Propanoic acid, 2,2-dimethyl-, ethyl ester
- Formula: C7H14O2
- Molecular weight: 130.1849
- IUPAC Standard InChIKey: HHEIMYAXCOIQCJ-UHFFFAOYSA-N
- CAS Registry Number: 3938-95-2
- Chemical structure:
This structure is also available as a 2d Mol file or as a computed 3d SD file
The 3d structure may be viewed using Java or Javascript. - Other names: Pivalic acid, ethyl ester; Ethyl pivalate; Ethyl 2,2-dimethylpropionate; Trimethylacetic acid, ethyl ester; 2,2-Dimethylpropanoic acid ethyl ester; Ethyl trimethylacetate; 2,2-Dimethylpropionic acid, ethyl ester; Ethyl 2,2-dimethylpropanoate; NSC 17494
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Condensed phase thermochemistry data
Go To: Top, Phase change data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DH - Eugene S. Domalski and Elizabeth D. Hearing
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔfH°liquid | -566.8 ± 1.0 | kJ/mol | Ccb | Verevkin, Beckhaus, et al., 1992 | See 90BEC/VER; ALS |
ΔfH°liquid | -577.2 ± 8.4 | kJ/mol | Ccb | Hancock, Watson, et al., 1954 | Reanalyzed by Cox and Pilcher, 1970, Original value = -577. kJ/mol; ALS |
Quantity | Value | Units | Method | Reference | Comment |
ΔcH°liquid | -4188.5 ± 1.0 | kJ/mol | Ccb | Verevkin, Beckhaus, et al., 1992 | See 90BEC/VER; Corresponding ΔfHºliquid = -566.85 kJ/mol (simple calculation by NIST; no Washburn corrections); ALS |
ΔcH°liquid | -4178.1 ± 8.4 | kJ/mol | Ccb | Hancock, Watson, et al., 1954 | Reanalyzed by Cox and Pilcher, 1970, Original value = -4180. kJ/mol; Corresponding ΔfHºliquid = -577.22 kJ/mol (simple calculation by NIST; no Washburn corrections); ALS |
Constant pressure heat capacity of liquid
Cp,liquid (J/mol*K) | Temperature (K) | Reference | Comment |
---|---|---|---|
277.8 | 298.15 | Verevkin, Beckhaus, et al., 1992 | DH |
251.3 | 298.15 | Nilsson and Wadso, 1986 | DH |
Phase change data
Go To: Top, Condensed phase thermochemistry data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
BS - Robert L. Brown and Stephen E. Stein
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny director
DRB - Donald R. Burgess, Jr.
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
AC - William E. Acree, Jr., James S. Chickos
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
Tboil | 391.2 | K | N/A | Weast and Grasselli, 1989 | BS |
Tboil | 391.55 | K | N/A | Hancock, Watson, et al., 1954, 2 | Uncertainty assigned by TRC = 0.4 K; TRC |
Tboil | 391.5 | K | N/A | Howard, Mears, et al., 1947 | Uncertainty assigned by TRC = 0.1 K; TRC |
Tboil | 389.65 | K | N/A | Whitmore, 1938 | Uncertainty assigned by TRC = 2. K; TRC |
Quantity | Value | Units | Method | Reference | Comment |
Tfus | 183.6 | K | N/A | Howard, Mears, et al., 1947 | Uncertainty assigned by TRC = 0.1 K; TRC |
Quantity | Value | Units | Method | Reference | Comment |
ΔvapH° | 41.2 | kJ/mol | N/A | Verevkin, Beckhaus, et al., 1992 | DRB |
ΔvapH° | 41.3 ± 0.1 | kJ/mol | C | Wadso, 1966 | ALS |
ΔvapH° | 4150. | kJ/mol | C | Pawlenko, 1963 | ALS |
Enthalpy of vaporization
ΔvapH (kJ/mol) | Temperature (K) | Method | Reference | Comment |
---|---|---|---|---|
39.8 ± 0.1 | 320. | EB | Steele, Chirico, et al., 2002 | Based on data from 308. to 429. K.; AC |
36.9 ± 0.2 | 360. | EB | Steele, Chirico, et al., 2002 | Based on data from 308. to 429. K.; AC |
33.8 ± 0.6 | 400. | EB | Steele, Chirico, et al., 2002 | Based on data from 308. to 429. K.; AC |
References
Go To: Top, Condensed phase thermochemistry data, Phase change data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Verevkin, Beckhaus, et al., 1992
Verevkin, S.P.; Beckhaus, H.-D.; Ruchardt, C.,
Geminale substituenteneffekte Teil 5α. Standardbildungsenthalpien von alkylsubstituierten Malonsaure- und α-aminocarbonsaureestern,
Thermochim. Acta, 1992, 197, 27-39. [all data]
Hancock, Watson, et al., 1954
Hancock, C.K.; Watson, G.M.; Gilby, R.F.,
Heats of combustion of five-carbon fatty acids and their methyl and ethyl esters,
J. Phys. Chem., 1954, 58, 127-129. [all data]
Cox and Pilcher, 1970
Cox, J.D.; Pilcher, G.,
Thermochemistry of Organic and Organometallic Compounds, Academic Press, New York, 1970, 1-636. [all data]
Nilsson and Wadso, 1986
Nilsson, S.-O.; Wadso, I.,
Thermodynamic properties of some mono-, di-, and tri esters. Enthalpies of solution in water at 288.15 to 318.15 K and enthalpies of vaporization and heat capacities at 298.15 K,
J. Chem. Thermodyn., 1986, 18, 673-681. [all data]
Weast and Grasselli, 1989
CRC Handbook of Data on Organic Compounds, 2nd Editon, Weast,R.C and Grasselli, J.G., ed(s)., CRC Press, Inc., Boca Raton, FL, 1989, 1. [all data]
Hancock, Watson, et al., 1954, 2
Hancock, C.K.; Watson, G.M.; Gilby, R.F.,
Heats of Combustion of Five-Carbon Fatty Acids and Their Methyl and Ethyl Esters,
J. Phys. Chem., 1954, 58, 127. [all data]
Howard, Mears, et al., 1947
Howard, F.L.; Mears, T.W.; Fookson, A.; Pomerantz, P.; Brooks, D.B.,
Preparation and physical properties of several aliphatic hydrocarbons and intermediates,
J. Res. Natl. Bur. Stand. (U. S.), 1947, 38, 365. [all data]
Whitmore, 1938
Whitmore, F.C.,
The Reducing Action of Grignard Reagents on Acyl Chlorides,
Recl. Trav. Chim. Pays-Bas, 1938, 57, 562. [all data]
Wadso, 1966
Wadso, I.,
Acta Chem. Scand., 1966, 20, 544. [all data]
Pawlenko, 1963
Pawlenko, S.,
Kennzahlen und IR-Spektren Einiger Pivalinsaureester,
Liebigs Ann. Chem., 1963, 663, 8-11. [all data]
Steele, Chirico, et al., 2002
Steele, W.V.; Chirico, R.D.; Cowell, A.B.; Knipmeyer, S.E.; Nguyen, A.,
Thermodynamic Properties and Ideal-Gas Enthalpies of Formation for trans -Methyl Cinnamate, α-Methyl Cinnamaldehyde, Methyl Methacrylate, 1-Nonyne, Trimethylacetic Acid, Trimethylacetic Anhydride, and Ethyl Trimethyl Acetate,
J. Chem. Eng. Data, 2002, 47, 4, 700-714, https://doi.org/10.1021/je010086r
. [all data]
Notes
Go To: Top, Condensed phase thermochemistry data, Phase change data, References
- Symbols used in this document:
Cp,liquid Constant pressure heat capacity of liquid Tboil Boiling point Tfus Fusion (melting) point ΔcH°liquid Enthalpy of combustion of liquid at standard conditions ΔfH°liquid Enthalpy of formation of liquid at standard conditions ΔvapH Enthalpy of vaporization ΔvapH° Enthalpy of vaporization at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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