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Naphthalene, decahydro-, trans-

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Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DH - Eugene S. Domalski and Elizabeth D. Hearing

Quantity Value Units Method Reference Comment
Deltafliquid-230.7 ± 0.92kJ/molCcbSperos and Rossini, 1960ALS
Deltafliquid-228.7 ± 1.3kJ/molCcbDavies and Gilbert, 1941Reanalyzed by Cox and Pilcher, 1970, Original value = -229.6 kJ/mol; ALS
Quantity Value Units Method Reference Comment
Deltacliquid-6276.96 ± 0.92kJ/molCcbSperos and Rossini, 1960Corresponding «DELTA»fliquid = -230.6 kJ/mol (simple calculation by NIST; no Washburn corrections); ALS
Deltacliquid-6278.9 ± 1.3kJ/molCcbDavies and Gilbert, 1941Reanalyzed by Cox and Pilcher, 1970, Original value = -6277.3 ± 0.4 kJ/mol; Corresponding «DELTA»fliquid = -228.7 kJ/mol (simple calculation by NIST; no Washburn corrections); ALS
Deltacliquid-6264. ± 2.kJ/molCcbHuckel, Kamenz, et al., 1937Corresponding «DELTA»fliquid = -244. kJ/mol (simple calculation by NIST; no Washburn corrections); ALS
Deltacliquid-6255.9kJ/molCcbHuckel and Mentzel, 1926Corresponding «DELTA»fliquid = -251. kJ/mol (simple calculation by NIST; no Washburn corrections); ALS
Deltacliquid-6268.2 ± 4.6kJ/molCcbRoth and Lasse, 1925Corresponding «DELTA»fliquid = -239.4 kJ/mol (simple calculation by NIST; no Washburn corrections); ALS
Quantity Value Units Method Reference Comment
liquid264.93J/mol*KN/AMcCullough, Finke, et al., 1957DH

Constant pressure heat capacity of liquid

Cp,liquid (J/mol*K) Temperature (K) Reference Comment
229.17298.15Ohnishi, Fujihara, et al., 1989DH
229.17298.15Shiohama, Ogawa, et al., 1988DH
229.17298.15Shiohama, Ogawa, et al., 1988, 2DH
250.6313.Gudinowicz, Campbell, et al., 1963T = 313 to 423 K.; DH
228.49298.15McCullough, Finke, et al., 1957T = 10 to 350 K.; DH
226.86298.Seyer, 1953T = 293 to 413 K.; DH
217.72298.15Parks and Hatton, 1949T = 80 to 298.15 K.; DH

References

Go To: Top, Condensed phase thermochemistry data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Speros and Rossini, 1960
Speros, D.M.; Rossini, F.D., Heats of combustion and formation of naphthalene, the two methylnaphthalenes, cis and trans decahydronaphthalene and related compounds, J. Phys. Chem., 1960, 64, 1723-1727. [all data]

Davies and Gilbert, 1941
Davies, G.F.; Gilbert, E.C., The heat of combustion of cis- and trans-decahydronaphthalene, J. Am. Chem. Soc., 1941, 63, 1585-1586. [all data]

Cox and Pilcher, 1970
Cox, J.D.; Pilcher, G., Thermochemistry of Organic and Organometallic Compounds, Academic Press, New York, 1970, 1-636. [all data]

Huckel, Kamenz, et al., 1937
Huckel, W.; Kamenz, E.; Gross, A.; Tappe, W., Zur kenntnis der waldenschen umkehrung, Ann. Chim., 1937, 533, 1-45. [all data]

Huckel and Mentzel, 1926
Huckel, W.; Mentzel, R., Zur Stereochemie bicyclischer Ringsteme II. Die Stereoisomerie des Dekahydronaphtalins und seiner Derivate II. Stereoisomere «beta»-substituierte Dekaline, Ann., 1926, 451, 109-132. [all data]

Roth and Lasse, 1925
Roth, W.A.; Lasse, R., Verbrennungswarme der Dekahydro-naphthaline und der Dekalone, Ann., 1925, 441, 48-53. [all data]

McCullough, Finke, et al., 1957
McCullough, J.P.; Finke, H.L.; Messerly, J.F.; Kincheloe, T.C.; Waddington, G., The low temperature thermodynamic properties of naphthalene, 1-methylnaphthalene, 2-methylnaphthalene, 1,2,3,4-tetrahydronaphthalene, trans-decahydronaphthalene and cis-decahydronaphthalene, J. Phys. Chem., 1957, 61, 1105-1116. [all data]

Ohnishi, Fujihara, et al., 1989
Ohnishi, K.; Fujihara, I.; Murakami, S., Thermodynamic properties of decalins mixed with hexane isomers at 298.15K. 1. Excess enthalpies and excess isobaric heat capacities, Fluid Phase Equilib., 1989, 46, 59-72. [all data]

Shiohama, Ogawa, et al., 1988
Shiohama, Y.; Ogawa, H.; Murakami, S.; Fujihara, I., Excess molar isobaric heat capacities and isentropic compressibilities of (cis- or trans-decalin + benzene or toluene or iso-octane or n-heptane) at 298.15 K, J. Chem. Thermodynam., 1988, 20, 1183-1189. [all data]

Shiohama, Ogawa, et al., 1988, 2
Shiohama, Y.; Ogawa, H.; Murakami, S.; Fujihara, I., Excess thermodynamic properties of (cis-decalin or trans-decalin + cyclohexane or methylcyclohexane or cyclooctane) at 298.15 K, J. Chem. Thermodynam., 1988, 20, 1307-1314. [all data]

Gudinowicz, Campbell, et al., 1963
Gudinowicz, B.J.; Campbell, R.H.; Adams, J.S., Specific heat measurements of complex saturated hydrocarbons, J. Chem. Eng. Data, 1963, 8, 201-214. [all data]

Seyer, 1953
Seyer, W.F., The heat capacity of cis- and trans-decahydronaphthalene and the possible existence of a lambda-region for the cis form at 50.1-50.5, J. Am. Chem. Soc., 1953, 75, 616-621. [all data]

Parks and Hatton, 1949
Parks, G.S.; Hatton, J.A., Thermal data on organic compounds. XXIV. The heat capacities, entropies and free energies of cis- and trans-decahydronaphthalene, J. Am. Chem. Soc., 1949, 71, 2773-2775. [all data]


Notes

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