al., 1959, 2T = 15 to 320 K.; DH

Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
BS - Robert L. Brown and Stephen E. Stein
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny director
DRB - Donald R. Burgess, Jr.
AC - William E. Acree, Jr., James S. Chickos
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DH - Eugene S. Domalski and Elizabeth D. Hearing

Quantity Value Units Method Reference Comment
Tboil450. ± 2.KAVGN/AAverage of 9 values; Individual data points
Quantity Value Units Method Reference Comment
Tfus221.46KN/ABoord, Perilstein, et al., 1944Uncertainty assigned by TRC = 0.4 K; TRC
Quantity Value Units Method Reference Comment
Ttriple221.77KN/AStull, Sinke, et al., 1959, 3Uncertainty assigned by TRC = 0.02 K; TRC
Quantity Value Units Method Reference Comment
Tc684.9 ± 0.5KN/ATsonopoulos and Ambrose, 1995 
Tc684.9KN/AMajer and Svoboda, 1985 
Tc684.9KN/AAmbrose, Broderick, et al., 1974Uncertainty assigned by TRC = 0.4 K; TRC
Quantity Value Units Method Reference Comment
Pc39.0 ± 0.4atmN/ATsonopoulos and Ambrose, 1995 
Pc38.98atmN/AAmbrose, Broderick, et al., 1974Uncertainty assigned by TRC = 0.30 atm; TRC
Quantity Value Units Method Reference Comment
Δvap11.7kcal/molN/AMajer and Svoboda, 1985 
Δvap11.8 ± 0.24kcal/molReviewRoux, Temprado, et al., 2008There are sufficient high-quality literature values to make a good evaluation with a high degree of confidence. In general, the evaluated uncertainty limits are on the order of (0.5 to 2.5) kJ/mol.; DRB
Δvap11.7kcal/molCHossenlopp and Scott, 1981AC
Δvap11.72 ± 0.048kcal/molVOsborn and Scott, 1978ALS

Enthalpy of vaporization

ΔvapH (kcal/mol) Temperature (K) Method Reference Comment
9.472451.N/AMajer and Svoboda, 1985 
10.5389.AStephenson and Malanowski, 1987Based on data from 374. to 466. K.; AC
10.8370.N/AAmbrose and Sprake, 1976Based on data from 355. to 482. K.; AC

Enthalpy of vaporization

ΔvapH = A exp(-βTr) (1 − Tr)β
    ΔvapH = Enthalpy of vaporization (at saturation pressure) (kcal/mol)
    Tr = reduced temperature (T / Tc)

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Temperature (K) A (kcal/mol) β Tc (K) Reference Comment
382. to 451.15.60.2866684.9Majer and Svoboda, 1985 

Enthalpy of fusion

ΔfusH (kcal/mol) Temperature (K) Reference Comment
2.055221.77Stull, Sinke, et al., 1959, 2DH
2.1221.8Domalski and Hearing, 1996AC

Entropy of fusion

ΔfusS (cal/mol*K) Temperature (K) Reference Comment
9.266221.77Stull, Sinke, et al., 1959, 2DH

Enthalpy of phase transition

ΔHtrs (kcal/mol) Temperature (K) Initial Phase Final Phase Reference Comment
0.18773.82crystaline, IIcrystaline, IStull, Sinke, et al., 1961DH
2.055221.77crystaline, IliquidStull, Sinke, et al., 1961DH

Entropy of phase transition

ΔStrs (cal/mol*K) Temperature (K) Initial Phase Final Phase Reference Comment
2.52673.82crystaline, IIcrystaline, IStull, Sinke, et al., 1961DH
9.266221.77crystaline, IliquidStull, Sinke, et al., 1961DH

In addition to the Thermodynamics Research Center (TRC) data available from this site, much more physical and chemical property data is available from the following TRC products:


References

Go To: Top, Condensed phase thermochemistry data, Phase change data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Roux, Temprado, et al., 2008
Roux, M.V.; Temprado, M.; Chickos, J.S.; Nagano, Y., Critically Evaluated Thermochemical Properties of Polycyclic Aromatic Hydrocarbons, J. Phys. Chem. Ref. Data, 2008, 37, 4, 1855-1996. [all data]

Good, 1971
Good, W.D., The enthalpies of combustion and formation of indan and seven alkylindans, J. Chem. Thermodyn., 1971, 3, 711-717. [all data]

Stull, Sinke, et al., 1961
Stull, D.R.; Sinke, G.C.; McDonald, R.A.; Hatton, W.E.; Hildenbrand, D.L., Thermodynamic properties of indane and indene, Pure & Appl. Chem., 1961, 2, 315-322. [all data]

Stull, Sinke, et al., 1959
Stull, D.R.; Sinke, G.C.; McDonald, R.A.; Hatton, W.E.; Hildenbrand, D.L., Thermodynamic properties of indane and indene, Symposium uber Thermodynamik, 1959, 1-9. [all data]

Stull, Sinke, et al., 1959, 2
Stull, D.R.; Sinke, G.C.; McDonald, R.A.; Hatton, W.E.; Hildenbrand, D.L., Thermodynamic properties of indane and indene, Symp. Thermodynam. Fritens-Wattens, Tirol Austria, 1959, No. 48, 9p. [all data]

Boord, Perilstein, et al., 1944
Boord, C.E.; Perilstein, W.L.; Greenlee, K.W., , Am. Pet. Inst. Hydrocarbon Res. Proj., Sixth Annu. Ref., Ohio State Univ., Aug. 31, 1944. [all data]

Stull, Sinke, et al., 1959, 3
Stull, D.R.; Sinke, G.C.; McDonald, R.A.; Hatton, W.E.; Hildenbrand, D.L., Thermodynamic properties of indane and indene in Symp. Thermodyn. Fritens-Wattens, Tirol, Austria, 1959. [all data]

Tsonopoulos and Ambrose, 1995
Tsonopoulos, C.; Ambrose, D., Vapor-Liquid Critical Properties of Elements and Compounds. 3. Aromatic Hydrocarbons, J. Chem. Eng. Data, 1995, 40, 547-558. [all data]

Majer and Svoboda, 1985
Majer, V.; Svoboda, V., Enthalpies of Vaporization of Organic Compounds: A Critical Review and Data Compilation, Blackwell Scientific Publications, Oxford, 1985, 300. [all data]

Ambrose, Broderick, et al., 1974
Ambrose, D.; Broderick, B.E.; Townsend, R., The Critical Temperatures and Pressures of Thirty Organic Compounds, J. Appl. Chem. Biotechnol., 1974, 24, 359. [all data]

Hossenlopp and Scott, 1981
Hossenlopp, I.A.; Scott, D.W., Vapor heat capacities and enthalpies of vaporization of four aromatic and/or cycloalkane hydrocarbons, J. Chem. Thermodyn., 1981, 13, 423-428. [all data]

Osborn and Scott, 1978
Osborn, A.G.; Scott, D.W., J. Chem. Thermodyn., 1978, 10, 619. [all data]

Stephenson and Malanowski, 1987
Stephenson, Richard M.; Malanowski, Stanislaw, Handbook of the Thermodynamics of Organic Compounds, 1987, https://doi.org/10.1007/978-94-009-3173-2 . [all data]

Ambrose and Sprake, 1976
Ambrose, D.; Sprake, C.H.S., The vapour pressure of indane, The Journal of Chemical Thermodynamics, 1976, 8, 6, 601-602, https://doi.org/10.1016/0021-9614(76)90033-1 . [all data]

Domalski and Hearing, 1996
Domalski, Eugene S.; Hearing, Elizabeth D., Heat Capacities and Entropies of Organic Compounds in the Condensed Phase. Volume III, J. Phys. Chem. Ref. Data, 1996, 25, 1, 1, https://doi.org/10.1063/1.555985 . [all data]


Notes

Go To: Top, Condensed phase thermochemistry data, Phase change data, References