silicon carbide


Solid Phase Heat Capacity (Shomate Equation)

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Cp° = A + B*t + C*t2 + D*t3 + E/t2
H° − H°298.15= A*t + B*t2/2 + C*t3/3 + D*t4/4 − E/t + F − H
S° = A*ln(t) + B*t + C*t2/2 + D*t3/3 − E/(2*t2) + G
    Cp = heat capacity (cal/mol*K)
    H° = standard enthalpy (kcal/mol)
    S° = standard entropy (cal/mol*K)
    t = temperature (K) / 1000.

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Temperature (K) 298. - 1000.1000. - 4000.298. - 1100.1100. - 4000.
A 4.91362111.209904.89964011.52540
B 15.434901.39722015.146201.196021
C -12.66450-0.259419-11.84040-0.247991
D 4.0530910.0222333.5439800.020636
E -0.186866-0.824301-0.181637-0.935070
F -19.77460-22.81720-20.14660-23.53380
G 4.75824113.617404.85403013.80550
H -17.09990-17.09990-17.50000-17.50000
ReferenceChase, 1998Chase, 1998Chase, 1998Chase, 1998
Comment α phase; Data last reviewed in March, 1966 α phase; Data last reviewed in March, 1966 β phase; Data last reviewed in March, 1966 β phase; Data last reviewed in March, 1966
Temperature
(K)
Cp
(cal/mol*K)

(cal/mol*K)
-(G° - H°298.15)/T
(cal/mol*K)
H° - H°298.15
(kcal/mol)
298.6.393.933.94-0.00
300.6.443.983.940.01
400.8.156.094.220.75
500.9.228.034.791.62
600.9.979.785.482.58
700.10.5211.366.213.61
800.10.9412.796.944.68
900.11.2714.107.675.79
1000.11.5515.318.376.94
Temperature
(K)
Cp
(cal/mol*K)

(cal/mol*K)
-(G° - H°298.15)/T
(cal/mol*K)
H° - H°298.15
(kcal/mol)
1000.11.5515.308.376.93
1100.11.7816.429.058.10
1200.11.9817.459.719.29
1300.12.1518.4210.3410.50
1400.12.3019.3210.9511.72
1500.12.4320.1711.5412.96
1600.12.5520.9812.1014.20
1700.12.6621.7512.6515.46
1800.12.7622.4713.1716.74
1900.12.8523.1613.6818.02
2000.12.9423.8314.1719.31
2100.13.0224.4614.6520.60
2200.13.0925.0715.1121.91
2300.13.1725.6515.5523.22
2400.13.2326.2115.9924.54
2500.13.3026.7516.4125.87
2600.13.3627.2816.8127.20
2700.13.4227.7817.2128.54
2800.13.4728.2717.6029.89
2900.13.5228.7417.9731.24
3000.13.5829.2018.3432.59
3100.13.6229.6518.7033.95
3200.13.6730.0819.0535.32
3300.13.7230.5019.3936.68
3400.13.7630.9119.7238.06
3500.13.8131.3120.0539.44
3600.13.8531.7020.3640.82
3700.13.8932.0820.6842.21
3800.13.9432.4520.9843.60
3900.13.9832.8221.2844.99
4000.14.0233.1721.5746.39
Temperature
(K)
Cp
(cal/mol*K)

(cal/mol*K)
-(G° - H°298.15)/T
(cal/mol*K)
H° - H°298.15
(kcal/mol)
298.6.413.963.97-0.00
300.6.464.013.970.01
400.8.166.124.250.75
500.9.238.064.821.62
600.9.999.825.512.58
700.10.5511.406.243.61
800.10.9712.846.974.69
900.11.3014.157.705.80
1000.11.5715.358.416.95
1100.11.8016.479.098.12
Temperature
(K)
Cp
(cal/mol*K)

(cal/mol*K)
-(G° - H°298.15)/T
(cal/mol*K)
H° - H°298.15
(kcal/mol)
1100.11.8016.479.098.12
1200.11.9917.509.759.30
1300.12.1518.4710.3810.51
1400.12.2919.3710.9911.73
1500.12.4220.2211.5812.97
1600.12.5221.0312.1414.22
1700.12.6221.7912.6915.47
1800.12.7122.5213.2116.74
1900.12.7923.2013.7218.02
2000.12.8623.8614.2119.30
2100.12.9224.4914.6920.59
2200.12.9825.0915.1521.88
2300.13.0425.6715.5923.18
2400.13.0926.2316.0224.49
2500.13.1426.7616.4425.80
2600.13.1827.2816.8527.12
2700.13.2227.7817.2528.44
2800.13.2628.2617.6329.76
2900.13.3028.7318.0031.09
3000.13.3329.1818.3732.42
3100.13.3729.6118.7333.76
3200.13.4030.0419.0735.10
3300.13.4330.4519.4136.44
3400.13.4630.8519.7437.78
3500.13.4831.2420.0639.13
3600.13.5131.6220.3840.48
3700.13.5331.9920.6941.83
3800.13.5632.3620.9943.18
3900.13.5832.7121.2944.54
4000.13.6033.0521.5845.90

References

Go To: Top, Solid Phase Heat Capacity (Shomate Equation), Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Chase, 1998
Chase, M.W., Jr., NIST-JANAF Themochemical Tables, Fourth Edition, J. Phys. Chem. Ref. Data, Monograph 9, 1998, 1-1951. [all data]


Notes

Go To: Top, Solid Phase Heat Capacity (Shomate Equation), References