2α,4α-Dimethyl-6β-vinyl-1,3-dioxane


Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

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Individual Reactions

2α,4α-Dimethyl-6β-vinyl-1,3-dioxane = 1,3-Dioxane, 4-ethenyl-2,6-dimethyl-, (2α,4β,6α)-

By formula: C8H14O2 = C8H14O2

Quantity Value Units Method Reference Comment
Δr-0.64kcal/molEqkAnteunis and Coryn, 1973liquid phase; solvent: Pyridine

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Anteunis and Coryn, 1973
Anteunis, M.; Coryn, M., N.M.R. experiments on acetals. Part 44. The conformational behaviour of 4-vinylgroups in 1,3-dioxanes. 300 MHz study of 4-vinyl-5-Me, and 4-vinyl-6-Me-substituted 1,3-dioxanes, Bull. Soc. Chim. Belg., 1973, 82, 413-422. [all data]


Notes

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