(+)-2-Bornanone

• Formula: C₁₀H₁₆O
• Molecular weight: 152.2334
• IUPAC Standard InChI: InChI=1S/C10H16O/c1-9(2)7-4-5-10(9,3)8(11)6-7/h7H,4-6H2,1-3H3 Copy

  
• IUPAC Standard InChIKey: DSSYKIVIOFKYAU-UHFFFAOYSA-N Copy
• CAS Registry Number: 464-49-3
• Chemical structure:
  This structure is also available as a 2d Mol file or as a computed 3d SD file
  The 3d structure may be viewed using Java or Javascript.
• Species with the same structure:
  • 1,7,7-Trimethylbicyclo[2.2.1]heptan-2-one
  • Camphor
  • Bicyclo[2.2.1]heptan-2-one, 1,7,7-trimethyl-, (1S)-
  • Camphor
• Stereoisomers:
  • ( S)-camphor
• Other names: Bicyclo[2.2.1]heptan-2-one, 1,7,7-trimethyl-, (1R)-; Camphor, (1R,4R)-(+)-; Alcanfor; d-2-Bornanone; d-2-Camphanone; Camphor, (+)-; (+)-Camphor; d-Camphor; D-(+)-Camphor; Camphor USP; Japanese camphor; (1R)-(+)-Camphor; 1,7,7-Trimethylbicyclo[2.2.1]heptan-2-one, (1R)-; 1,7,7-trimethylbicyclo[2.2.1]-2-heptanone, (1R)-; Camphor (D); (1R)-Camphor; (1R,4R)-1,7,7-Trimethylbicyclo[2.2.1]heptan-2-one; (R)-(+)-Camphor; (R)-Camphor; 1,7,7-trimethylbicyclo[2.2.1]-2-heptanone (camphor); 1,7,7-trimethyl-bicyclo-[2,2,1]heptane-2-one; (+)-bornan-2-one
• Information on this page:
  • Phase change data
  • Gas Chromatography
  • References
  • Notes
• Other data available:
  • Condensed phase thermochemistry data
  • Mass spectrum (electron ionization)
• Options:
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Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny director
AC - William E. Acree, Jr., James S. Chickos
DH - Eugene S. Domalski and Elizabeth D. Hearing

Enthalpy of fusion

Temperature of phase transition

Enthalpy of phase transition

Entropy of phase transition

Gas Chromatography

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Van Den Dool and Kratz RI, non-polar column, temperature ramp

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Van Den Dool and Kratz RI, non-polar column, custom temperature program

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Van Den Dool and Kratz RI, polar column, temperature ramp

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Van Den Dool and Kratz RI, polar column, custom temperature program

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Normal alkane RI, non-polar column, custom temperature program

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Normal alkane RI, polar column, temperature ramp

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References

Go To: Top, Phase change data, Gas Chromatography, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Andersson and Ross, 1992
Andersson, O.; Ross, R.G., Thermal conductivity of (+)- and (±)-camphor at pressures up to 0.5 GPa and temperatures down to 40 K, Mol. Phys., 1992, 76, 433-44. [all data]

Donnelly, Drewes, et al., 1990
Donnelly, J.R.; Drewes, L.A.; Johnson, R.L.; Munslow, W.D.; Knapp, K.K.; Sovocool, G.W., Purity and heat of fusion data for environmental standards as determined by differential scanning calorimetry, Thermochim. Acta, 1990, 167, 2, 155, https://doi.org/10.1016/0040-6031(90)80476-F . [all data]

Mjojo, 1979
Mjojo, C.C., Order-disorder phenomena: part 2. order-disorder phase equilibria in d-and l-systems of camphor and related compounds., J. Chem. Soc., Faraday Trans. 2, 1979, 75, 692-703. [all data]

van Roon, Parsons, et al., 2002
van Roon, André; Parsons, John R.; Govers, Harrie A.J., Gas chromatographic determination of vapour pressure and related thermodynamic properties of monoterpenes and biogenically related compounds, Journal of Chromatography A, 2002, 955, 1, 105-115, https://doi.org/10.1016/S0021-9673(02)00200-5 . [all data]

Mjojo, 1979, 2
Mjojo, Chodziwadziwa C., Order?disorder phenomena. Part 2.?Order?disorder phase equilibria in D- and L-systems of camphor and related compounds, J. Chem. Soc., Faraday Trans. 2, 1979, 75, 692, https://doi.org/10.1039/f29797500692 . [all data]

Nagumo, Matsuo, et al., 1989
Nagumo, T.; Matsuo, T.; Suga, H., Thermodynamic study on camphor crystals, Thermochim. Acta, 1989, 139, 121-132. [all data]

Schfer, 1953
Schfer, K., Fenomenos de orden y desorden en solidos, An. R. Soc. Esp. Fis. Quim. Ser., 1953, B 49, 161-174. [all data]

White and Morgan, 1935
White, A.H.; Morgan, S.O., Transitions in camphor and chemically related compounds. II. Vibration of atomic groups, J. Am. Chem. Soc., 1935, 57, 2078-2086. [all data]

Song, Sawamura, et al., 2000
Song, H.S.; Sawamura, M.; Ito, T.; Kawashimo, K.; Ukeda, H., Quantitative determination of characteric flavour of Citrus junos (yuzu) peel oil, Flavour Fragr. J., 2000, 15, 4, 245-250, https://doi.org/10.1002/1099-1026(200007/08)15:4<245::AID-FFJ904>3.0.CO;2-V . [all data]

Wang, Finn, et al., 2005
Wang, Y.; Finn, C.; Qian, M.C., Impact of Growing Environment on Chickasaw Blackberry ( Rubus L.) Aroma Evaluated by Gas Chromatography Olfactometry Dilution Analysis, J. Agric. Food Chem., 2005, 53, 9, 3563-3571, https://doi.org/10.1021/jf048102m . [all data]

Choi, 2005
Choi, H.-S., Characteristic odor components of kumquat (Fortunella japonica Swingle) peel oil, J. Agric. Food Chem., 2005, 53, 5, 1642-1647, https://doi.org/10.1021/jf040324x . [all data]

Choi and Sawamura, 2000
Choi, H.-S.; Sawamura, M., Composition of the essential oil of Citrus tamurana Hort. ex Tanaka (Hyuganatsu), J. Agric. Food Chem., 2000, 48, 10, 4868-4873, https://doi.org/10.1021/jf000651e . [all data]

Purushothaman and Ravi, 2013
Purushothaman, D.N.; Ravi, S., GC-MS analusis of essential oil obtained from Heracleum candolleanum (Wight et Arn), J. Pharmacy Res., 2013, 6, 1, 155-157, https://doi.org/10.1016/j.jopr.2012.11.032 . [all data]

Huang, Qin, et al., 2009
Huang, B.; Qin, L.; Chu, Q.; Zhang, Q.; Gao, L.; Zheng, H., Comparison of headspace SPME with hydrodistillation and SFE for analysis of the volatile components of the roots of Valeriana officinalis var. latifolia, Chromatographia, 2009, 69, 5/6, 489-496, https://doi.org/10.1365/s10337-008-0921-y . [all data]

Choi, 2004
Choi, H.-S., Aroma evaluation of an aquatic herb, changpo (Acorus calamus Var. angustatus Bess), by AEDA and SPME, J. Agric. Food Chem., 2004, 52, 26, 8099-8104, https://doi.org/10.1021/jf040239p . [all data]

Tu, Thanh, et al., 2002
Tu, N.T.M.; Thanh, L.X.; Une, A.; Ukeda, H.; Sawamura, M., Volatile constituents of Vietnamese pummelo, orange, tangerine and lime peel oils, Flavour Fragr. J., 2002, 17, 3, 169-174, https://doi.org/10.1002/ffj.1076 . [all data]

Notes

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• Symbols used in this document:
  

  Tfus	Fusion (melting) point
  Ttrs	Temperature of phase transition
  ΔHtrs	Enthalpy of phase transition
  ΔStrs	Entropy of phase transition
  ΔfusH	Enthalpy of fusion
  ΔvapH°	Enthalpy of vaporization at standard conditions

• Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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