Resorcinol, 2TMS derivative
- Formula: C12H22O2Si2
- Molecular weight: 254.4729
- IUPAC Standard InChI: InChI=1S/C12H22O2Si2/c1-15(2,3)13-11-8-7-9-12(10-11)14-16(4,5)6/h7-10H,1-6H3
- IUPAC Standard InChIKey: YFESIIOSRMXYCF-UHFFFAOYSA-N
- CAS Registry Number: 4520-29-0
- Chemical structure:
This structure is also available as a 2d Mol file or as a computed 3d SD file
The 3d structure may be viewed using Java or Javascript. - Other names: 1,3-Bis(trimethylsiloxy)benzene; Silane, [1,3-phenylenebis(oxy)]bis[trimethyl-; 1,3-Dihydroxybenzene, bisTMS ether; Resorcinol, bis(trimethylsilyl) ether; Trimethyl(3-[(trimethylsilyl)oxy]phenoxy)silane; Resorcinol, TMS; 1,3-Dihydroxybenzene, TMS; 1,3-Benzenediol, bis-trimethylsilyl ether
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Mass spectrum (electron ionization)
Go To: Top, Gas Chromatography, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director
Spectrum
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Additional Data
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| Owner | NIST Mass Spectrometry Data Center Collection (C) 2014 copyright by the U.S. Secretary of Commerce on behalf of the United States of America. All rights reserved. |
|---|---|
| Origin | NIST Mass Spectrometry Data Center |
| NIST MS number | 352781 |
Gas Chromatography
Go To: Top, Mass spectrum (electron ionization), References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director
Van Den Dool and Kratz RI, non-polar column, temperature ramp
| Column type | Active phase | I | Reference | Comment |
|---|---|---|---|---|
| Capillary | DB-5 | 1389. | Jaroszynska and Ligor, 2005 | 30. m/0.25 mm/0.25 μm, He, 3. K/min; Tstart: 50. C; Tend: 320. C |
| Capillary | DB-5 | 1389. | Jaroszynska and Ligor, 2005 | 30. m/0.25 mm/0.25 μm, He, 3. K/min; Tstart: 50. C; Tend: 320. C |
| Capillary | DB-5 | 1390. | Jaroszynska and Ligor, 2005 | 30. m/0.25 mm/0.25 μm, He, 3. K/min; Tstart: 50. C; Tend: 320. C |
| Capillary | PE-5ht | 1386. | Jaroszynska and Ligor, 2005 | 30. m/0.25 mm/0.1 μm, He, 3. K/min; Tstart: 50. C; Tend: 320. C |
| Capillary | PE-5ht | 1387. | Jaroszynska and Ligor, 2005 | 30. m/0.25 mm/0.1 μm, He, 3. K/min; Tstart: 50. C; Tend: 320. C |
| Capillary | PE-5ht | 1389. | Jaroszynska and Ligor, 2005 | 30. m/0.25 mm/0.1 μm, He, 3. K/min; Tstart: 50. C; Tend: 320. C |
| Capillary | PE-5ms | 1378. | Jaroszynska and Ligor, 2005 | 30. m/0.25 mm/0.25 μm, He, 3. K/min; Tstart: 50. C; Tend: 320. C |
| Capillary | DB-5 | 1389. | Jaroszynska, 2003 | 30. m/0.25 mm/0.25 μm, He, 3. K/min; Tstart: 50. C; Tend: 240. C |
| Capillary | DB-5 | 1390. | Jaroszynska, 2003 | 30. m/0.25 mm/0.25 μm, He, 3. K/min; Tstart: 50. C; Tend: 240. C |
| Capillary | DB-5 | 1388. | Jaroszynska, 2003 | 30. m/0.25 mm/0.25 μm, He, 7. K/min; Tstart: 50. C; Tend: 240. C |
| Capillary | DB-5 | 1390. | Jaroszynska, 2003 | 30. m/0.25 mm/0.25 μm, He, 7. K/min; Tstart: 50. C; Tend: 240. C |
| Packed | OV-1 | 1378. | Mattsson and Petersson, 1977 | N2, Supelcoport, 4. K/min; Column length: 2. m; Tstart: 80. C; Tend: 240. C |
Van Den Dool and Kratz RI, non-polar column, custom temperature program
| Column type | Active phase | I | Reference | Comment |
|---|---|---|---|---|
| Capillary | VF-5MS | 1376.5 | Tret'yakov, 2008 | 30. m/0.25 mm/0.25 μm, He; Program: Multi-step temperature program; T(initial)=60C; T(final)=270C |
Normal alkane RI, non-polar column, temperature ramp
| Column type | Active phase | I | Reference | Comment |
|---|---|---|---|---|
| Capillary | HP-5 | 1390. | Isidorov, Kotowska, et al., 2005 | 30. m/0.25 mm/0.25 μm, He, 5. K/min; Tstart: 50. C; Tend: 300. C |
Normal alkane RI, non-polar column, custom temperature program
| Column type | Active phase | I | Reference | Comment |
|---|---|---|---|---|
| Capillary | SE-30 | 1378. | Zimmermann, Lauterbach, et al., 1985 | Program: not specified |
References
Go To: Top, Mass spectrum (electron ionization), Gas Chromatography, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Jaroszynska and Ligor, 2005
Jaroszynska, J.; Ligor, T.,
The identification of phenolic compounds by a gas chromatographic method on three capillary columns with the same non-polar stationary phase,
Anal. Chim. Acta., 2005, 539, 1-2, 11-15, https://doi.org/10.1016/j.aca.2005.03.024
. [all data]
Jaroszynska, 2003
Jaroszynska, J.,
Isolation of free phenolic compounds from arboreal leaves by use of the Florisil/C18 system,
Anal. Bioanal. Chem., 2003, 377, 4, 702-708, https://doi.org/10.1007/s00216-003-2155-z
. [all data]
Mattsson and Petersson, 1977
Mattsson, M.; Petersson, G.,
Reference GLC Data for the Analysis of Phenolic Compounds as Trimethylsilyl Derivatives,
J. Chromatogr. Sci., 1977, 15, 12, 546-554, https://doi.org/10.1093/chromsci/15.12.546
. [all data]
Tret'yakov, 2008
Tret'yakov, K.V.,
Retention Data. NIST Mass Spectrometry Data Center., NIST Mass Spectrometry Data Center, 2008. [all data]
Isidorov, Kotowska, et al., 2005
Isidorov, V.A.; Kotowska, U.; Vinogorova, V.T.,
GC Identification of organic compounds based on partition coefficients of their TMS derivatives in a hexane-acetonitrile system and retention indices,
Anal. Sci., 2005, 21, 12, 1483-1489, https://doi.org/10.2116/analsci.21.1483
. [all data]
Zimmermann, Lauterbach, et al., 1985
Zimmermann, V.; Lauterbach, M.; Jaeger, G.,
Analytical characterization phenolic compounds obtained from phenosolvan-extracts by use of gas-chromatography with capillary columns,
Chem. Tech. (Leipzig), 1985, 37, 11, 476-478. [all data]
Notes
Go To: Top, Mass spectrum (electron ionization), Gas Chromatography, References
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