Triphenylphosphine sulfide


Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: William E. Acree, Jr., James S. Chickos

Quantity Value Units Method Reference Comment
Δsub34.1 ± 1.6kcal/molN/AKirklin, Chickos, et al., 1996 

Enthalpy of sublimation

ΔsubH (kcal/mol) Temperature (K) Method Reference Comment
32.7 ± 1.5403.HSAKirklin, Chickos, et al., 1996Based on data from 388. to 419. K.

Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data evaluated by: Edward P. Hunter and Sharon G. Lias

Quantity Value Units Method Reference Comment
Proton affinity (review)216.6kcal/molN/AHunter and Lias, 1998 
Quantity Value Units Method Reference Comment
Gas basicity209.5kcal/molN/AHunter and Lias, 1998 

Mass spectrum (electron ionization)

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Spectrum

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Mass spectrum
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Additional Data

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Owner NIST Mass Spectrometry Data Center
Collection (C) 2014 copyright by the U.S. Secretary of Commerce
on behalf of the United States of America. All rights reserved.
Origin Japan AIST/NIMC Database- Spectrum MS-NW-6725
NIST MS number 235653

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References

Go To: Top, Phase change data, Gas phase ion energetics data, Mass spectrum (electron ionization), Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Kirklin, Chickos, et al., 1996
Kirklin, Duane R.; Chickos, James S.; Liebman, Joel F., Enthalpy of formation of triphenylphosphine sulfide, Struct Chem, 1996, 7, 5-6, 355-361, https://doi.org/10.1007/BF02275161 . [all data]

Hunter and Lias, 1998
Hunter, E.P.; Lias, S.G., Evaluated Gas Phase Basicities and Proton Affinities of Molecules: An Update, J. Phys. Chem. Ref. Data, 1998, 27, 3, 413-656, https://doi.org/10.1063/1.556018 . [all data]


Notes

Go To: Top, Phase change data, Gas phase ion energetics data, Mass spectrum (electron ionization), References