(S)-butan-2-ol

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Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny director
AC - William E. Acree, Jr., James S. Chickos

Quantity Value Units Method Reference Comment
Tboil372.9KN/ABothner-By, 1951Uncertainty assigned by TRC = 0.5 K; TRC
Tboil372.95KN/ABernstein and Pedersen, 1949Uncertainty assigned by TRC = 0.5 K; TRC
Tboil372.15KN/AKornblum, Patton, et al., 1948Uncertainty assigned by TRC = 1. K; TRC
Tboil372.65KN/ATimmermans, 1927Uncertainty assigned by TRC = 0.3 K; source of data not clear; TRC
Tboil372.05KN/AWillcox and Brunel, 1916Uncertainty assigned by TRC = 0.5 K; TRC
Quantity Value Units Method Reference Comment
Ttriple177.38KN/AWilhoit, Chao, et al., 1985Uncertainty assigned by TRC = 0.1 K; TRC
Ttriple177.38KN/AAndon, Connett, et al., 1971Uncertainty assigned by TRC = 0.02 K; TRC

Enthalpy of fusion

ΔfusH (kcal/mol) Temperature (K) Reference Comment
1.4177.4Andon, Connett, et al., 1971, 2AC

In addition to the Thermodynamics Research Center (TRC) data available from this site, much more physical and chemical property data is available from the following TRC products:


References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Bothner-By, 1951
Bothner-By, A.A., J. Am. Chem. Soc., 1951, 73, 846. [all data]

Bernstein and Pedersen, 1949
Bernstein, H.J.; Pedersen, E.E., Internal rotation: IV the optical activity and isomerization energy of the rotational isomers of d-secondary butyl alcohol, J. Chem. Phys., 1949, 17, 885. [all data]

Kornblum, Patton, et al., 1948
Kornblum, N.; Patton, J.T.; Nordmann, J.B., The Basis for the Reported Optical Activity of the Salts of Aliphatic Nitro Compounds: 2-Nitrobutane, J. Am. Chem. Soc., 1948, 70, 746. [all data]

Timmermans, 1927
Timmermans, J., The Melting Point of Organic Substances, Bull. Soc. Chim. Belg., 1927, 36, 502. [all data]

Willcox and Brunel, 1916
Willcox, M.; Brunel, R.F., J. Am. Chem. Soc., 1916, 38, 1821. [all data]

Wilhoit, Chao, et al., 1985
Wilhoit, R.C.; Chao, J.; Hall, K.R., Thermodynamic Properties of Key Organic Compounds in the Carbon Range C1 to C4. Part 1. Properties of Condensed Phases, J. Phys. Chem. Ref. Data, 1985, 14, 1. [all data]

Andon, Connett, et al., 1971
Andon, R.J.L.; Connett, J.E.; Counsell, J.F.; Lees, E.B.; Martin, J.F., Thermodynamic properties of organic oxygen compounds: xxvii racemate of - butan-2-ol and (+)-butan-2-ol, J. Chem. Soc. A, 1971, 1971, 661-4. [all data]

Andon, Connett, et al., 1971, 2
Andon, R.J.L.; Connett, J.E.; Counsell, J.F.; Lees, E.B.; Martin, J.F., Thermodynamic properties of organic oxygen compounds. Part XXVII. («65533»)-Butan-2-ol and (+)-butan-2-ol, J. Chem. Soc., A, 1971, 661, https://doi.org/10.1039/j19710000661 . [all data]


Notes

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