2,3-Butanedione

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Gas phase thermochemistry data

Go To: Top, Condensed phase thermochemistry data, Phase change data, Henry's Law data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Quantity Value Units Method Reference Comment
Δfgas-78.10kcal/molCcbNicholson, Szwarc, et al., 1954 

Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Quantity Value Units Method Reference Comment
Δfliquid-87.35kcal/molCcbNicholson, Szwarc, et al., 1954 
Quantity Value Units Method Reference Comment
Δcliquid-493.81 ± 0.19kcal/molCcbNicholson, Szwarc, et al., 1954Corresponding Δfliquid = -87.34 kcal/mol (simple calculation by NIST; no Washburn corrections)

Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
BS - Robert L. Brown and Stephen E. Stein
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny director
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
AC - William E. Acree, Jr., James S. Chickos

Quantity Value Units Method Reference Comment
Tboil361.2KN/AWeast and Grasselli, 1989BS
Tboil361.15KN/AOthmer, 1943Uncertainty assigned by TRC = 1. K; TRC
Tboil361.15KN/ASabatier and Mailhe, 1909Uncertainty assigned by TRC = 2. K; TRC
Tboil360.15KN/ASabatier and Mailhe, 1907Uncertainty assigned by TRC = 2. K; TRC
Quantity Value Units Method Reference Comment
Δvap9.25 ± 0.22kcal/molVNicholson, Szwarc, et al., 1954ALS

Enthalpy of vaporization

ΔvapH (kcal/mol) Temperature (K) Method Reference Comment
9.20288.A,IStephenson and Malanowski, 1987Based on data from 273. to 348. K. See also Neely and Hall, 1972.; AC
9.46 ± 0.05283.N/ANicholson, Szwarc, et al., 1954, 2Based on data from 273. to 293. K.; AC

Antoine Equation Parameters

log10(P) = A − (B / (T + C))
    P = vapor pressure (atm)
    T = temperature (K)

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Temperature (K) A B C Reference Comment
273.16 to 348.163.53347927.108-98.949Neely and Hall, 1972Coefficents calculated by NIST from author's data.

In addition to the Thermodynamics Research Center (TRC) data available from this site, much more physical and chemical property data is available from the following TRC products:


Henry's Law data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Rolf Sander

Henry's Law constant (water solution)

kH(T) = H exp(d(ln(kH))/d(1/T) ((1/T) - 1/(298.15 K)))
H = Henry's law constant for solubility in water at 298.15 K (mol/(kg*bar))
d(ln(kH))/d(1/T) = Temperature dependence constant (K)

H (mol/(kg*bar)) d(ln(kH))/d(1/T) (K) Method Reference Comment
74.5700.MN/A 
57. MN/A 
190. XN/AValue given here as quoted by missing citation.

References

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Henry's Law data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Nicholson, Szwarc, et al., 1954
Nicholson, G.R.; Szwarc, M.; Taylor, J.W., The heats of formation of diacetyl and of benzyl methyl ketone in the vapour phase, J. Chem. Soc., 1954, 2767-2769. [all data]

Weast and Grasselli, 1989
CRC Handbook of Data on Organic Compounds, 2nd Editon, Weast,R.C and Grasselli, J.G., ed(s)., CRC Press, Inc., Boca Raton, FL, 1989, 1. [all data]

Othmer, 1943
Othmer, D.F., Composition of vapors from boiling binary solutions, Ind. Eng. Chem., 1943, 35, 614-20. [all data]

Sabatier and Mailhe, 1909
Sabatier, P.; Mailhe, A., New Applications of the General Method of Hydrogenation with Various Metals, Ann. Chim. Phys., 1909, 16, 70. [all data]

Sabatier and Mailhe, 1907
Sabatier, P.; Mailhe, A., The Direct Hydrogenation of Methyl Diketones, C. R. Hebd. Seances Acad. Sci., 1907, 144, 1086. [all data]

Stephenson and Malanowski, 1987
Stephenson, Richard M.; Malanowski, Stanislaw, Handbook of the Thermodynamics of Organic Compounds, 1987, https://doi.org/10.1007/978-94-009-3173-2 . [all data]

Neely and Hall, 1972
Neely, William C.; Hall, Terry D., Vapor pressure of biacetyl, J. Chem. Eng. Data, 1972, 17, 3, 294-295, https://doi.org/10.1021/je60054a010 . [all data]

Nicholson, Szwarc, et al., 1954, 2
Nicholson, G.R.; Szwarc, M.; Taylor, J. Watson, The heats of formation of diacetyl and of benzyl methyl ketone in the vapour phase, J. Chem. Soc., 1954, 2767, https://doi.org/10.1039/jr9540002767 . [all data]


Notes

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Henry's Law data, References