Quinoline, 4-methyl-

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Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Quantity Value Units Method Reference Comment
Δfliquid94.5 ± 2.6kJ/molCcbRibeiro da Silva, Matos, et al., 1995 
Quantity Value Units Method Reference Comment
Δcliquid-5315.9 ± 2.4kJ/molCcbRibeiro da Silva, Matos, et al., 1995 

Phase change data

Go To: Top, Condensed phase thermochemistry data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
BS - Robert L. Brown and Stephen E. Stein
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny director
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DRB - Donald R. Burgess, Jr.
AC - William E. Acree, Jr., James S. Chickos

Quantity Value Units Method Reference Comment
Tboil535. ± 6.KAVGN/AAverage of 7 values; Individual data points
Quantity Value Units Method Reference Comment
Tfus282.7KN/AZegalska, 1968Uncertainty assigned by TRC = 0.2 K; TRC
Tfus282.KN/ACampbell and Schaffner, 1945Uncertainty assigned by TRC = 1.5 K; TRC
Quantity Value Units Method Reference Comment
Δvap67.6 ± 1.8kJ/molCRibeiro da Silva, Matos, et al., 1995ALS
Δvap67.6kJ/molN/ARibeiro da Silva, Matos, et al., 1995DRB
Δvap67.6 ± 1.8kJ/molCRibeiro da Silva, 1995AC

Enthalpy of vaporization

ΔvapH (kJ/mol) Temperature (K) Method Reference Comment
58.2478.A,EBStephenson and Malanowski, 1987Based on data from 463. to 539. K. See also Malanowski, 1961 and Malanowski, 1961, 2.; AC

Antoine Equation Parameters

log10(P) = A − (B / (T + C))
    P = vapor pressure (bar)
    T = temperature (K)

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Temperature (K) A B C Reference Comment
471.73 to 538.974.313941877.712-102.915Malanowski, 1961, 3Coefficents calculated by NIST from author's data.

In addition to the Thermodynamics Research Center (TRC) data available from this site, much more physical and chemical property data is available from the following TRC products:


References

Go To: Top, Condensed phase thermochemistry data, Phase change data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Ribeiro da Silva, Matos, et al., 1995
Ribeiro da Silva, M.A.V.; Matos, M.A.R.; Amaral, L.M.P.F., Thermochemical study of 2-,4-,6-, and 8-methylquinoline, J. Chem. Thermodyn., 1995, 27, 565-574. [all data]

Zegalska, 1968
Zegalska, B., Liquid-Solid Equilibria in Binary Systems Formed by Quinoline, Bull. Acad. Pol. Sci., Ser. Sci. Chim., 1968, 16, 335-41. [all data]

Campbell and Schaffner, 1945
Campbell, K.N.; Schaffner, I.J., The Preparation of 4-Methylquinolines, J. Am. Chem. Soc., 1945, 67, 86. [all data]

Ribeiro da Silva, 1995
Ribeiro da Silva, M., Thermochemical study of 2-, 4-, 6-, and 8-methylquinoline, The Journal of Chemical Thermodynamics, 1995, 27, 6, 565-574, https://doi.org/10.1006/jcht.1995.0058 . [all data]

Stephenson and Malanowski, 1987
Stephenson, Richard M.; Malanowski, Stanislaw, Handbook of the Thermodynamics of Organic Compounds, 1987, https://doi.org/10.1007/978-94-009-3173-2 . [all data]

Malanowski, 1961
Malanowski, S., Bull. Acad. Pol. Sci. Ser. Sci. Chim., 1961, 9, 83. [all data]

Malanowski, 1961, 2
Malanowski, S., Bull. Acad. Pol. Sci. Ser. Sci. Chim., 1961, 9, 71. [all data]

Malanowski, 1961, 3
Malanowski, S., Vapour Pressures and Boiling Temperatures of Some Quinoline Bases, Bull. Acad. Pol. Sci. Ser. Sci. Chim., 1961, 9, 2, 71-76. [all data]


Notes

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