Bis(η5-cyclopentadienyl)dimethyl tungsten


Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: José A. Martinho Simões

Quantity Value Units Method Reference Comment
Δfgas346.2 ± 8.7kJ/molReviewMartinho SimõesThe enthalpy of formation relies on -63.1 ± 7.2 kJ/mol for the enthalpy of formation of W(Cp)2(Cl)2(cr)

Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: José A. Martinho Simões

Quantity Value Units Method Reference Comment
Δfsolid271.6 ± 7.6kJ/molReviewMartinho SimõesThe enthalpy of formation relies on -63.1 ± 7.2 kJ/mol for the enthalpy of formation of W(Cp)2(Cl)2(cr)

Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: José A. Martinho Simões

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Individual Reactions

C12H16W (cr) + 2(Hydrogen chloride • 5.55Water) (solution) = C10H10Cl2W (cr) + 2Methane (g)

By formula: C12H16W (cr) + 2(HCl • 5.55H2O) (solution) = C10H10Cl2W (cr) + 2CH4 (g)

Quantity Value Units Method Reference Comment
Δr-169.9 ± 2.3kJ/molRSCCalado, Dias, et al., 1978Please also see Calhorda, Dias, et al., 1987.

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Martinho Simões
Martinho Simões, J.A., Private communication (see http://webbook.nist.gov/chemistry/om/). [all data]

Calado, Dias, et al., 1978
Calado, J.C.G.; Dias, A.R.; Martinho Simões, J.A.; Ribeiro da Silva, M.A.V., J. Chem. Soc., Chem. Commun., 1978, 737.. [all data]

Calhorda, Dias, et al., 1987
Calhorda, M.J.; Dias, A.R.; Minas da Piedade M.E.; Salema, M.S.; Martinho Simões J.A., Organometallics, 1987, 6, 734. [all data]


Notes

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