2,2,2-trifluoro-N-(trifluoroacetyl)acetamide


Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

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Individual Reactions

C4F6NO2- + Hydrogen cation = C4HF6NO2

By formula: C4F6NO2- + H+ = C4HF6NO2

Quantity Value Units Method Reference Comment
Δr314.4 ± 2.2kcal/molG+TSKoppel, Taft, et al., 1994gas phase
Quantity Value Units Method Reference Comment
Δr307.5 ± 2.0kcal/molIMRELeito, Raamat, et al., 2009gas phase
Δr307.5 ± 2.0kcal/molIMREKoppel, Taft, et al., 1994gas phase

Gas phase ion energetics data

Go To: Top, Reaction thermochemistry data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

De-protonation reactions

C4F6NO2- + Hydrogen cation = C4HF6NO2

By formula: C4F6NO2- + H+ = C4HF6NO2

Quantity Value Units Method Reference Comment
Δr314.4 ± 2.2kcal/molG+TSKoppel, Taft, et al., 1994gas phase
Quantity Value Units Method Reference Comment
Δr307.5 ± 2.0kcal/molIMRELeito, Raamat, et al., 2009gas phase
Δr307.5 ± 2.0kcal/molIMREKoppel, Taft, et al., 1994gas phase

References

Go To: Top, Reaction thermochemistry data, Gas phase ion energetics data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Koppel, Taft, et al., 1994
Koppel, I.A.; Taft, R.W.; Anvia, F.; Zhu, S.Z.; Hu, L.Q.; Sung, K.S.; Desmarteau, D.D.; Yagupolskii, L.M., The Gas-Phase Acidities of Very Strong Neutral Bronsted Acids, J. Am. Chem. Soc., 1994, 116, 7, 3047, https://doi.org/10.1021/ja00086a038 . [all data]

Leito, Raamat, et al., 2009
Leito, I.; Raamat, E.; Kutt, A.; Saame, J.; Kipper, K.; Koppel, I.A.; Koppel, I.; Zhang, M.; Mishima, M.; Yagupolskii, L.M.; Garlyauskayte, R.Y.; Filatov, A.A., Revision of the Gas-Phase Acidity Scale below 300 kcal mol(-1), J. Phys. Chem. A, 2009, 113, 29, 8421-8424, https://doi.org/10.1021/jp903780k . [all data]


Notes

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