1,1'-Biphenyl, 2,2',4,5'-tetrachloro-
- Formula: C12H6Cl4
- Molecular weight: 291.988
- IUPAC Standard InChIKey: ZWPVHELAQPIZHO-UHFFFAOYSA-N
- CAS Registry Number: 41464-40-8
- Chemical structure:
This structure is also available as a 2d Mol file or as a computed 3d SD file
The 3d structure may be viewed using Java or Javascript. - Other names: 2,2',4,5'-Tetrachlorobiphenyl; 2,4,2',5'-Tetrachlorobiphenyl; 1,1'-Biphenyl, 2,2',4',5-tetrachloro; PCB 49
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Gas Chromatography
Go To: Top, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director
Kovats' RI, non-polar column, isothermal
Column type | Active phase | Temperature (C) | I | Reference | Comment |
---|---|---|---|---|---|
Capillary | OV-101 | 150. | 1890. | Zell, Neu, et al., 1977 | Column length: 27. m |
Capillary | OV-101 | 150. | 1891. | Zell, Neu, et al., 1977 | Column length: 27. m |
Capillary | OV-101 | 180. | 1911.8 | Krupcik, Leclercq, et al., 1976 | Column length: 50. m |
Capillary | OV-101 | 190. | 1921.6 | Krupcik, Leclercq, et al., 1976 | Column length: 50. m |
Capillary | OV-101 | 200. | 1931.7 | Krupcik, Leclercq, et al., 1976 | Column length: 50. m |
Capillary | OV-101 | 200. | 1931.3 | Krupcik, Leclercq, et al., 1976 | Column length: 50. m |
Van Den Dool and Kratz RI, non-polar column, temperature ramp
Column type | Active phase | I | Reference | Comment |
---|---|---|---|---|
Capillary | Methyl Silicone | 1909. | Kozloski, 1985 | He, 5. K/min; Column length: 10. m; Column diameter: 0.21 mm; Tstart: 60. C; Tend: 210. C |
Capillary | CP Sil 5 CB | 1895. | Wells, Gillespie, et al., 1985 | 120. C @ 1. min, 3. K/min; Column length: 25. m; Column diameter: 0.22 mm; Tend: 250. C |
Normal alkane RI, non-polar column, isothermal
Column type | Active phase | Temperature (C) | I | Reference | Comment |
---|---|---|---|---|---|
Capillary | Apiezon L | 180. | 1972. | Ballschmiter and Zell, 1980 | H2; Column length: 40. m; Column diameter: 0.30 mm |
Normal alkane RI, non-polar column, temperature ramp
Column type | Active phase | I | Reference | Comment |
---|---|---|---|---|
Capillary | SPB-1 | 1895. | Nakano, Tsuji, et al., 1987 | 30. m/0.25 mm/0.25 μm, 4. K/min; Tstart: 130. C; Tend: 280. C |
Normal alkane RI, non-polar column, custom temperature program
Column type | Active phase | I | Reference | Comment |
---|---|---|---|---|
Capillary | Apolane | 1937. | Bush, Murphy, et al., 1985 | He; Column length: 50. m; Column diameter: 0.25 mm; Program: 70 0C (2 min) 10 0C/min (6 min) 2 0C/min -> 250 0C |
Capillary | Apolane | 1937. | Bush, Murphy, et al., 1985 | He; Column length: 50. m; Column diameter: 0.25 mm; Program: 70 0C (2 min) 10 0C/min (6 min) 2 0C/min -> 250 0C |
Capillary | Apiezon L | 1971. | Ballschmiter and Zell, 1980 | H2; Column length: 40. m; Column diameter: 0.30 mm; Program: not specified |
References
Go To: Top, Gas Chromatography, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Zell, Neu, et al., 1977
Zell, M.; Neu, H.J.; Ballschmiter, K.,
Identifizierung der PCB-Komponenten durch retentionsindexvergleich nach kapillar-gaschromatographie,
Chemosphere, 1977, 2/3, 2-3, 69-76, https://doi.org/10.1016/0045-6535(77)90047-9
. [all data]
Krupcik, Leclercq, et al., 1976
Krupcik, J.; Leclercq, P.A.; Símová, A.; Suchánek, P.; Collák, M.; Hrivnák, J.,
Possibilities and limitations of capillary gas chromatography and mass spectrometry in the analysis of polychlorinated biphenyls,
J. Chromatogr., 1976, 119, 271-283, https://doi.org/10.1016/S0021-9673(00)86791-6
. [all data]
Kozloski, 1985
Kozloski, R.P.,
Polychlorinated biphenyl retention time standards obtained by chemical dechlorination of polychlorinated biphenyl isomers,
J. Chromatogr., 1985, 318, 211-219, https://doi.org/10.1016/S0021-9673(01)90682-X
. [all data]
Wells, Gillespie, et al., 1985
Wells, D.E.; Gillespie, M.J.; Porter, A.E.A.,
Dichlorobenzyl alkyl ether homologs as retention index markers and internal standards for the analysis of environmental samples using capillary gas chromatography,
J. Hi. Res. Chromatogr. Chromatogr. Comm., 1985, 8, 8, 443-449, https://doi.org/10.1002/jhrc.1240080818
. [all data]
Ballschmiter and Zell, 1980
Ballschmiter, K.; Zell, M.,
Analysis of polychlorinated biphenyls (PCB) by glass capillary gas chromatography,
Fresenius Z. Anal. Chem., 1980, 302, 1, 20-31, https://doi.org/10.1007/BF00469758
. [all data]
Nakano, Tsuji, et al., 1987
Nakano, T.; Tsuji, M.; Okuno, T.,
Analytical methods for PCB using GC/ECD and GC/MS with capillary column,
Report of the Environmental Science Institute of Hyoho Prefecture, 1987, 19, 57-62. [all data]
Bush, Murphy, et al., 1985
Bush, B.; Murphy, M.J.; Connor, S.; Snow, J.; Barnard, E.,
Improvements in Glass Capillary Gas Chromatographic Polychlorobiphenyl Analysis,
J. Chromatogr. Sci., 1985, 23, 11, 509-515, https://doi.org/10.1093/chromsci/23.11.509
. [all data]
Notes
Go To: Top, Gas Chromatography, References
- Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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