1H-Cycloprop[e]azulene, 1a,2,3,4,4a,5,6,7b-octahydro-1,1,4,7-tetramethyl-, [1aR-(1aα,4α,4aβ,7bα)]-


Van Den Dool and Kratz RI, non-polar column, temperature ramp

Go To: Top, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase CP-Sil PONA GBDB-5BP-1DB-5HP-5
Column length (m) 100.30.50.30.30.
Carrier gas HeHeHe He
Substrate      
Column diameter (mm) 0.250.250.220.220.25
Phase thickness (μm) 0.250.250.250.250.25
Tstart (C) 140.60.60.60.50.
Tend (C) 230.240.220.240.250.
Heat rate (K/min) 5.3.2.3.4.
Initial hold (min) 10.  2.4.
Final hold (min) 25. 20. 10.
I 1436.1409.1412.1413.1411.
ReferenceCunicao, Lopes, et al., 2007Flamini, Cioni, et al., 2007Lesueur, de Rocca Serra, et al., 2007Martins, Santos, et al., 2007Quijano, Salamanca, et al., 2007
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase SPB-1HP-5MSHP-5MSHP-5MSDB-5
Column length (m) 30.30.30.30.30.
Carrier gas HeHeHeHeHe
Substrate      
Column diameter (mm) 0.250.250.250.250.25
Phase thickness (μm) 0.250.250.250.250.25
Tstart (C) 50.60.60.60.50.
Tend (C) 250.280.280.280.250.
Heat rate (K/min) 5.4.4.3.3.
Initial hold (min) 3.5.5.  
Final hold (min) 15.   10.
I 1400.1409.1409.1408.1407.
ReferenceRadulovic, Lazarevic, et al., 2007Radulovic, Lazarevic, et al., 2007Saroglou, Marin, et al., 2007Vagionas, Ngassapa, et al., 2007Yu, Liao, et al., 2007
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase HP-5MSDB-5DB-5SPB-1DB-5
Column length (m) 30.30.30.30.30.
Carrier gas HeHeHeHeHe
Substrate      
Column diameter (mm) 0.250.250.250.250.2
Phase thickness (μm) 0.250.250.250.250.25
Tstart (C) 80.60.60.50.50.
Tend (C) 300.240.240.250.250.
Heat rate (K/min) 4.3.3.5.5.
Initial hold (min)  2.2.3.3.
Final hold (min)    15.15.
I 1409.1408.1408.1400.1409.
ReferenceZeng, Zhao, et al., 2007Batista-Pereira, Fernandes, et al., 2006Batista-Pereira, Fernandes, et al., 2006Blagojevic, Radulovic, et al., 2006Blagojevic, Radulovic, et al., 2006
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase DB-5BP-1HP-5HP-5HP-5
Column length (m) 30.50.30.30.30.
Carrier gas N2HeN2HeHe
Substrate      
Column diameter (mm) 0.320.220.250.250.25
Phase thickness (μm) 0.250.250.250.250.25
Tstart (C) 60.60.60.60.60.
Tend (C) 240.220.220.250.260.
Heat rate (K/min) 3.2.5.3.3.
Initial hold (min) 3. 10.  
Final hold (min) 5.20.   
I 1411.1412.1408.1410.1407.
ReferenceDob, Dahmane, et al., 2006Duquesnoy, Dinh, et al., 2006Flamini, Tebano, et al., 2006Javidnia, Miri, et al., 2006Javidnia K., Miri R., et al., 2006
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase HP-5MSSPB-1SPB-1HP-5MSHP-5MS
Column length (m) 30.30.30.30.30.
Carrier gas HeHeHeHeHe
Substrate      
Column diameter (mm) 0.250.250.20.250.25
Phase thickness (μm) 0.250.250.20.250.25
Tstart (C) 60.50.70.60.60.
Tend (C) 280.250.220.280.300.
Heat rate (K/min) 3.5.3.4.3.
Initial hold (min)  3. 5. 
Final hold (min)  15.15.  
I 1381.1402.1402.1424.1425.
ReferencePavlovic, Kovacevic, et al., 2006Radulovic, Mananjarasoa, et al., 2006Salgueiro L.R., Pinto E., et al., 2006Saroglou, Dorizas, et al., 2006Silva-Brandão, Solferini, et al., 2006
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase DB-5HP-5HP-5HP-5HP-5MS
Column length (m) 30.30.30.30.30.
Carrier gas HeN2N2HeHe
Substrate      
Column diameter (mm) 0.250.250.250.250.25
Phase thickness (μm) 0.250.250.25 0.25
Tstart (C) 50.60.60.60.60.
Tend (C) 250.220.220.260.250.
Heat rate (K/min) 5.5.5.3.4.
Initial hold (min) 2.10.10. 2.
Final hold (min)     20.
I 1410.1408.1409.1409.1407.
ReferenceSu, Ho, et al., 2006Celik, Gokturk, et al., 2005Flamini, Luigi Cioni, et al., 2005Javidnia, Miri, et al., 2005Pino, Mesa, et al., 2005
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase DB-5HP-5MSSPB-1SPB-1HP-1
Column length (m) 30.30.30.30.25.
Carrier gas HeHeHeHeHe
Substrate      
Column diameter (mm) 0.250.250.250.20.32
Phase thickness (μm) 0.260.250.250.20.17
Tstart (C) 60.60.70.70.50.
Tend (C) 210.280.220.220.200.
Heat rate (K/min) 3.3.3.3.3.
Initial hold (min)      
Final hold (min)   15.15. 
I 1407.1404.1402.1401.1393.
ReferenceSati and Mathela, 2005Aligiannis, Kalpoutzakis, et al., 2004Antunes, Sevinate-Pinto, et al., 2004Cavaleiro, Salgueiro, et al., 2004Fernández-Ocaña, Gómez-Rodríguez, et al., 2004
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase HP-5HP-5HP-5MSBP-1DB-5
Column length (m) 30.30.30.50.30.
Carrier gas HeHeHeHeHe
Substrate      
Column diameter (mm) 0.250.250.250.220.25
Phase thickness (μm) 0.250.250.250.250.25
Tstart (C) 50.60.60.60.60.
Tend (C) 290.260.280.220.240.
Heat rate (K/min) 4.3.4.2.3.
Initial hold (min)   5.  
Final hold (min)    20.30.
I 1410.1409.1409.1411.1409.
ReferenceFlach A., Dondon R.C., et al., 2004Javidnia, Miri, et al., 2004Karioti, Hadjipavlou-Litina, et al., 2004Tam, Thuam, et al., 2004Bader, Caponi, et al., 2003
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase HP-5RTX-1Ultra-2HP-5DB-1
Column length (m) 30.60.25.30.30.
Carrier gas HeHeH2N2He
Substrate      
Column diameter (mm) 0.250.220.250.250.25
Phase thickness (μm) 0.250.250.330.250.25
Tstart (C) 60.60.40.60.40.
Tend (C) 280.230.280.220.250.
Heat rate (K/min) 3.2.3.5.2.
Initial hold (min)   2.10.5.
Final hold (min)  45.10. 20.
I 1409.1410.1409.1410.1392.
ReferenceBougatsos, Meyer, et al., 2003Cavalli, Tomi, et al., 2003Ceva-Antunes, Bizzo, et al., 2003Dural, Bagci, et al., 2003de Feo, Bruno, et al., 2003
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase HP-5DB-5HP-5RTX-5HP-5
Column length (m) 30.30.30.30.30.
Carrier gas  HeHeHeHe
Substrate      
Column diameter (mm) 0.250.250.250.250.25
Phase thickness (μm)  0.250.250.250.25
Tstart (C) 25.75.60.45.60.
Tend (C) 150.230.280.250.280.
Heat rate (K/min) 3.3.4.3.4.
Initial hold (min) 5.10.5.6.5.
Final hold (min)  20.   
I 1412.1406.1409.1412.1409.
ReferenceIsidorov, Vinogorova, et al., 2003Jantan, Ling, et al., 2003Karioti, Skaltsa, et al., 2003Shellie, Marriott, et al., 2003Skaltsa, Demetzos, et al., 2003
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase HP-5SPB-1HP-5MSHP-5MSHP-5
Column length (m) 30.30.30.30.30.
Carrier gas HeHeHe  
Substrate      
Column diameter (mm) 0.250.200.250.250.25
Phase thickness (μm) 0.250.200.250.250.25
Tstart (C) 60.70.60.50.60.
Tend (C) 280.220.300.280.280.
Heat rate (K/min) 3.3.3.3.3.
Initial hold (min)    5.5.
Final hold (min)  15.   
I 1410.1404.1409.1409.1408.
ReferenceTsiri, Kretsi, et al., 2003Cavaleiro, Salgueiro, et al., 2002Couladis, Chinou, et al., 2002Demetzos, Angelopoulou, et al., 2002Fokialakis, Magiatis, et al., 2002
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase DB-5HP-5CP Sil 5 CBCP Sil 5 CBHP-5
Column length (m) 30.30.25.30.30.
Carrier gas HeHeN2H2He
Substrate      
Column diameter (mm) 0.250.250.250.250.25
Phase thickness (μm) 0.250.250.250.250.25
Tstart (C) 60.60.60.60.60.
Tend (C) 260.280.280.280.280.
Heat rate (K/min) 4.3.4.2.3.
Initial hold (min)   6.10.5.
Final hold (min)    40. 
I 1409.1402.1401.1401.1406.
ReferenceJavidnia, Miri, et al., 2002Kovacevic, Pavlovic, et al., 2002Pino, Marbot, et al., 2002Pino, Marbot, et al., 2002, 2Aligiannis, Kalpoutzakis, et al., 2001
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase HP-5MSRTX-5 MSDB-5CP Sil 5 CBHP-5MS
Column length (m) 30.30.30.50.30.
Carrier gas HeHeH2HeHe
Substrate      
Column diameter (mm) 0.250.250.250.320.25
Phase thickness (μm) 0.250.250.250.40.25
Tstart (C) 60.70.60.60.60.
Tend (C) 280.210.240.280.280.
Heat rate (K/min) 3.4.3.3.4.
Initial hold (min) 5.10. 10.5.
Final hold (min)  10. 60. 
I 1409.1394.1410.1405.1409.
ReferenceGiamakis, Kretsi, et al., 2001Hudaib, Grazia Bellardi, et al., 2001Nogueira, Bittrich, et al., 2001Pino, Marbot, et al., 2001Skaltsa, Mavrommati, et al., 2001
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase BPX-5DB-5DB-5OV-101CBP-1
Column length (m) 50.30.30.25.30.
Carrier gas H2HeHeN2He
Substrate      
Column diameter (mm) 0.220.250.250.250.25
Phase thickness (μm) 0.250.250.25  
Tstart (C) 60.60.60.50.60.
Tend (C) 180.240.240.200.240.
Heat rate (K/min) 4.3.3.5.4.
Initial hold (min) 5.2.2.  
Final hold (min) 5.    
I 1422.1408.1411.1411.1406.
ReferenceZabaras and Wyllie, 2001Maia, de Paula, et al., 2000Maia, de Paula, et al., 2000Menut, Bessiere, et al., 2000Zunino, Lopez, et al., 2000
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase HP-5DB-1HP-1CP Sil 5 CBOV-1
Column length (m) 30.60.60.25.25.
Carrier gas HeHeHeHe 
Substrate      
Column diameter (mm) 0.250.250.250.250.25
Phase thickness (μm) 0.250.250.25 0.3
Tstart (C) 50.50.50.60.50.
Tend (C) 280.220.250.260.200.
Heat rate (K/min) 4.4.2.55.3.
Initial hold (min) 5. 5. 1.
Final hold (min)     20.
I 1403.1420.1422.1412.1393.
ReferenceLazari, Skaltsa, et al., 1999Mirza and Sefidkon, 1999Stashenko, Cervantes, et al., 1999Weyerstahl, Marschall, et al., 1999Bicchi, Rubiolo, et al., 1998
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillary
Active phase HP-5BP-1BP-1Methyl Silicone
Column length (m)  50.50.25.
Carrier gas HeHeHeHe
Substrate     
Column diameter (mm) 0.260.220.220.2
Phase thickness (μm) 0.250.250.250.3
Tstart (C) 60.60.60.40.
Tend (C) 240.230.230.200.
Heat rate (K/min) 3.2.2.2.
Initial hold (min)     
Final hold (min)  35.35. 
I 1409.1420.1409.1425.
ReferenceOprean, Tamas, et al., 1998Mariotti, Costa, et al., 1997Mariotti, Tomi, et al., 1997Píry, Príbela, et al., 1995
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI

References

Go To: Top, Van Den Dool and Kratz RI, non-polar column, temperature ramp, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Cunicao, Lopes, et al., 2007
Cunicao, M.M.; Lopes, A.R.; Côcco, L.C.; Yamamoto, C.I.; Plocharski, R.C.B.; Miguel, M.D.; Junior, A.G.; Auer, C.G.; Miguel, O.G., Phytochemical and antibacterial evaluation of essential oils from Ottonia Martiana Miq. (Piperaceae), J. Braz. Chem. Soc., 2007, 18, 1, 184-188, https://doi.org/10.1590/S0103-50532007000100021 . [all data]

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Notes

Go To: Top, Van Den Dool and Kratz RI, non-polar column, temperature ramp, References