CF3OCH3

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Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny director
AC - William E. Acree, Jr., James S. Chickos

Quantity Value Units Method Reference Comment
Tfus124.KN/ASalvi-Narkhede, Wang, et al., 1992Uncertainty assigned by TRC = 2. K; TRC
Tfus124.KN/AWang, Adcock, et al., 1991Uncertainty assigned by TRC = 2. K; TRC
Quantity Value Units Method Reference Comment
Tc378.02KN/ASalvi-Narkhede, Wang, et al., 1992Uncertainty assigned by TRC = 0.2 K; method of measurement not clearly described; TRC
Tc378.08KN/AWang, Adcock, et al., 1991Uncertainty assigned by TRC = 0.3 K; TRC
Quantity Value Units Method Reference Comment
Pc35.41atmN/ASalvi-Narkhede, Wang, et al., 1992Uncertainty assigned by TRC = 0.05 atm; TRC
Pc36.32atmN/AWang, Adcock, et al., 1991Uncertainty assigned by TRC = 0.12 atm; TRC
Quantity Value Units Method Reference Comment
Vc0.229l/molN/ASalvi-Narkhede, Wang, et al., 1992Uncertainty assigned by TRC = 0.003 l/mol; TRC
Vc0.229l/molN/AWang, Adcock, et al., 1991Uncertainty assigned by TRC = 0.005 l/mol; TRC

Enthalpy of vaporization

ΔvapH (kcal/mol) Temperature (K) Method Reference Comment
5.38248.ASalvi-Narkhede, Wang, et al., 1992, 2Based on data from 233. to 313. K.; AC

In addition to the Thermodynamics Research Center (TRC) data available from this site, much more physical and chemical property data is available from the following TRC products:


Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data evaluated by: Edward P. Hunter and Sharon G. Lias

Quantity Value Units Method Reference Comment
Proton affinity (review)171.9kcal/molN/AHunter and Lias, 1998 
Quantity Value Units Method Reference Comment
Gas basicity164.9kcal/molN/AHunter and Lias, 1998 

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Salvi-Narkhede, Wang, et al., 1992
Salvi-Narkhede, M.; Wang, B.H.; Adcock, J.I.; Van Hook, W.A., Vapor pressures, liquid molar volumes, vapor non-ideality, and critical properties of some partially fluorinated ethers (CF3OCF2CF2H, CF3OCF2H, and CF3OCH3), some perfluoroethers (CF3OCF2OCF3, c-CF2O, J. Chem. Thermodyn., 1992, 24, 1065-75. [all data]

Wang, Adcock, et al., 1991
Wang, B.H.; Adcock, J.L.; Mathur, S.B.; Van Hook, W.A., Vapor pressures, liquid molar volumes, vapor non-idealities, and critical properties of some fluorinated ethers: CF3OCF2OCF3, CF3OCF2CF2H, c-CF2CF2 CF2O, CF3OCF2H, and CF3OCH3; and of CCl3F and CF2CI, J. Chem. Thermodyn., 1991, 23, 699-710. [all data]

Salvi-Narkhede, Wang, et al., 1992, 2
Salvi-Narkhede, M.; Wang, Bao-Huai; Adcock, James L.; Alexander Van Hook, W., Vapor pressures, liquid molar volumes, vapor non-ideality, and critical properties of some partially fluorinated ethers (CF3OCF2CF2H, CF3OCF2H, and CF3OCH3), some perfluoroethers (CF3OCF2OCF3, c-CF2OCF2OCF2, and c-CF2CF2CF2O), and of CHF2Br and CF3CFHCF3, The Journal of Chemical Thermodynamics, 1992, 24, 10, 1065-1075, https://doi.org/10.1016/S0021-9614(05)80017-5 . [all data]

Hunter and Lias, 1998
Hunter, E.P.; Lias, S.G., Evaluated Gas Phase Basicities and Proton Affinities of Molecules: An Update, J. Phys. Chem. Ref. Data, 1998, 27, 3, 413-656, https://doi.org/10.1063/1.556018 . [all data]


Notes

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