cis-1-Propenyl methyl ether
- Formula: C4H8O
- Molecular weight: 72.1057
- IUPAC Standard InChI: InChI=1S/C8H14O/c1-3-5-7-9-8-6-4-2/h3-6H,7-8H2,1-2H3/b5-3-,6-4-
- IUPAC Standard InChIKey: FXCXOKOKILDXCL-GLIMQPGKSA-N
- CAS Registry Number: 4188-68-5
- Chemical structure:
This structure is also available as a 2d Mol file or as a computed 3d SD file
The 3d structure may be viewed using Java or Javascript. - Other names: 1-Propene, 1-methoxy-, (Z)-; (Z)-CH3OCH=CHCH3; 1-Propene, 1-methoxy-, (1Z)-; cis-1-METHOXYPROPEN
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Phase change data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: William E. Acree, Jr., James S. Chickos
Enthalpy of vaporization
| ΔvapH (kcal/mol) | Temperature (K) | Method | Reference | Comment |
|---|---|---|---|---|
| 7.31 | 305. | A | Stephenson and Malanowski, 1987 | Based on data from 293. to 318. K. |
Reaction thermochemistry data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
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Individual Reactions
=
By formula: C4H8O = C4H8O
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | -4.83 ± 0.05 | kcal/mol | Eqk | Taskinen, 1993 | liquid phase; solvent: DMSO; Isomerization |
=
By formula: C4H8O = C4H8O
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | -0.913 ± 0.057 | kcal/mol | Eqk | Okuyama, Fueno, et al., 1969 | liquid phase; Gc |
References
Go To: Top, Phase change data, Reaction thermochemistry data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Stephenson and Malanowski, 1987
Stephenson, Richard M.; Malanowski, Stanislaw,
Handbook of the Thermodynamics of Organic Compounds, 1987, https://doi.org/10.1007/978-94-009-3173-2
. [all data]
Taskinen, 1993
Taskinen, E.,
Relative thermodynamic stabilities of isomeric alkyl allyl and alkyl (Z)-propenyl ethers,
Tetrahedron, 1993, 49, 11389-11394. [all data]
Okuyama, Fueno, et al., 1969
Okuyama, T.; Fueno, T.; Furukawa, J.,
Structure and reactivity of α,β-unsaturated ethers. 9. Cis-trans isomerization equilibriums in the liquid phase,
Tetrahedron, 1969, 25, 5409-5414. [all data]
Notes
Go To: Top, Phase change data, Reaction thermochemistry data, References
- Symbols used in this document:
ΔrH° Enthalpy of reaction at standard conditions ΔvapH Enthalpy of vaporization - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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