4-Tetradecene, (Z)-
- Formula: C14H28
- Molecular weight: 196.3721
- IUPAC Standard InChIKey: XEIYDTUADLFFTM-CLFYSBASSA-N
- CAS Registry Number: 41446-65-5
- Chemical structure:
This structure is also available as a 2d Mol file or as a computed 3d SD file
The 3d structure may be viewed using Java or Javascript. - Stereoisomers:
- Other names: (4Z)-4-Tetradecene; cis-4-Tetradecene; (Z)-4-Tetradecene
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Gas Chromatography
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director
Kovats' RI, non-polar column, isothermal
Column type | Active phase | Temperature (C) | I | Reference | Comment |
---|---|---|---|---|---|
Capillary | Squalane | 100. | 1378. | Heinzen, Soares, et al., 1999 | |
Capillary | SE-30 | 120. | 1392. | Gusev, Sokolov, et al., 1989 | H2; Column length: 40. m; Column diameter: 0.30 mm |
Capillary | OV-101 | 110. | 1389. | Rang, Kuningas, et al., 1987 | He; Column length: 50. m; Column diameter: 0.25 mm |
Capillary | Squalane | 74. | 1376.8 | Soják, Kraus, et al., 1982 | Column length: 62. m; Column diameter: 0.25 mm |
Capillary | Squalane | 100. | 1378. | Sojak, Hrivnak, et al., 1973 | |
Capillary | Squalane | 130. | 1380. | Sojak, Hrivnak, et al., 1973 |
Kovats' RI, polar column, isothermal
Column type | Active phase | Temperature (C) | I | Reference | Comment |
---|---|---|---|---|---|
Capillary | PEG-20M | 80. | 1427. | Orav, Kuningas, et al., 1993 | 100. m/0.25 mm/0.12 μm |
Capillary | PEG-20M | 80. | 1432.9 | Orav, Kuningas, et al., 1993 | 100. m/0.25 mm/0.24 μm |
Capillary | PEG-20M | 80. | 1434.3 | Orav, Kuningas, et al., 1993 | 60. m/0.32 mm/0.25 μm |
Capillary | PEG 4000 | 100. | 1443. | Rang, Orav, et al., 1988 | |
Capillary | PEG 4000 | 110. | 1444. | Rang, Orav, et al., 1988 | |
Capillary | PEG 4000 | 120. | 1445. | Rang, Orav, et al., 1988 | |
Capillary | PEG 4000 | 140. | 1447. | Rang, Orav, et al., 1988 | |
Capillary | PEG 4000 | 160. | 1449. | Rang, Orav, et al., 1988 | |
Capillary | PEG-20M | 120. | 1439. | Rang, Orav, et al., 1988 | |
Capillary | PEG-20M | 130. | 1440. | Rang, Orav, et al., 1988 | |
Capillary | PEG-20M | 140. | 1441. | Rang, Orav, et al., 1988 | |
Capillary | PEG-20M | 150. | 1443. | Rang, Orav, et al., 1988 | |
Capillary | PEG-20M | 160. | 1444. | Rang, Orav, et al., 1988 | |
Capillary | PEG-20M | 65. | 1422. | Rang, Orav, et al., 1988 | |
Capillary | PEG-20M | 65. | 1430. | Rang, Orav, et al., 1988 | |
Capillary | PEG-20M | 65. | 1430. | Rang, Orav, et al., 1988 | |
Capillary | PEG-20M | 65. | 1431. | Rang, Orav, et al., 1988 | |
Capillary | PEG-20M | 70. | 1424. | Rang, Orav, et al., 1988 | |
Capillary | PEG-20M | 70. | 1431. | Rang, Orav, et al., 1988 | |
Capillary | PEG-20M | 70. | 1431. | Rang, Orav, et al., 1988 | |
Capillary | PEG-20M | 70. | 1432. | Rang, Orav, et al., 1988 | |
Capillary | PEG-20M | 80. | 1425. | Rang, Orav, et al., 1988 | |
Capillary | PEG-20M | 80. | 1433. | Rang, Orav, et al., 1988 | |
Capillary | PEG-20M | 80. | 1433. | Rang, Orav, et al., 1988 | |
Capillary | PEG-20M | 65. | 1422. | Orav, Kuningas, et al., 1985 | Column length: 100. m; Column diameter: 0.25 mm |
Capillary | PEG-20M | 65. | 1430.2 | Orav, Kuningas, et al., 1985 | Column length: 100. m; Column diameter: 0.25 mm |
Capillary | PEG-20M | 70. | 1424.4 | Orav, Kuningas, et al., 1985 | Column length: 100. m; Column diameter: 0.25 mm |
Capillary | PEG-20M | 70. | 1431.1 | Orav, Kuningas, et al., 1985 | Column length: 100. m; Column diameter: 0.25 mm |
Capillary | PEG-20M | 65. | 1419.4 | Orav, Kuningas, et al., 1985 | Column length: 50. m; Column diameter: 0.25 mm |
Capillary | PEG-20M | 65. | 1422.5 | Orav, Kuningas, et al., 1985 | Column length: 50. m; Column diameter: 0.25 mm |
Capillary | PEG-20M | 65. | 1430.1 | Orav, Kuningas, et al., 1985 | Column length: 50. m; Column diameter: 0.25 mm |
Capillary | PEG-20M | 65. | 1431.1 | Orav, Kuningas, et al., 1985 | Column length: 50. m; Column diameter: 0.25 mm |
Capillary | PEG-20M | 70. | 1422.3 | Orav, Kuningas, et al., 1985 | Column length: 50. m; Column diameter: 0.25 mm |
Capillary | PEG-20M | 70. | 1424.4 | Orav, Kuningas, et al., 1985 | Column length: 50. m; Column diameter: 0.25 mm |
Capillary | PEG-20M | 70. | 1431.1 | Orav, Kuningas, et al., 1985 | Column length: 50. m; Column diameter: 0.25 mm |
Capillary | PEG-20M | 70. | 1432. | Orav, Kuningas, et al., 1985 | Column length: 50. m; Column diameter: 0.25 mm |
Capillary | PEG 4000 | 100. | 1443. | Rang, Kuningas, et al., 1977 | Column diameter: 0.25 mm |
Capillary | PEG 4000 | 120. | 1445. | Rang, Kuningas, et al., 1977 | Column diameter: 0.25 mm |
Capillary | PEG 4000 | 140. | 1447. | Rang, Kuningas, et al., 1977 | Column diameter: 0.25 mm |
Capillary | PEG 4000 | 160. | 1449. | Rang, Kuningas, et al., 1977 | Column diameter: 0.25 mm |
Normal alkane RI, non-polar column, custom temperature program
Column type | Active phase | I | Reference | Comment |
---|---|---|---|---|
Capillary | Polydimethyl siloxane | 1378. | Junkes, Castanho, et al., 2003 | Program: not specified |
References
Go To: Top, Gas Chromatography, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Heinzen, Soares, et al., 1999
Heinzen, V.E.F.; Soares, M.F.; Yunes, R.A.,
Semi-empirical topological method for the prediction of the chromatographic retention of cis- and trans-alkene isomers and alkanes,
J. Chromatogr. A, 1999, 849, 2, 495-506, https://doi.org/10.1016/S0021-9673(99)00530-0
. [all data]
Gusev, Sokolov, et al., 1989
Gusev, G.M.; Sokolov, V.P.; Yurov, V.V.; Kuznetsov, A.V.; Potatuev, A.A.,
Identification of olefins during hydrocarboxylation,
Zh. Anal. Khim., 1989, 44, 551-555. [all data]
Rang, Kuningas, et al., 1987
Rang, S.; Kuningas, K.; Strenze, T.; Orav, A.; Eisen, O.,
Retention and Thermodynamics of Solution of n-Alkenes in OV-101,
J. Chromatogr., 1987, 406, 75-80, https://doi.org/10.1016/S0021-9673(00)94018-4
. [all data]
Soják, Kraus, et al., 1982
Soják, L.; Kraus, G.; Farkas, P.; Ostovský, I.,
Hochleistungs-gaschromatographie an flüssigkristall-glaskapillaren. V. Trennung von isomeren n-tridecenen und n-tetradecenen,
J. Chromatogr., 1982, 238, 1, 51-57, https://doi.org/10.1016/S0021-9673(00)82710-7
. [all data]
Sojak, Hrivnak, et al., 1973
Sojak, L.; Hrivnak, J.; Majer, P.; Janak, J.,
Capillary Gas Chromatography of Linear Alkenes on Squalane,
Anal. Chem., 1973, 45, 2, 293-302, https://doi.org/10.1021/ac60324a039
. [all data]
Orav, Kuningas, et al., 1993
Orav, A.; Kuningas, K.; Rang, S.,
A comparison of different retention index systems with unsaturated and aromatic hydrocarbons in capillary gas chromatography on PEG 20MK,
Chromatographia, 1993, 37, 7/8, 411-414, https://doi.org/10.1007/BF02272257
. [all data]
Rang, Orav, et al., 1988
Rang, S.A.; Orav, A.E.; Kuningas, K.R.; Meister, A.E.; Strense, T.V.; Eisen, O.G.,
Gas-Chromatographic Characteristics of unsaturated hydrocarbons, Academy of Sciences of Estonia SSR, Tallinn, Estonia SSR, 1988, 208. [all data]
Orav, Kuningas, et al., 1985
Orav, A.; Kuningas, K.; Rang, S.; Eisen, O.,
Capillary gas chromatography of n-tridecenes, n-tetradecenes and C10-C14 n-alkynes on polyethylene glycol 20m of different polarity,
Eesti NSV Tead. Akad. Toim. Keem., 1985, 34, 2, 105-113. [all data]
Rang, Kuningas, et al., 1977
Rang, S.; Kuningas, K.; Orav, A.; Eisen, O.,
Capillary Gas Chromatography of C6-C14 n-Alkenes on Polyphenyl Ether and Polyethylene Glycol 4000,
Chromatographia, 1977, 10, 2, 55-64, https://doi.org/10.1007/BF02274460
. [all data]
Junkes, Castanho, et al., 2003
Junkes, B.S.; Castanho, R.D.M.; Amboni, C.; Yunes, R.A.; Heinzen, V.E.F.,
Semiempirical Topological Index: A Novel Molecular Descriptor for Quantitative Structure-Retention Relationship Studies,
Internet Electronic Journal of Molecular Design, 2003, 2, 1, 33-49. [all data]
Notes
Go To: Top, Gas Chromatography, References
- Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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