Bicyclo[2.2.1]heptan-2-ol, 2,3,3-trimethyl-
- Formula: C10H18O
- Molecular weight: 154.2493
- IUPAC Standard InChI: InChI=1S/C10H18O/c1-9(2)7-4-5-8(6-7)10(9,3)11/h7-8,11H,4-6H2,1-3H3
- IUPAC Standard InChIKey: PXRCIOIWVGAZEP-UHFFFAOYSA-N
- CAS Registry Number: 465-31-6
- Chemical structure:
This structure is also available as a 2d Mol file or as a computed 3d SD file
The 3d structure may be viewed using Java or Javascript. - Stereoisomers:
- Other names: Camphene hydrate; Camphenilanol, 3-methyl-; 3-Methylcamphenilol; 2-Norbornanol; 3-Methylcamphenilanol; Methyl camphenilol; 2,3,3-Trimethylbicyclo[2.2.1]heptan-2-ol
- Permanent link for this species. Use this link for bookmarking this species for future reference.
- Information on this page:
- Other data available:
- Options:
Normal alkane RI, non-polar column, temperature ramp
Go To: Top, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director
| Column type | Capillary | Capillary | Capillary | Capillary | Capillary |
|---|---|---|---|---|---|
| Active phase | RTX-1 | DB-5 | DB-5 | DB-5 | 5 % Phenyl methyl siloxane |
| Column length (m) | 60. | 30. | 30. | 30. | 60. |
| Carrier gas | Helium | Helium | Helium | Helium | Helium |
| Substrate | |||||
| Column diameter (mm) | 0.22 | 0.25 | 0.25 | 0.25 | 0.25 |
| Phase thickness (μm) | 0.25 | 0.25 | 0.25 | 0.25 | 0.25 |
| Tstart (C) | 60. | 50. | 50. | 70. | 90. |
| Tend (C) | 230. | 250. | 250. | 240. | 225. |
| Heat rate (K/min) | 2. | 2. | 5. | 5. | 3. |
| Initial hold (min) | 2. | ||||
| Final hold (min) | 45. | 3. | |||
| I | 1128. | 1150. | 1150. | 1147. | 1147. |
| Reference | Yapi, Boti, et al., 2012 | Ho, Wang, et al., 2010 | Ho, Wang, et al., 2009 | Lawal and Oyedelji, 2009 | Retta, Gattuso, et al., 2009 |
| Comment | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI |
| Column type | Capillary | Capillary | Capillary | Capillary | Capillary |
|---|---|---|---|---|---|
| Active phase | SLB-5 MS | Elite-1 | HP-5 | HP-5 MS | HP-5MS |
| Column length (m) | 30. | 30. | 30. | 30. | 30. |
| Carrier gas | Helium | Helium | Nitrogen | Helium | He |
| Substrate | |||||
| Column diameter (mm) | 0.25 | 0.32 | 0.25 | 0.25 | 0.25 |
| Phase thickness (μm) | 0.25 | 0.25 | 0.25 | 0.25 | 0.25 |
| Tstart (C) | 50. | 60. | 50. | 50. | 60. |
| Tend (C) | 250. | 246. | 280. | 230. | 280. |
| Heat rate (K/min) | 3. | 3. | 5. | 3. | 3. |
| Initial hold (min) | 2. | 1. | 10. | ||
| Final hold (min) | 10. | 1. | 10. | ||
| I | 1155. | 1152. | 1147. | 1148. | 1148. |
| Reference | Lo Presti, Sciarrone, et al., 2008 | Raj, Baby, et al., 2008 | Saidana, Mahjoub, et al., 2008 | Adams, Beauchamp, et al., 2007 | Bozin B., Mlmica-Dukic N., et al., 2007 |
| Comment | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI |
| Column type | Capillary | Capillary | Capillary | Capillary | Capillary |
|---|---|---|---|---|---|
| Active phase | HP-5 | HP-1 | DB-5 | DB-5 | HP-5MS |
| Column length (m) | 30. | 50. | 30. | 30. | 30. |
| Carrier gas | N2 | He | He | He | He |
| Substrate | |||||
| Column diameter (mm) | 0.25 | 0.2 | 0.25 | 0.25 | 0.25 |
| Phase thickness (μm) | 0.25 | 0.33 | 0.25 | 0.25 | 0.25 |
| Tstart (C) | 50. | 60. | 60. | 60. | 60. |
| Tend (C) | 240. | 250. | 200. | 260. | 280. |
| Heat rate (K/min) | 5. | 2. | 2. | 5. | 3. |
| Initial hold (min) | 1. | 5. | |||
| Final hold (min) | 4. | 40. | 60. | ||
| I | 1148. | 1129. | 1151. | 1154. | 1147. |
| Reference | Cheraif, Ben Jannet, et al., 2007 | Filippi, Lanfranchi, et al., 2006 | Rout, Naik, et al., 2006 | Sabulal, Dan, et al., 2006 | Setzer, Noletto, et al., 2005 |
| Comment | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI |
| Column type | Capillary | Capillary | Capillary | Capillary | Capillary |
|---|---|---|---|---|---|
| Active phase | BP-1 | CP Sil 5 CB | DB-5 | HP-5 | ZEBRON-5 |
| Column length (m) | 50. | 25. | 30. | 30. | 6. |
| Carrier gas | He | He | He | He | |
| Substrate | |||||
| Column diameter (mm) | 0.22 | 0.25 | 0.25 | 0.25 | 0.25 |
| Phase thickness (μm) | 0.25 | 0.25 | 0.25 | 0.25 | 0.25 |
| Tstart (C) | 60. | 35. | 60. | 60. | 40. |
| Tend (C) | 220. | 280. | 280. | 280. | 200. |
| Heat rate (K/min) | 2. | 5. | 3. | 3. | 3. |
| Initial hold (min) | 2.5 | 5. | |||
| Final hold (min) | 20. | 30. | 15. | ||
| I | 1133. | 1127. | 1141. | 1135. | 1112. |
| Reference | Blanc, Muselli, et al., 2004 | Kanjilal, Kotoky, et al., 2003 | Marongiu, Porcedda, et al., 2003 | Pitarokili, Tzakou, et al., 2003 | Öztürk, Akay, et al., 2002 |
| Comment | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI |
| Column type | Capillary | Capillary | Capillary | Capillary | Capillary |
|---|---|---|---|---|---|
| Active phase | DB-1 | DB-1 | DB-5 | DB-1 | CP Sil 5 CB |
| Column length (m) | 50. | 50. | 30. | 30. | 25. |
| Carrier gas | N2 | N2 | He | He | |
| Substrate | |||||
| Column diameter (mm) | 0.25 | 0.25 | 0.25 | 0.32 | 0.25 |
| Phase thickness (μm) | 0.25 | 0.25 | 0.25 | 0.25 | |
| Tstart (C) | 80. | 60. | 60. | 45. | 50. |
| Tend (C) | 225. | 240. | 240. | 300. | 230. |
| Heat rate (K/min) | 4. | 3. | 3. | 15. | 3. |
| Initial hold (min) | 2. | ||||
| Final hold (min) | 5. | ||||
| I | 1132. | 1128. | 1150. | 1185. | 1128. |
| Reference | Palá-Paúl, Pérez-Alonso, et al., 2002 | Velasco-Negueruela, Pérez-Alonso, et al., 2002 | Zoghbi, Andrade, et al., 2002 | Hedin, McKibben, et al., 2000 | Oyedeji, Olawore, et al., 1999 |
| Comment | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI |
| Column type | Capillary | Capillary | Capillary | Capillary |
|---|---|---|---|---|
| Active phase | DB-5MS | OV-101 | HP-1 | DB-1 |
| Column length (m) | 30. | 50. | 25. | 60. |
| Carrier gas | He | He | Helium | He |
| Substrate | ||||
| Column diameter (mm) | 0.25 | 0.25 | 0.32 | 0.25 |
| Phase thickness (μm) | 0.25 | 0.25 | 0.25 | |
| Tstart (C) | 60. | 50. | 60. | 80. |
| Tend (C) | 240. | 250. | 220. | 210. |
| Heat rate (K/min) | 3. | 2. | 4. | 3. |
| Initial hold (min) | 2. | |||
| Final hold (min) | 20. | |||
| I | 1147. | 1130. | 1127. | 1152. |
| Reference | Zoghbi, Andrade, et al., 1999 | Orav, Kailas, et al., 1996 | Thanh, Dung, et al., 1996 | Nishimura, 1995 |
| Comment | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI |
References
Go To: Top, Normal alkane RI, non-polar column, temperature ramp, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
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Essential oil compositions and bioactivities of the various parts of Cinnamomum camphora Sieb. var. linallolifera Fujuta,
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Lawal and Oyedelji, 2009
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Chemical composition of the essential oils of Cyperus rotundus L. from South Africa,
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Lo Presti, Sciarrone, et al., 2008
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Volatile constituents from the rhisomes of Curcuma haritha Mangaly and Sabu from Sauthern India,
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New Natural Products Isolated from One-Seeded Juniperus of the Southwestern United States: Isolation and Occurence of 2-Ethenyl-3-methyl Phanol and Its Derivatives,
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Notes
Go To: Top, Normal alkane RI, non-polar column, temperature ramp, References
- Symbols used in this document:
Tend Final temperature Tstart Initial temperature - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
- The National Institute of Standards and Technology (NIST) uses its best efforts to deliver a high quality copy of the Database and to verify that the data contained therein have been selected on the basis of sound scientific judgment. However, NIST makes no warranties to that effect, and NIST shall not be liable for any damage that may result from errors or omissions in the Database.
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