cis-1-Propenyl tert-butyl ether


Reaction thermochemistry data

Go To: Top, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

1-Propene, 3-(1,1-dimethylethoxy)- = cis-1-Propenyl tert-butyl ether

By formula: C7H14O = C7H14O

Quantity Value Units Method Reference Comment
Δr-25.4 ± 1.2kJ/molEqkTaskinen, 1993liquid phase; solvent: DMSO; Isomerization

cis-1-Propenyl tert-butyl ether = Ether, tert-butyl propenyl, (E)-

By formula: C7H14O = C7H14O

Quantity Value Units Method Reference Comment
Δr2.85 ± 0.56kJ/molEqkOkuyama, Fueno, et al., 1969liquid phase; GC

References

Go To: Top, Reaction thermochemistry data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Taskinen, 1993
Taskinen, E., Relative thermodynamic stabilities of isomeric alkyl allyl and alkyl (Z)-propenyl ethers, Tetrahedron, 1993, 49, 11389-11394. [all data]

Okuyama, Fueno, et al., 1969
Okuyama, T.; Fueno, T.; Furukawa, J., Structure and reactivity of α,β-unsaturated ethers. 9. Cis-trans isomerization equilibriums in the liquid phase, Tetrahedron, 1969, 25, 5409-5414. [all data]


Notes

Go To: Top, Reaction thermochemistry data, References