Retrorsine
- Formula: C18H25NO6
- Molecular weight: 351.3942
- IUPAC Standard InChI: InChI=1S/C18H25NO6/c1-3-12-8-11(2)18(23,10-20)17(22)24-9-13-4-6-19-7-5-14(15(13)19)25-16(12)21/h3-4,11,14-15,20,23H,5-10H2,1-2H3/b12-3-/t11-,14-,15-,18-/m1/s1
- IUPAC Standard InChIKey: BCJMNZRQJAVDLD-CQRYIUNCSA-N
- CAS Registry Number: 480-54-6
- Chemical structure:
This structure is also available as a 2d Mol file - Stereoisomers:
- Other names: Retrosine; [1,6]Dioxacyclododecino[2,3,4-gh]pyrrolizine-2,7-dione, 3-ethylidene-3,4,5,6,9,11,13,14,14a,14b-decahydro-6-hydroxy-6-(hydroxymethyl)-5-methyl-, (3Z,5R,6S,14aR,14bR)-; 12,18-Dihydroxysenecionan-11,16-dione
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- Other data available:
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Normal alkane RI, non-polar column, temperature ramp
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director
| Column type | Capillary | Capillary |
|---|---|---|
| Active phase | OV-1 | OV-1 |
| Column length (m) | 30. | 30. |
| Carrier gas | Helium | He |
| Substrate | ||
| Column diameter (mm) | 0.25 | 0.32 |
| Phase thickness (μm) | 0.25 | 0.25 |
| Tstart (C) | 100. | 70. |
| Tend (C) | 300. | 300. |
| Heat rate (K/min) | 6. | 6. |
| Initial hold (min) | 3. | |
| Final hold (min) | ||
| I | 2548. | 2548. |
| Reference | Asres, Sporer, et al., 2008 | Woldemichael and Wink, 2002 |
| Comment | MSDC-RI | MSDC-RI |
References
Go To: Top, Normal alkane RI, non-polar column, temperature ramp, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Asres, Sporer, et al., 2008
Asres, K.; Sporer, F.; Wink, M.,
Occurence of pyrrolizidine alkaloids in three Ethiopian Solanecio species,
Biochem. Systematics and Ecology, 2008, 36, 5-6, 399-407, https://doi.org/10.1016/j.bse.2007.10.003
. [all data]
Woldemichael and Wink, 2002
Woldemichael, G.M.; Wink, M.,
Concomitant occurrence of pyrrolizidine and quinolizidine alkaloids in hemiparasite Osyris alba L. (Santalaceae),
Biochem. Syst. Ecol., 2002, 30, 2, 139-149, https://doi.org/10.1016/S0305-1978(01)00065-5
. [all data]
Notes
Go To: Top, Normal alkane RI, non-polar column, temperature ramp, References
- Symbols used in this document:
Tend Final temperature Tstart Initial temperature - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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