Diazene, diisopropyl
- Formula: C6H14N2
- Molecular weight: 114.1888
- IUPAC Standard InChI: InChI=1S/C6H14N2/c1-5(2)7-8-6(3)4/h5-6H,1-4H3
- IUPAC Standard InChIKey: BXCOOPLIKAAONJ-UHFFFAOYSA-N
- CAS Registry Number: 3880-49-7
- Chemical structure:
This structure is also available as a 2d Mol file or as a computed 3d SD file
The 3d structure may be viewed using Java or Javascript. - Stereoisomers:
- Other names: 1,2-Diisopropyldiazene
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Gas phase thermochemistry data
Go To: Top, Condensed phase thermochemistry data, Phase change data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔfH°gas | 36. | kJ/mol | Ccb | Engel, Wood, et al., 1974 | see Engel, Melaugh, et al., 1976 |
Condensed phase thermochemistry data
Go To: Top, Gas phase thermochemistry data, Phase change data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔfH°liquid | -0.1 ± 0.79 | kJ/mol | Ccb | Engel, Wood, et al., 1974 | Reanalyzed by Pedley, Naylor, et al., 1986, Original value = -0.3 kJ/mol; see Engel, Melaugh, et al., 1976 |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔcH°liquid | -4361.74 ± 0.71 | kJ/mol | Ccb | Engel, Wood, et al., 1974 | see Engel, Melaugh, et al., 1976 |
| ΔcH°liquid | -4406.2 ± 1.3 | kJ/mol | Ccb | Coates and Sutton, 1948 | Reanalyzed by Cox and Pilcher, 1970, Original value = -4407. ± 1. kJ/mol |
Phase change data
Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
AC - William E. Acree, Jr., James S. Chickos
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DRB - Donald R. Burgess, Jr.
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔvapH° | 35.9 ± 0.4 | kJ/mol | C | Engel, Melaugh, et al., 1976 | AC |
| ΔvapH° | 36.2 | kJ/mol | V | Engel, Wood, et al., 1974 | see Engel, Melaugh, et al., 1976; ALS |
| ΔvapH° | 36.1 | kJ/mol | N/A | Engel, Wood, et al., 1974 | DRB |
Enthalpy of vaporization
| ΔvapH (kJ/mol) | Temperature (K) | Method | Reference | Comment |
|---|---|---|---|---|
| 36.1 | 302. | UV | Engel, Wood, et al., 1974 | Based on data from 296. to 308. K.; AC |
| 36. ± 2. | 293. | V | Coates and Sutton, 1948 | ALS |
References
Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Engel, Wood, et al., 1974
Engel, P.S.; Wood, J.L.; Sweet, J.A.; Margrave, J.L.,
Thermochemistry of azoalkanes,
J. Am. Chem. Soc., 1974, 96, 2381-2387. [all data]
Engel, Melaugh, et al., 1976
Engel, P.S.; Melaugh, R.A.; Mansson, M.; Timberlake, J.W.; Garner, A.W.; Rossini, F.D.,
Thermochemistry of nine diazenes (azo compounds),
J. Chem. Thermodyn., 1976, 8, 607-621. [all data]
Pedley, Naylor, et al., 1986
Pedley, J.B.; Naylor, R.D.; Kirby, S.P.,
Thermochemical Data of Organic Compounds, Chapman and Hall, New York, 1986, 1-792. [all data]
Coates and Sutton, 1948
Coates, G.E.; Sutton, L.E.,
The heats of formation of the -N=N- and >C=N- bonds,
J. Chem. Soc., 1948, 1187-1196. [all data]
Cox and Pilcher, 1970
Cox, J.D.; Pilcher, G.,
Thermochemistry of Organic and Organometallic Compounds, Academic Press, New York, 1970, 1-636. [all data]
Notes
Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, References
- Symbols used in this document:
ΔcH°liquid Enthalpy of combustion of liquid at standard conditions ΔfH°gas Enthalpy of formation of gas at standard conditions ΔfH°liquid Enthalpy of formation of liquid at standard conditions ΔvapH Enthalpy of vaporization ΔvapH° Enthalpy of vaporization at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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