Butane, 2,3-dimethyl-2,3-dinitro-

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Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Quantity Value Units Method Reference Comment
Δfsolid-311. ± 1.kJ/molCcbLebedeva and Ryadnenko, 1968 
Quantity Value Units Method Reference Comment
Δcsolid-3765. ± 1.kJ/molCcbLebedeva and Ryadnenko, 1968 
Δcsolid-3855.1 ± 6.7kJ/molCcbMiller and Hunt, 1945Reanalyzed by Cox and Pilcher, 1970, Original value = -3858. ± 6.7 kJ/mol

Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: William E. Acree, Jr., James S. Chickos

Quantity Value Units Method Reference Comment
Δsub79.5 ± 0.8kJ/molN/AMiroshnichenko and Vorob'eva, 1999 

Enthalpy of sublimation

ΔsubH (kJ/mol) Temperature (K) Method Reference Comment
85. ± 2.303. to 330.MESmirnov, Matiushin, et al., 1994See also Jones, Lightfoot, et al., 2002.

Enthalpy of fusion

ΔfusH (kJ/mol) Temperature (K) Reference
8.8473.Jones, Lightfoot, et al., 2002

Mass spectrum (electron ionization)

Go To: Top, Condensed phase thermochemistry data, Phase change data, Gas Chromatography, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Spectrum

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Mass spectrum
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Additional Data

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Owner NIST Mass Spectrometry Data Center
Collection (C) 2014 copyright by the U.S. Secretary of Commerce
on behalf of the United States of America. All rights reserved.
Origin Japan AIST/NIMC Database- Spectrum MS-NW-6356
NIST MS number 235165

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Gas Chromatography

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Normal alkane RI, non-polar column, temperature ramp

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Column type Active phase I Reference Comment
CapillaryZB-11126.Harvey and Wenzel, 200915. m/0.25 mm/0.10 μm, Helium, 4. K/min, 185. C @ 15. min; Tstart: 35. C
CapillaryZB-11128.Harvey and Wenzel, 200915. m/0.25 mm/0.10 μm, Helium, 4. K/min, 185. C @ 15. min; Tstart: 35. C
CapillaryZB-11154.Harvey and Wenzel, 200915. m/0.25 mm/0.10 μm, Helium, 4. K/min, 185. C @ 15. min; Tstart: 35. C

References

Go To: Top, Condensed phase thermochemistry data, Phase change data, Mass spectrum (electron ionization), Gas Chromatography, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Lebedeva and Ryadnenko, 1968
Lebedeva, N.D.; Ryadnenko, V.L., Heats of combustion and formation of polynitroalkanes, Russ. J. Phys. Chem. (Engl. Transl.), 1968, 42, 1225-1227. [all data]

Miller and Hunt, 1945
Miller, A.J.; Hunt, H., Heats of combustion. III The heats of combustion of some polynitroparaffins, J. Phys. Chem., 1945, 49, 20-21. [all data]

Cox and Pilcher, 1970
Cox, J.D.; Pilcher, G., Thermochemistry of Organic and Organometallic Compounds, Academic Press, New York, 1970, 1-636. [all data]

Miroshnichenko and Vorob'eva, 1999
Miroshnichenko, E.O.; Vorob'eva, V.P., Thermochemical characteristics of nitroalkanes, Zh. Fiz. Khim., 1999, 73, 3, 419. [all data]

Smirnov, Matiushin, et al., 1994
Smirnov, S.P.; Matiushin, Y.N.; Akmetov, I.Z., , Conf. International Civil Aviation Organization, 14-18 February, paper No. AH-DE/8-WP/12, Montreal, Canada, 1994. [all data]

Jones, Lightfoot, et al., 2002
Jones, D.E.G.; Lightfoot, P.D.; Fouchard, R.C.; Kwok, Q.S.M., Thermal properties of DMNB, a detection agent for explosives, Thermochimica Acta, 2002, 388, 1-2, 159-173, https://doi.org/10.1016/S0040-6031(02)00033-3 . [all data]

Harvey and Wenzel, 2009
Harvey, S.D.; Wenzel, T.J., Selective retention of explosives and related compounds on gas-chromatographic capillary columns coated with lanthanide(III) beta-diketonate polymers, J. Chromatogr. A, 2009, 1216, 36, 6417-6423, https://doi.org/10.1016/j.chroma.2009.07.008 . [all data]


Notes

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