tris(2,2,6,6-tetramethyl-3,5-heptanedionato)ruthenium(III)
- Formula: C33H57O6Ru
- Molecular weight: 650.87
- CAS Registry Number: 38625-54-6
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Phase change data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: William E. Acree, Jr., James S. Chickos
Enthalpy of sublimation
| ΔsubH (kJ/mol) | Temperature (K) | Method | Reference |
|---|---|---|---|
| 149.2 ± 2.2 | 353. to 393. | ME | Morozova, Zherikova, et al., 2009 |
Gas phase ion energetics data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: John E. Bartmess
Electron affinity determinations
| EA (eV) | Method | Reference | Comment |
|---|---|---|---|
| 1.960 ± 0.065 | IMRB | Sharpe, Alameddin, et al., 1994 | EA given is actually -ΔGea(350 K) |
References
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Morozova, Zherikova, et al., 2009
Morozova, N.B.; Zherikova, K.V.; Semyannikov, P.P.; Trubin, S.V.; Igumenov, I.K.,
Study of temperature dependencies of saturated vapor pressure of ruthenium(III) beta-diketonate derivatives,
J Therm Anal Calorim, 2009, 98, 2, 395-399, https://doi.org/10.1007/s10973-009-0309-8
. [all data]
Sharpe, Alameddin, et al., 1994
Sharpe, P.; Alameddin, N.G.; Richardson, D.E.,
Alkyl Substituent Effects in the Redox Thermochemistry of Coordination Compounds: Oxidation and Reduction Energetics for Ruthenium tris(b-diketonate) Complexes,
J. Am. Chem. Soc., 1994, 116, 24, 11098, https://doi.org/10.1021/ja00103a027
. [all data]
Notes
Go To: Top, Phase change data, Gas phase ion energetics data, References
- Symbols used in this document:
EA Electron affinity ΔsubH Enthalpy of sublimation - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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