1,2-Butanediamine

Data at NIST subscription sites:

NIST subscription sites provide data under the NIST Standard Reference Data Program, but require an annual fee to access. The purpose of the fee is to recover costs associated with the development of data collections included in such sites. Your institution may already be a subscriber. Follow the links above to find out more about the data in these sites and their terms of usage.


Gas phase thermochemistry data

Go To: Top, Phase change data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Quantity Value Units Method Reference Comment
Δfgas-17.58 ± 0.20kcal/molCcbMesserly, Finke, et al., 1975 
Δfgas-17.68 ± 0.20kcal/molCcrGood and Moore, 1970 

Phase change data

Go To: Top, Gas phase thermochemistry data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
AC - William E. Acree, Jr., James S. Chickos
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DRB - Donald R. Burgess, Jr.

Quantity Value Units Method Reference Comment
Δvap11.1 ± 0.05kcal/molIPDouslin and Osborn, 2002See also Good and Moore, 1970.; AC
Δvap11.16kcal/molVMesserly, Finke, et al., 1975ALS
Δvap11.2kcal/molIPMesserly, Finke, et al., 1975, 2Based on data from 251. to 293. K.; AC
Δvap11.06 ± 0.05kcal/molVGood and Moore, 1970ALS
Δvap11.0kcal/molN/AGood and Moore, 1970DRB

Enthalpy of vaporization

ΔvapH (kcal/mol) Temperature (K) Reference Comment
12.0278.Stephenson and Malanowski, 1987Based on data from 251. to 293. K. See also Messerly, Finke, et al., 1975, 2.; AC

References

Go To: Top, Gas phase thermochemistry data, Phase change data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Messerly, Finke, et al., 1975
Messerly, J.F.; Finke, H.L.; Osborn, A.G.; Douslin, D.R., Low-temperature calorimetric and vapor-pressure studies on alkanediamines, J. Chem. Thermodyn., 1975, 7, 1029-10. [all data]

Good and Moore, 1970
Good, W.D.; Moore, R.T., Enthalpies of formation of ethylenediamine, 1,2,-propanediamine, 1,2,-butanediamine, 2-methyl-1,2-propanediamine, and isobutylamine C-N and N-F Thermochemical bond energies, J. Chem. Eng. Data, 1970, 15, 150-154. [all data]

Douslin and Osborn, 2002
Douslin, D.R.; Osborn, A., Pressure measurements in the 0.01-30 torr range with an inclined-piston gauge, J. Sci. Instrum., 2002, 42, 6, 369-373, https://doi.org/10.1088/0950-7671/42/6/301 . [all data]

Messerly, Finke, et al., 1975, 2
Messerly, J.F.; Finke, H.L.; Osborn, A.G.; Douslin, D.R., Low-temperature calorimetric and vapor-pressure studies on alkanediamines, J. Chem. Thermodynam., 1975, 7, 1029-1046. [all data]

Stephenson and Malanowski, 1987
Stephenson, Richard M.; Malanowski, Stanislaw, Handbook of the Thermodynamics of Organic Compounds, 1987, https://doi.org/10.1007/978-94-009-3173-2 . [all data]


Notes

Go To: Top, Gas phase thermochemistry data, Phase change data, References