α-D-Glucose

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Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
DH - Eugene S. Domalski and Elizabeth D. Hearing
AC - William E. Acree, Jr., James S. Chickos

Enthalpy of fusion

ΔfusH (kJ/mol) Temperature (K) Reference Comment
31.420414.Parks and Thomas, 1934DH
31.42414.Domalski and Hearing, 1996AC
34.3423.2Schwarz, 1996AC

Entropy of fusion

ΔfusS (J/mol*K) Temperature (K) Reference Comment
75.9414.Parks and Thomas, 1934DH

Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

C6H11O6- + Hydrogen cation = α-D-Glucose

By formula: C6H11O6- + H+ = C6H12O6

Quantity Value Units Method Reference Comment
Δr1389. ± 17.kJ/molIMRBCai and Cole, 2002gas phase

Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

De-protonation reactions

C6H11O6- + Hydrogen cation = α-D-Glucose

By formula: C6H11O6- + H+ = C6H12O6

Quantity Value Units Method Reference Comment
Δr1389. ± 17.kJ/molIMRBCai and Cole, 2002gas phase

Mass spectrum (electron ionization)

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Spectrum

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Mass spectrum
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Additional Data

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Owner NIST Mass Spectrometry Data Center
Collection (C) 2014 copyright by the U.S. Secretary of Commerce
on behalf of the United States of America. All rights reserved.
Origin W.E. FRANKLIN, SOUTH. REG. RES. CENT., NEW ORLEANS, LA., USA
NIST MS number 98151

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References

Go To: Top, Phase change data, Reaction thermochemistry data, Gas phase ion energetics data, Mass spectrum (electron ionization), Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Parks and Thomas, 1934
Parks, G.S.; Thomas, S.B., The heat capacities of crystalline, glassy and undercooled liquid glucose, J. Am. Chem. Soc., 1934, 56, 1423. [all data]

Domalski and Hearing, 1996
Domalski, Eugene S.; Hearing, Elizabeth D., Heat Capacities and Entropies of Organic Compounds in the Condensed Phase. Volume III, J. Phys. Chem. Ref. Data, 1996, 25, 1, 1, https://doi.org/10.1063/1.555985 . [all data]

Schwarz, 1996
Schwarz, Frederick P., Enthalpy of solution of carbohydrates using a modified differential scanning calorimeter, J Solution Chem, 1996, 25, 5, 471-484, https://doi.org/10.1007/BF00972993 . [all data]

Cai and Cole, 2002
Cai, Y.; Cole, R.B., Stabilization of anionic adducts in negative ion electrospray mass spectrometry, Anal. Chem., 2002, 74, 5, 985-991, https://doi.org/10.1021/ac0108818 . [all data]


Notes

Go To: Top, Phase change data, Reaction thermochemistry data, Gas phase ion energetics data, Mass spectrum (electron ionization), References