2-Tridecene, (E)


Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

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Individual Reactions

2-Tridecene, (Z) = 2-Tridecene, (E)

By formula: C13H26 = C13H26

Quantity Value Units Method Reference Comment
Δr-1.5kcal/molEqkDoering, Estel, et al., 1973liquid phase

Gas Chromatography

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Kovats' RI, non-polar column, isothermal

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Column type Active phase Temperature (C) I Reference Comment
CapillarySqualane100.1297.Heinzen, Soares, et al., 1999 
CapillaryOV-101110.1302.Rang, Kuningas, et al., 1987He; Column length: 50. m; Column diameter: 0.25 mm
CapillarySqualane74.1297.7Soják, Kraus, et al., 1982Column length: 62. m; Column diameter: 0.25 mm
CapillarySqualane100.1297.Sojak, Hrivnak, et al., 1973 
CapillarySqualane115.1297.Sojak, Hrivnak, et al., 1973 
CapillarySqualane130.1297.Sojak, Hrivnak, et al., 1973 
CapillarySqualane86.1297.Sojak, Hrivnak, et al., 1973 

Kovats' RI, polar column, isothermal

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Column type Active phase Temperature (C) I Reference Comment
CapillaryPEG-20M80.1350.4Orav, Kuningas, et al., 199450. m/0.2 mm/0.13 μm, He
CapillaryPEG-20M80.1353.1Orav, Kuningas, et al., 199450. m/0.2 mm/0.19 μm, He
CapillaryPEG-20M80.1354.9Orav, Kuningas, et al., 199450. m/0.2 mm/0.22 μm, He
CapillaryPEG-20M65.1348.Rang, Orav, et al., 1988 
CapillaryPEG-20M65.1355.Rang, Orav, et al., 1988 
CapillaryPEG-20M65.1356.Rang, Orav, et al., 1988 
CapillaryPEG-20M65.1358.Rang, Orav, et al., 1988 
CapillaryPEG-20M70.1348.Rang, Orav, et al., 1988 
CapillaryPEG-20M70.1357.Rang, Orav, et al., 1988 
CapillaryPEG-20M70.1358.Rang, Orav, et al., 1988 
CapillaryPEG-20M80.1357.Rang, Orav, et al., 1988 
CapillaryPEG 4000100.1365.Rang, Orav, et al., 1988 
CapillaryPEG 4000110.1365.Rang, Orav, et al., 1988 
CapillaryPEG 4000120.1365.Rang, Orav, et al., 1988 
CapillaryPEG 4000140.1365.Rang, Orav, et al., 1988 
CapillaryPEG 4000160.1366.Rang, Orav, et al., 1988 
CapillaryPEG-20M110.1360.Rang, Orav, et al., 1988 
CapillaryPEG-20M120.1360.Rang, Orav, et al., 1988 
CapillaryPEG-20M130.1361.Rang, Orav, et al., 1988 
CapillaryPEG-20M140.1361.Rang, Orav, et al., 1988 
CapillaryPEG-20M150.1362.Rang, Orav, et al., 1988 
CapillaryPEG-20M160.1362.Rang, Orav, et al., 1988 
CapillaryPEG-20M65.1348.Orav, Kuningas, et al., 1985Column length: 100. m; Column diameter: 0.25 mm
CapillaryPEG-20M65.1357.9Orav, Kuningas, et al., 1985Column length: 100. m; Column diameter: 0.25 mm
CapillaryPEG-20M70.1349.Orav, Kuningas, et al., 1985Column length: 100. m; Column diameter: 0.25 mm
CapillaryPEG-20M70.1358.1Orav, Kuningas, et al., 1985Column length: 100. m; Column diameter: 0.25 mm
CapillaryPEG-20M65.1343.3Orav, Kuningas, et al., 1985Column length: 50. m; Column diameter: 0.25 mm
CapillaryPEG-20M65.1347.5Orav, Kuningas, et al., 1985Column length: 50. m; Column diameter: 0.25 mm
CapillaryPEG-20M65.1355.Orav, Kuningas, et al., 1985Column length: 50. m; Column diameter: 0.25 mm
CapillaryPEG-20M65.1355.9Orav, Kuningas, et al., 1985Column length: 50. m; Column diameter: 0.25 mm
CapillaryPEG-20M70.1344.1Orav, Kuningas, et al., 1985Column length: 50. m; Column diameter: 0.25 mm
CapillaryPEG-20M70.1348.4Orav, Kuningas, et al., 1985Column length: 50. m; Column diameter: 0.25 mm
CapillaryPEG-20M70.1357.2Orav, Kuningas, et al., 1985Column length: 50. m; Column diameter: 0.25 mm
CapillaryPEG 4000100.1365.Rang, Kuningas, et al., 1977Column diameter: 0.25 mm
CapillaryPEG 4000120.1365.Rang, Kuningas, et al., 1977Column diameter: 0.25 mm
CapillaryPEG 4000140.1365.Rang, Kuningas, et al., 1977Column diameter: 0.25 mm
CapillaryPEG 4000160.1366.Rang, Kuningas, et al., 1977Column diameter: 0.25 mm

Van Den Dool and Kratz RI, non-polar column, custom temperature program

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Column type Active phase I Reference Comment
CapillaryDB-51305.Zaikin and Borisov, 2002He; Column length: 30. m; Column diameter: 0.25 mm; Program: 30C => 5K/min=120C => 10C/min => 270C

Normal alkane RI, non-polar column, temperature ramp

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Column type Active phase I Reference Comment
CapillaryPetrocol DH1301.Sojak, Kubinec, et al., 2006150. m/0.25 mm/1.0 μm, 1. K/min; Tstart: 40. C; Tend: 300. C

Normal alkane RI, non-polar column, custom temperature program

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Column type Active phase I Reference Comment
CapillaryPolydimethyl siloxane1297.Junkes, Castanho, et al., 2003Program: not specified

References

Go To: Top, Reaction thermochemistry data, Gas Chromatography, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Doering, Estel, et al., 1973
Doering, C.E.; Estel, D.; Fischer, R.; Baberowski, G.; Prinzler, H., Analysis of C13 olefins as epoxides by capillary gas chromatography, Z. Chem., 1973, 13, 257-258. [all data]

Heinzen, Soares, et al., 1999
Heinzen, V.E.F.; Soares, M.F.; Yunes, R.A., Semi-empirical topological method for the prediction of the chromatographic retention of cis- and trans-alkene isomers and alkanes, J. Chromatogr. A, 1999, 849, 2, 495-506, https://doi.org/10.1016/S0021-9673(99)00530-0 . [all data]

Rang, Kuningas, et al., 1987
Rang, S.; Kuningas, K.; Strenze, T.; Orav, A.; Eisen, O., Retention and Thermodynamics of Solution of n-Alkenes in OV-101, J. Chromatogr., 1987, 406, 75-80, https://doi.org/10.1016/S0021-9673(00)94018-4 . [all data]

Soják, Kraus, et al., 1982
Soják, L.; Kraus, G.; Farkas, P.; Ostovský, I., Hochleistungs-gaschromatographie an flüssigkristall-glaskapillaren. V. Trennung von isomeren n-tridecenen und n-tetradecenen, J. Chromatogr., 1982, 238, 1, 51-57, https://doi.org/10.1016/S0021-9673(00)82710-7 . [all data]

Sojak, Hrivnak, et al., 1973
Sojak, L.; Hrivnak, J.; Majer, P.; Janak, J., Capillary Gas Chromatography of Linear Alkenes on Squalane, Anal. Chem., 1973, 45, 2, 293-302, https://doi.org/10.1021/ac60324a039 . [all data]

Orav, Kuningas, et al., 1994
Orav, A.; Kuningas, K.; Kailas, T.; Koplimets, E.; Rang, S., Effect of adsorption on the retention values in capillary columns coated with OV-225 and PEG 20M, J. Chromatogr. A, 1994, 659, 1, 143-150, https://doi.org/10.1016/0021-9673(94)85016-X . [all data]

Rang, Orav, et al., 1988
Rang, S.A.; Orav, A.E.; Kuningas, K.R.; Meister, A.E.; Strense, T.V.; Eisen, O.G., Gas-Chromatographic Characteristics of unsaturated hydrocarbons, Academy of Sciences of Estonia SSR, Tallinn, Estonia SSR, 1988, 208. [all data]

Orav, Kuningas, et al., 1985
Orav, A.; Kuningas, K.; Rang, S.; Eisen, O., Capillary gas chromatography of n-tridecenes, n-tetradecenes and C10-C14 n-alkynes on polyethylene glycol 20m of different polarity, Eesti NSV Tead. Akad. Toim. Keem., 1985, 34, 2, 105-113. [all data]

Rang, Kuningas, et al., 1977
Rang, S.; Kuningas, K.; Orav, A.; Eisen, O., Capillary Gas Chromatography of C6-C14 n-Alkenes on Polyphenyl Ether and Polyethylene Glycol 4000, Chromatographia, 1977, 10, 2, 55-64, https://doi.org/10.1007/BF02274460 . [all data]

Zaikin and Borisov, 2002
Zaikin, V.G.; Borisov, R.S., Chromatographic-mass spectrometric analysis of Fishcer-Tropsch synthesis products, J. Anal. Chem. USSR (Engl. Transl.), 2002, 57, 6, 544-551. [all data]

Sojak, Kubinec, et al., 2006
Sojak, L.; Kubinec, R.; Jurdakova, H.; Hajekova, E.; Bajus, M., GC-MS of polyethylene and polypropylene thermal cracking produxts, Petroleum Coal, 2006, 48, 1, 1-14. [all data]

Junkes, Castanho, et al., 2003
Junkes, B.S.; Castanho, R.D.M.; Amboni, C.; Yunes, R.A.; Heinzen, V.E.F., Semiempirical Topological Index: A Novel Molecular Descriptor for Quantitative Structure-Retention Relationship Studies, Internet Electronic Journal of Molecular Design, 2003, 2, 1, 33-49. [all data]


Notes

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