α-Copaene

Formula: C₁₅H₂₄
Molecular weight: 204.3511
IUPAC Standard InChI: InChI=1S/C15H24/c1-9(2)11-7-8-15(4)12-6-5-10(3)14(15)13(11)12/h5,9,11-14H,6-8H2,1-4H3
IUPAC Standard InChIKey: VLXDPFLIRFYIME-UHFFFAOYSA-N
CAS Registry Number: 3856-25-5
Chemical structure:
This structure is also available as a 2d Mol file or as a computed 3d SD file
The 3d structure may be viewed using Java or Javascript.
Stereoisomers:
- Ylangene
- trans-α-Copaene
Other names: Copaene; Tricyclo[4.4.0.02,7]dec-3-ene, 1,3-dimethyl-8-(1-methylethyl)-, stereoisomer; Tricyclo[4.4.0.02,7]dec-3-ene, 8-isopropyl-1,3-dimethyl-, (1R,2S,6S,7S,8S)-(-)-; (-)-α-Copaene; Copaen; Tricyclo[4.4.0.0(2,7)]dec-3-ene, 1,3-dimethyl-8-(1-methylethyl)-, st; Aglaiene; Tricyclo[4.4.0.0(2,7)]dec-3-ene, 8-isopropyl-1,3-dimethyl-; Tricyclo[4.4.0.0(2,7)]dec-3-ene, 8-isopropyl-1,3-dimethyl-, (1R,2S,6S,7S,8S)-; 8-isopropyl-1,3-dimethyltricyclo[4.4.0.02,7]dec-3-ene
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Information on this page:
Other data available:
- Mass spectrum (electron ionization)
- Gas Chromatography
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Van Den Dool and Kratz RI, non-polar column, temperature ramp

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Column type	Capillary	Capillary	Capillary	Capillary	Capillary
Active phase	DB-5	HP-5MS	CP-Sil PONA GB	HP-5	SPB-5
Column length (m)	30.	30.	100.	25.	60.
Carrier gas	He	He	He	He
Substrate
Column diameter (mm)	0.25	0.25	0.25	0.25	0.32
Phase thickness (μm)	0.25	0.25	0.25	0.25	1.
T_start (C)	60.	60.	140.	60.	40.
T_end (C)	240.	250.	230.	240.	230.
Heat rate (K/min)	3.	2.	5.	4.	3.
Initial hold (min)		8.	10.	2.	2.
Final hold (min)		30.	25.		10.
I	1377.	1375.	1397.	1382.	1402.
Reference	Baccouri, Ben Temime, et al., 2007	Benkaci-Ali, Baaliouamer, et al., 2007	Cunicao, Lopes, et al., 2007	Dehghan, Solaimanian, et al., 2007	Engel and Ratel, 2007
Comment	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI

Column type	Capillary	Capillary	Capillary	Capillary	Capillary
Active phase	DB-5	HP-5MS	BP-1	DB-5	DB-5
Column length (m)	30.	30.	50.	30.	30.
Carrier gas	He	He	He	He	He
Substrate
Column diameter (mm)	0.25	0.25	0.22	0.25	0.25
Phase thickness (μm)	0.25	0.25	0.25	0.25	0.25
T_start (C)	60.	60.	60.	60.	60.
T_end (C)	240.	280.	220.	240.	240.
Heat rate (K/min)	3.	3.	2.	3.	3.
Initial hold (min)
Final hold (min)			20.
I	1377.	1379.	1376.	1376.	1376.
Reference	Flamini, Cioni, et al., 2007	Kundakovic, Fokialakis, et al., 2007	Lesueur, de Rocca Serra, et al., 2007	Maccioni, Baldini, et al., 2007	Maccioni, Baldini, et al., 2007
Comment	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI

Column type	Capillary	Capillary	Capillary	Capillary	Capillary
Active phase	DB-5	RTX-1	RTX-1	HP-5	SPB-1
Column length (m)	30.	60.	60.	30.	30.
Carrier gas		He	He	He	He
Substrate
Column diameter (mm)	0.22	0.22	0.22	0.25	0.25
Phase thickness (μm)	0.25	0.25	0.25	0.25	0.25
T_start (C)	60.	60.	60.	50.	50.
T_end (C)	240.	230.	230.	250.	250.
Heat rate (K/min)	3.	2.	2.	4.	5.
Initial hold (min)	2.			4.	3.
Final hold (min)		30.	35.	10.	15.
I	1378.	1374.	1377.	1376.	1366.
Reference	Martins, Santos, et al., 2007	Muselli, Rossi, et al., 2007	Paolini, Muselli, et al., 2007	Quijano, Salamanca, et al., 2007	Radulovic, Lazarevic, et al., 2007
Comment	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI

Column type	Capillary	Capillary	Capillary	Capillary	Capillary
Active phase	HP-5MS	DB-5	DB-5	HP-5MS	ZB-5
Column length (m)	30.	25.	30.	30.	30.
Carrier gas	He	He	He	He	He
Substrate
Column diameter (mm)	0.25	0.25	0.25	0.25	0.25
Phase thickness (μm)	0.25	0.25	0.25	0.25	0.25
T_start (C)	60.	60.	60.	60.	50.
T_end (C)	280.	200.	260.	280.	250.
Heat rate (K/min)	4.	2.	5.	4.	3.
Initial hold (min)	5.			5.
Final hold (min)		60.
I	1375.	1372.	1383.	1375.	1375.
Reference	Radulovic, Lazarevic, et al., 2007	Rout, Rao, et al., 2007	Sabulal, Dan, et al., 2007	Saroglou, Marin, et al., 2007	Simoniatto, Bonani, et al., 2007
Comment	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI

Column type	Capillary	Capillary	Capillary	Capillary	Capillary
Active phase	DB-1	DB-5	HP-5MS	DB-5	CP Sil 5 CB
Column length (m)	60.	30.	30.	30.	30.
Carrier gas	N2	He	He	He	N2
Substrate
Column diameter (mm)	0.25	0.25	0.25	0.25	0.25
Phase thickness (μm)	0.25	0.25	0.25	0.25	0.25
T_start (C)	60.	60.	60.	50.	50.
T_end (C)	250.	240.	280.	250.	200.
Heat rate (K/min)	5.	3.	3.	3.	5.
Initial hold (min)
Final hold (min)	10.			10.
I	1383.	1376.	1372.	1373.	1370.
Reference	Sonboli, Azizian, et al., 2007	Telascrea, de Araujo, et al., 2007	Vagionas, Ngassapa, et al., 2007	Yu, Liao, et al., 2007	Andrianoelisoa H.S., Menut C., et al., 2006
Comment	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI

Column type	Capillary	Capillary	Capillary	Capillary	Capillary
Active phase	HP-5MS	BP-1	SPB-1	DB-5	DB-5
Column length (m)	30.	50.	30.	30.	30.
Carrier gas	He		He	He	He
Substrate
Column diameter (mm)	0.25	0.22	0.25	0.2	0.25
Phase thickness (μm)	0.25	0.25	0.25	0.25	0.25
T_start (C)	60.	60.	50.	50.	60.
T_end (C)	280.	220.	250.	250.	240.
Heat rate (K/min)	3.	2.	5.	5.	3.
Initial hold (min)			3.	3.
Final hold (min)		20.	15.	15.
I	1353.	1381.	1365.	1372.	1376.
Reference	Basta, Tzakou, et al., 2006	Blanc, Bradesi, et al., 2006	Blagojevic, Radulovic, et al., 2006	Blagojevic, Radulovic, et al., 2006	Block, Flamini, et al., 2006
Comment	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI

Column type	Capillary	Capillary	Capillary	Capillary	Capillary
Active phase	BP-1	DB-5	RTX-1	HP-5MS	5 % Phenyl methyl siloxane
Column length (m)	50.	30.	60.	30.	25.
Carrier gas	He		He	He	He
Substrate
Column diameter (mm)	0.22	0.25	0.22	0.25	0.25
Phase thickness (μm)	0.25	1.	0.25	0.25	0.25
T_start (C)	60.	50.	60.	60.	60.
T_end (C)	220.	290.	230.	280.	280.
Heat rate (K/min)	2.	10.	2.	3.	3.
Initial hold (min)		1.
Final hold (min)	20.	10.	45.		20.
I	1378.	1355.	1376.	1370.	1373.
Reference	Boti, Bighelli, et al., 2006	Bylaite and Meyer, 2006	Cavalli, Tomi, et al., 2006	Chorianopoulos N., Evergets E., et al., 2006	Djarri, Medjroubi, et al., 2006
Comment	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI

Column type	Capillary	Capillary	Capillary	Capillary	Capillary
Active phase	DB-5	DB-5	DB-5	HP-5	BP-1
Column length (m)	30.	30.	50.	30.	50.
Carrier gas	N2	N2	N2	N2	He
Substrate
Column diameter (mm)	0.32	0.25	0.2	0.25	0.22
Phase thickness (μm)	0.25	0.25	0.32	0.25	0.25
T_start (C)	60.	60.	60.	60.	60.
T_end (C)	240.	240.	220.	220.	220.
Heat rate (K/min)	3.	3.	5.	5.	2.
Initial hold (min)	3.	3.	3.	10.
Final hold (min)	5.	3.	5.		20.
I	1375.	1374.	1376.	1378.	1376.
Reference	Dob, Dahmane, et al., 2006	Dob, Dahmane, et al., 2006, 2	Esmaeili, Nematollahi, et al., 2006	Flamini, Tebano, et al., 2006	Gonny, Cavaleiro, et al., 2006
Comment	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI

Column type	Capillary	Capillary	Capillary	Capillary	Capillary
Active phase	HP-5	HP-5	DB-1	HP-5MS	HP-5
Column length (m)	30.	30.	30.	30.	30.
Carrier gas	He	He	N2	He	He
Substrate
Column diameter (mm)	0.25	0.25	0.25	0.25	0.25
Phase thickness (μm)	0.25	0.25	0.25	0.25	0.25
T_start (C)	60.	60.	50.	60.	60.
T_end (C)	260.	260.	220.	280.	250.
Heat rate (K/min)	3.	3.	4.	3.	10.
Initial hold (min)					2.
Final hold (min)					10.
I	1379.	1375.	1374.	1375.	1379.
Reference	Javidnia, Miri, et al., 2006	Javidnia K., Miri R., et al., 2006	Kuiate, Bessière, et al., 2006	Kukic J., Petrovic S., et al., 2006	Liu J.M., Nan P., et al., 2006
Comment	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI

Column type	Capillary	Capillary	Capillary	Capillary	Capillary
Active phase	DB-5	RTX-1	DB-5	HP-5	SPB-1
Column length (m)	50.	60.	30.	60.	30.
Carrier gas	N2	He	He	He	He
Substrate
Column diameter (mm)	0.2	0.22	0.32	0.25	0.2
Phase thickness (μm)	0.32	0.25	0.25	0.25	0.2
T_start (C)	60.	60.	60.	60.	70.
T_end (C)	220.	230.	280.	250.	220.
Heat rate (K/min)	5.	2.	3.	3.	3.
Initial hold (min)	3.
Final hold (min)	5.	35.			15.
I	1376.	1367.	1366.	1388.	1369.
Reference	Masoudi, Esmaeili, et al., 2006	Paolini J., Desjobert J.M., et al., 2006	Pavlovic, Tzakou, et al., 2006	Perraudin, Popovici, et al., 2006	Pinto, Pina-Vaz, et al., 2006
Comment	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI

Column type	Capillary	Capillary	Capillary	Capillary	Capillary
Active phase	SPB-1	SPB-1	DB-1	HP-5	OV-1
Column length (m)	30.	30.	30.	25.	25.
Carrier gas	He	He	He	He	He
Substrate
Column diameter (mm)	0.25	0.25	0.25	0.25	0.25
Phase thickness (μm)	0.25	0.25	0.25	0.25	0.25
T_start (C)	50.	50.	60.	60.	50.
T_end (C)	250.	250.	240.	240.	220.
Heat rate (K/min)	5.	5.	4.	4.	3.
Initial hold (min)	3.	3.			1.
Final hold (min)	15.	15.			5.
I	1366.	1366.	1371.	1378.	1376.
Reference	Radulovic, Lazarevic, et al., 2006	Radulovic, Mananjarasoa, et al., 2006	Rezazadeh, Hamedani, et al., 2006	Rezazadeh, Hamedani, et al., 2006	Rubiolo P., Matteodo M., et al., 2006
Comment	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI

Column type	Capillary	Capillary	Capillary	Capillary	Capillary
Active phase	HP-5MS	HP-5MS	DB-5	DB-5	HP-5MS
Column length (m)	30.	30.	30.	30.	30.
Carrier gas	He	He	He	He	H2
Substrate
Column diameter (mm)	0.25	0.25	0.25	0.25	0.25
Phase thickness (μm)	0.25	0.25	0.25	0.25	0.25
T_start (C)	60.	60.	50.	50.	50.
T_end (C)	280.	300.	250.	250.	285.
Heat rate (K/min)	4.	3.	5.	5.	4.3
Initial hold (min)	5.		2.	2.
Final hold (min)
I	1374.	1372.	1377.	1377.	1368.
Reference	Saroglou, Dorizas, et al., 2006	Silva-Brandão, Solferini, et al., 2006	Su, Ho, et al., 2006	Su, Ho, et al., 2006, 2	Vujisic L., Vuckovic I., et al., 2006
Comment	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI

Column type	Capillary	Capillary	Capillary	Capillary	Capillary
Active phase	HP-5	HP-5MS	CP Sil 5 CB	DB-1	SPB-1
Column length (m)	30.	30.	25.	30.	30.
Carrier gas	He	He	H2	N2	He
Substrate
Column diameter (mm)	0.25	0.25	0.25	0.25	0.25
Phase thickness (μm)	0.25	0.25		0.25	0.25
T_start (C)	40.	80.	80.	50.	50.
T_end (C)	300.	300.	270.	200.	250.
Heat rate (K/min)	4.	4.	10.	5.	5.
Initial hold (min)	5.				3.
Final hold (min)					15.
I	1372.	1416.8	1379.	1380.	1338.
Reference	Vundac, Pfeifhofer, et al., 2006	Zhao C.X., Li, et al., 2006	Ziegenbein, Hanssen, et al., 2006	Agnaniet, Makani, et al., 2005	Boskovic, Radulovic, et al., 2005
Comment	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI

Column type	Capillary	Capillary	Capillary	Capillary	Capillary
Active phase	DB-5	BP-1	SE-54	HP-5	DB-1
Column length (m)	30.	50.	50.	30.	30.
Carrier gas	He	He	H2	N2
Substrate
Column diameter (mm)	0.2	0.22	0.25	0.25	0.32
Phase thickness (μm)	0.25	0.25	0.27	0.25	0.25
T_start (C)	50.	60.	50.	60.	50.
T_end (C)	250.	220.	300.	220.	250.
Heat rate (K/min)	5.	2.	5.	5.	2.
Initial hold (min)	3.			10.	8.
Final hold (min)	15.	20.
I	1376.	1376.	1378.	1377.	1358.
Reference	Boskovic, Radulovic, et al., 2005	Boti J.B., Koukoua G., et al., 2005	Brantner, Pfeifhofer, et al., 2005	Celik, Gokturk, et al., 2005	Dob, Dahmane, et al., 2005
Comment	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI

Column type	Capillary	Capillary	Capillary	Capillary	Capillary
Active phase	MDN-5	DB-1	BP-1	HP-5	HP-5
Column length (m)	30.	30.	50.	30.	30.
Carrier gas	He	He	He	N2	N2
Substrate
Column diameter (mm)	0.25	0.25	0.22	0.25	0.25
Phase thickness (μm)	0.25	0.25	0.25	0.25	0.25
T_start (C)	50.	40.	60.	60.	60.
T_end (C)	250.	250.	220.	220.	220.
Heat rate (K/min)	3.	3.	2.	5.	5.
Initial hold (min)				10.	10.
Final hold (min)		20.	20.
I	1373.	1349.	1376.	1377.	1378.
Reference	Dugo, Mondello, et al., 2005	Fanciullino, Gancel, et al., 2005	Ferrari, Tomi, et al., 2005	Flamini, Luigi Cioni, et al., 2005	Flamini, Luigi Cioni, et al., 2005, 2
Comment	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI

Column type	Capillary	Capillary	Capillary	Capillary	Capillary
Active phase	DB-1	CP Sil 5 CB	DB-5	HP-5	HP-5
Column length (m)	30.	50.	25.	30.	30.
Carrier gas	He	H2	N2	He	He
Substrate
Column diameter (mm)	0.25	0.22	0.25	0.25	0.25
Phase thickness (μm)	0.25	0.13	0.25	0.25
T_start (C)	40.	40.	75.	60.	60.
T_end (C)	250.	300.	210.	260.	260.
Heat rate (K/min)	3.	4.	3.	3.	3.
Initial hold (min)			10.
Final hold (min)	20.	10.	1.
I	1355.	1366.	1376.	1376.	1376.
Reference	Gancel, Ollitrault, et al., 2005	Idzojtic, Kajba, et al., 2005	bin Jantan, Yalvema, et al., 2005	Javidnia, Miri, et al., 2005	Javidnia, Miri, et al., 2005, 2
Comment	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI

Column type	Capillary	Capillary	Capillary	Capillary	Capillary
Active phase	HP-5	HP-5	RTX-1	HP-5MS	DB-5
Column length (m)	30.	30.	60.	30.	30.
Carrier gas	He		He	He	He
Substrate
Column diameter (mm)	0.25		0.22	0.25	0.25
Phase thickness (μm)	0.25		0.25	0.25	0.25
T_start (C)	60.	50.	60.	60.	40.
T_end (C)	260.	290.	230.	250.	260.
Heat rate (K/min)	3.	4.	2.	4.	2.
Initial hold (min)				2.	5.
Final hold (min)			35.	20.	20.
I	1373.	1376.	1377.	1376.	1375.
Reference	Javidnia, Miri, et al., 2005, 3	Magalhães, Ruiz, et al., 2005	Paolini, Costa, et al., 2005	Pino, Mesa, et al., 2005	Senatore, Napolitano, et al., 2005
Comment	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI

Column type	Capillary	Capillary	Capillary	Capillary	Capillary
Active phase	DB-5MS	DB-1	BP-1	HP-5MS	SPB-1
Column length (m)	60.	30.	50.	30.	30.
Carrier gas	He	N2	He	He	He
Substrate
Column diameter (mm)	0.25	0.25	0.22	0.25	0.25
Phase thickness (μm)	0.25	0.25	0.25	0.25	0.25
T_start (C)	40.	50.	60.	60.	70.
T_end (C)	200.	200.	230.	280.	220.
Heat rate (K/min)	2.	5.	2.	3.	3.
Initial hold (min)
Final hold (min)	20.		35.		15.
I	1368.	1378.	1377.	1371.	1369.
Reference	Seo and Baek, 2005	Tchoumbougnang, Zollo, et al., 2005	Vellutini, Baldovini, et al., 2005	Aligiannis, Kalpoutzakis, et al., 2004	Antunes, Sevinate-Pinto, et al., 2004
Comment	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI

Column type	Capillary	Capillary	Capillary	Capillary	Capillary
Active phase	DB-5	HP-5	SPB-1	HP-5	HP-5MS
Column length (m)	60.	30.	30.	30.	30.
Carrier gas	Helium	N2	He		He
Substrate
Column diameter (mm)	0.25	0.25	0.2	0.25	0.25
Phase thickness (μm)	0.25	0.25	0.2	0.25	0.25
T_start (C)	40.	60.	70.	60.	60.
T_end (C)	250.	220.	220.	220.	280.
Heat rate (K/min)	7.	5.	3.	5.	3.
Initial hold (min)		10.		10.
Final hold (min)			15.
I	1385.	1377.	1368.	1377.	1370.
Reference	Bell, 2004	Bertoli, Menichini, et al., 2004	Cavaleiro, Salgueiro, et al., 2004	Ceccarini, Macchia, et al., 2004	Chorianopoulos, Kalpoutzakis, et al., 2004
Comment	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI

Column type	Capillary	Capillary	Capillary	Capillary	Capillary
Active phase	HP-1	DB-5	DB-5	HP-5	HP-5
Column length (m)	25.	30.	30.	30.	30.
Carrier gas	He	N2	N2	He	N2
Substrate
Column diameter (mm)	0.32	0.25	0.25	0.25	0.25
Phase thickness (μm)	0.17	0.25	0.25	0.25	0.25
T_start (C)	50.	60.	60.	50.	60.
T_end (C)	200.	240.	240.	290.	220.
Heat rate (K/min)	3.	3.	3.	4.	5.
Initial hold (min)					10.
Final hold (min)
I	1334.	1377.	1377.	1375.	1377.
Reference	Fernández-Ocaña, Gómez-Rodríguez, et al., 2004	Flamini, Cioni, et al., 2004	Flamini, Cioni, et al., 2004	Flach A., Dondon R.C., et al., 2004	Flamini, Luigi Cioni, et al., 2004
Comment	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI

Column type	Capillary	Capillary	Capillary	Capillary	Capillary
Active phase	HP-5MS	HP-5	HP-5	HP-5	HP-5MS
Column length (m)	30.	30.	30.	30.	30.
Carrier gas	He	He	He	He	He
Substrate
Column diameter (mm)	0.25	0.25	0.25	0.25	0.25
Phase thickness (μm)	0.25	0.25	0.25		0.25
T_start (C)	60.	40.	60.	60.	60.
T_end (C)	280.	250.	260.	260.	280.
Heat rate (K/min)	4.	3.	3.	3.	4.
Initial hold (min)	5.				5.
Final hold (min)
I	1375.	1375.	1374.	1374.	1377.
Reference	Grujic-Jovanovic, Skaltsa, et al., 2004	Isidorov, Krajewska, et al., 2004	Javidnia, Miri, et al., 2004	Javidnia, Miri, et al., 2004, 2	Karioti, Hadjipavlou-Litina, et al., 2004
Comment	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI

Column type	Capillary	Capillary	Capillary	Capillary	Capillary
Active phase	RSL-200	SPB-5	DB-5	HP-5MS	HP-5
Column length (m)	30.	30.	30.	30.	30.
Carrier gas	H2	He	He	He	He
Substrate
Column diameter (mm)	0.32	0.25	0.25	0.25	0.25
Phase thickness (μm)	0.25	0.25	0.25	0.25	0.25
T_start (C)	40.	60.	50.	50.	50.
T_end (C)	280.	250.	290.	250.	310.
Heat rate (K/min)	6.	4.	4.	3.	4.
Initial hold (min)	5.	2.
Final hold (min)	5.	20.
I	1390.	1376.	1368.	1377.	1374.
Reference	Ngassoum, Ousmaila, et al., 2004	Pino, Marbot, et al., 2004	Reis, Pansarim, et al., 2004	Salido, Valenzuela, et al., 2004	Singer, Flach, et al., 2004
Comment	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI

Column type	Capillary	Capillary	Capillary	Capillary	Capillary
Active phase	HP-5	HP-5	BP-1	HP-5MS	Optima 5
Column length (m)	50.	50.	50.	30.	25.
Carrier gas	He	He	He	He	He
Substrate
Column diameter (mm)	0.2	0.2	0.22	0.25	0.25
Phase thickness (μm)	0.2	0.2	0.25	0.25	0.25
T_start (C)	40.	35.	60.	60.	60.
T_end (C)	250.	250.	220.	280.	280.
Heat rate (K/min)	3.	3.	2.	3.	3.
Initial hold (min)	15.	15.
Final hold (min)	40.	40.	20.		20.
I	1376.	1388.	1377.	1355.	1367.
Reference	Stashenko, Jaramillo, et al., 2004	Stashenko, Jaramillo, et al., 2004, 2	Tam, Thuam, et al., 2004	Tzakou, Vagias, et al., 2004	Vérité, Nacer, et al., 2004
Comment	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI

Column type	Capillary	Capillary	Capillary	Capillary	Capillary
Active phase	DB-5MS	DB-5MS	DB-5MS	DB-5	DB-5
Column length (m)	30.	30.	30.	25.	30.
Carrier gas	He	He	He	N2	He
Substrate
Column diameter (mm)	0.25	0.25	0.25	0.25	0.25
Phase thickness (μm)	0.25	0.25	0.25	0.25	0.25
T_start (C)	40.	40.	40.	75.	60.
T_end (C)	200.	200.	200.	210.	240.
Heat rate (K/min)	4.	4.	4.	3.	3.
Initial hold (min)	5.	5.	5.	10.
Final hold (min)	20.	20.	20.	1.	30.
I	1380.	1379.	1376.	1373.	1377.
Reference	Yu, Kim, et al., 2004	Yu, Kim, et al., 2004, 2	Zheng, Kim, et al., 2004	bin Ahmad and bin Jantan, 2003	Bader, Caponi, et al., 2003
Comment	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI

Column type	Capillary	Capillary	Capillary	Capillary	Capillary
Active phase	BP-1	BP-1	OV-1	HP-5	DB-1
Column length (m)	50.	50.	25.	30.	30.
Carrier gas	He	He	H2	He	N2
Substrate
Column diameter (mm)	0.22	0.22	0.25	0.25	0.25
Phase thickness (μm)	0.25	0.25	0.3	0.25	0.25
T_start (C)	60.	60.	50.	60.	50.
T_end (C)	230.	230.	200.	280.	200.
Heat rate (K/min)	2.	2.	3.	3.	5.
Initial hold (min)			1.
Final hold (min)	35.	35.	20.		0.
I	1379.	1379.	1360.	1376.	1380.
Reference	Bianchini, Tomi, et al., 2003	Bianchini, Tomi, et al., 2003	Bicchi, Rubiolo, et al., 2003	Bougatsos, Meyer, et al., 2003	Boyom, Assembe, et al., 2003
Comment	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI

Column type	Capillary	Capillary	Capillary	Capillary	Capillary
Active phase	DB-1	HP-5	HP-5	HP-1	HP-1
Column length (m)	30.	30.	30.	50.	50.
Carrier gas	He	N2	N2	He	He
Substrate
Column diameter (mm)	0.25	0.25	0.25	0.2	0.2
Phase thickness (μm)	0.25	0.25	0.25	0.33	0.33
T_start (C)	40.	60.	60.	60.	60.
T_end (C)	250.	220.	220.	250.	250.
Heat rate (K/min)	3.	5.	5.	2.	2.
Initial hold (min)		10.	10.	5.	5.
Final hold (min)	20.			20.	20.
I	1390.	1377.	1377.	1376.	1369.
Reference	Brat, Rega, et al., 2003	Campeol, Flamini, et al., 2003	Campeol, Flamini, et al., 2003	Cavalli, Fernandez, et al., 2003	Cavalli, Fernandez, et al., 2003
Comment	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI

Column type	Capillary	Capillary	Capillary	Capillary	Capillary
Active phase	SPB-1	RTX-1	Ultra-2	Optima 5	HP-5
Column length (m)	30.	60.	25.	25.	30.
Carrier gas	He	He	H2	He	N2
Substrate
Column diameter (mm)	0.2	0.22	0.25	0.25	0.25
Phase thickness (μm)	0.2	0.25	0.33	0.25	0.25
T_start (C)	70.	60.	40.	60.	60.
T_end (C)	220.	230.	280.	280.	220.
Heat rate (K/min)	3.	2.	3.	3.	5.
Initial hold (min)			2.		10.
Final hold (min)	15.	45.	10.	20.
I	1369.	1377.	1366.	1365.	1378.
Reference	Cavaleiro, Salgueiro, et al., 2003	Cavalli, Tomi, et al., 2003	Ceva-Antunes, Bizzo, et al., 2003	Chosson, Vérité, et al., 2003	Dural, Bagci, et al., 2003
Comment	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI

Column type	Capillary	Capillary	Capillary	Capillary	Capillary
Active phase	HP-5	DB-1	HP-5	HP-5	HP-5
Column length (m)	30.	30.	30.	30.	30.
Carrier gas	N2	He	N2	N2	He
Substrate
Column diameter (mm)	0.25	0.25	0.25	0.25	0.25
Phase thickness (μm)	0.25	0.25	0.25	0.25	0.25
T_start (C)	60.	40.	60.	60.	60.
T_end (C)	220.	250.	220.	220.	280.
Heat rate (K/min)	5.	2.	5.	5.	3.
Initial hold (min)	10.	5.	10.	10.
Final hold (min)		20.
I	1377.	1360.	1377.	1378.	1376.
Reference	Ertugrul, Dural, et al., 2003	de Feo, Bruno, et al., 2003	Flamini, Luigi Cioni, et al., 2003	Flamini, Luigi Cioni, et al., 2003, 2	Fokialakis, Melliou, et al., 2003
Comment	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI

Column type	Capillary	Capillary	Capillary	Capillary	Capillary
Active phase	DB-1	DB-5	HP-5	DB-5	HP-5
Column length (m)	30.	30.	30.	30.	30.
Carrier gas	He			He	He
Substrate
Column diameter (mm)	0.25	0.32	0.25	0.25	0.25
Phase thickness (μm)	0.25	0.5		0.25	0.25
T_start (C)	40.	40.	25.	75.	60.
T_end (C)	250.	265.	150.	230.	280.
Heat rate (K/min)	3.	7.	3.	3.	4.
Initial hold (min)			5.	10.	5.
Final hold (min)	20.	5.		20.
I	1355.	1391.	1377.	1370.	1376.
Reference	Gancel, Ollitrault, et al., 2003	Högnadóttir and Rouseff, 2003	Isidorov, Vinogorova, et al., 2003	Jantan, Ling, et al., 2003	Karioti, Skaltsa, et al., 2003
Comment	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI

Column type	Capillary	Capillary	Capillary	Capillary	Capillary
Active phase	HP-5	HP-5MS	HP-5	HP-5MS	DB-1
Column length (m)	30.	30.	30.	30.	30.
Carrier gas	He	He	He	He	He
Substrate
Column diameter (mm)	0.25	0.25	0.25	0.25	0.25
Phase thickness (μm)	0.25	0.25	0.25	0.25	0.25
T_start (C)	60.	60.	60.	50.	40.
T_end (C)	240.	280.	280.	250.	270.
Heat rate (K/min)	3.	3.	3.	3.	2.
Initial hold (min)					5.
Final hold (min)					20.
I	1377.	1375.	1376.	1376.	1361.
Reference	Macchioni, Cioni, et al., 2003	Mimica-Dukic, Kujundzic, et al., 2003	Ngassapa, Runyoro, et al., 2003	Salido, Altarejos, et al., 2003	Senatore, Lentini, et al., 2003
Comment	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI

Column type	Capillary	Capillary	Capillary	Capillary	Capillary
Active phase	MS5	BPX-5	RTX-5	HP-5	HP-5
Column length (m)	25.	30.	30.	30.	30.
Carrier gas		He	He	He	He
Substrate
Column diameter (mm)	0.25	0.25	0.25	0.25	0.25
Phase thickness (μm)	0.25	0.25	0.25	0.25	0.25
T_start (C)	40.	60.	45.	40.	60.
T_end (C)	180.	240.	250.	240.	280.
Heat rate (K/min)	3.	3.	3.	3.	4.
Initial hold (min)		2.	6.		5.
Final hold (min)
I	1371.	1374.	1378.	1376.	1375.
Reference	Shao, Marriott, et al., 2003	Shellie, Marriott, et al., 2003	Shellie, Marriott, et al., 2003, 2	Shellie and Marriott, 2003	Skaltsa, Demetzos, et al., 2003
Comment	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI

Column type	Capillary	Capillary	Capillary	Capillary	Capillary
Active phase	HP-5	HP-5	HP-5	SPB-1	DB-5
Column length (m)	30.	30.	30.	30.	30.
Carrier gas	He	He	He	He	He
Substrate
Column diameter (mm)	0.25	0.25	0.25	0.20	0.25
Phase thickness (μm)	0.25	0.25	0.25	0.20	0.25
T_start (C)	60.	60.	60.	70.	70.
T_end (C)	280.	280.	280.	220.	230.
Heat rate (K/min)	3.	3.	3.	3.	4.
Initial hold (min)					2.
Final hold (min)				15.	20.
I	1377.	1377.	1375.	1368.	1376.
Reference	Tsiri, Kretsi, et al., 2003	Tsiri, Kretsi, et al., 2003	Tzakou, Couladis, et al., 2003	Cavaleiro, Salgueiro, et al., 2002	Choi, Kim. M.-S.L., et al., 2002
Comment	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI

Column type	Capillary	Capillary	Capillary	Capillary	Capillary
Active phase	HP-5MS	HP-5MS	CP Sil 8 CB	DB-5	HP-5
Column length (m)	30.	30.	60.	30.	30.
Carrier gas	He		He		N2
Substrate
Column diameter (mm)	0.25	0.25	0.25	0.25	0.25
Phase thickness (μm)	0.25	0.25	0.25	0.25	0.25
T_start (C)	60.	50.	40.	50.	60.
T_end (C)	300.	280.	250.	280.	220.
Heat rate (K/min)	3.	3.	4.	3.	5.
Initial hold (min)		5.	8.	5.	10.
Final hold (min)			10.
I	1377.	1376.	1392.	1376.	1377.
Reference	Couladis, Chinou, et al., 2002	Demetzos, Angelopoulou, et al., 2002	Duckham, Dodson, et al., 2002	Economakis, Skaltsa, et al., 2002	Flamini, Cioni, et al., 2002
Comment	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI

Column type	Capillary	Capillary	Capillary	Capillary	Capillary
Active phase	HP-5	CP Sil 5 CB	RTX-5 MS	DB-5	DB-5
Column length (m)	30.	50.	30.	25.	30.
Carrier gas		H2	He	He	He
Substrate
Column diameter (mm)	0.25	0.25	0.25	0.25	0.25
Phase thickness (μm)	0.25	0.15	0.25		0.25
T_start (C)	60.	40.	45.	70.	60.
T_end (C)	280.	300.	180.	275.	260.
Heat rate (K/min)	3.	4.	2.5	4.	4.
Initial hold (min)	5.	3.	10.
Final hold (min)
I	1377.	1375.	1377.	1376.	1376.
Reference	Fokialakis, Magiatis, et al., 2002	Heinrich, Pfeifhofer, et al., 2002	Hudaib, Speroni, et al., 2002	Javidnia, Miri, et al., 2002	Javidnia, Miri, et al., 2002, 2
Comment	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI

Column type	Capillary	Capillary	Capillary	Capillary	Capillary
Active phase	HP-5	RTX-5	CP Sil 8 CB	CP Sil 5 CB	SPB-5
Column length (m)	30.	30.	60.	25.	30.
Carrier gas	He	He	He	N2	He
Substrate
Column diameter (mm)	0.25	0.25	0.25	0.25	0.25
Phase thickness (μm)	0.25	0.25	0.25	0.25	0.25
T_start (C)	60.	45.	40.	60.	60.
T_end (C)	280.	300.	250.	280.	250.
Heat rate (K/min)	3.	3.	4.	4.	4.
Initial hold (min)		6.	8.	6.	2.
Final hold (min)		10.	10.		20.
I	1370.	1379.	1383.	1370.	1376.
Reference	Kovacevic, Pavlovic, et al., 2002	Mondello, Zappia, et al., 2002	Oruna-Concha, Ames, et al., 2002	Pino, Marbot, et al., 2002	Pino, Marbot, et al., 2002, 2
Comment	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI

Column type	Capillary	Capillary	Capillary	Capillary	Capillary
Active phase	CP Sil 5 CB	CP Sil 5 CB	HP-5	RTX-5	RTX-5
Column length (m)	30.	50.	30.	30.	30.
Carrier gas	H2	He	He	He	He
Substrate
Column diameter (mm)	0.25	0.32	0.25	0.25	0.25
Phase thickness (μm)	0.25	0.4	0.25	0.25	0.25
T_start (C)	60.	60.	60.	45.	45.
T_end (C)	280.	280.	280.	250.	250.
Heat rate (K/min)	2.	3.	3.	3.	3.
Initial hold (min)	10.	10.		6.	6.
Final hold (min)	40.	60.
I	1370.	1374.	1347.	1372.	1380.
Reference	Pino, Marbot, et al., 2002, 3	Pino, Marbot, et al., 2002, 4	Pitarokili, Couladis, et al., 2002	Shellie, Mondello, et al., 2002	Shellie, Mondello, et al., 2002
Comment	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI

Column type	Capillary	Capillary	Capillary	Capillary	Capillary
Active phase	HP-5	DB-5	HP-5	HP-5	HP-5
Column length (m)	30.	30.	30.	30.	30.
Carrier gas	He	He	He	He	He
Substrate
Column diameter (mm)	0.25	0.25	0.25	0.25	0.25
Phase thickness (μm)	0.25	0.25	0.25	0.25	0.50
T_start (C)	60.	60.	60.	60.	60.
T_end (C)	280.	300.	260.	380.	280.
Heat rate (K/min)	3.	5.	3.	3.	3.
Initial hold (min)	5.	3.
Final hold (min)			10.
I	1373.	1380.	1375.	1368.	1375.
Reference	Aligiannis, Kalpoutzakis, et al., 2001	Bortolomeazzi, Berno, et al., 2001	Couladis, Baziou, et al., 2001	Couladis, Tsortanidou, et al., 2001	Couladis, Tzakou, et al., 2001
Comment	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI

Column type	Capillary	Capillary	Capillary	Capillary	Capillary
Active phase	HP-1	HP-5	RTX-5 MS	RTX-5 MS	SPB-Sulfur
Column length (m)	60.	50.	30.	30.	30.
Carrier gas	He	He	He	He
Substrate
Column diameter (mm)	0.25	0.25	0.25	0.25	0.32
Phase thickness (μm)	0.25	0.25	0.25	0.25	4.
T_start (C)	50.	50.	70.	70.	40.
T_end (C)	250.	250.	210.	210.	200.
Heat rate (K/min)	2.5	2.5	4.	4.	4.
Initial hold (min)	5.	5.	10.	10.	12.5
Final hold (min)			10.	10.
I	1378.	1377.	1377.	1377.	1393.
Reference	Guilliard, Delgado, et al., 2001	Guilliard, Delgado, et al., 2001	Hudaib, Grazia Bellardi, et al., 2001	Hudaib, Grazia Bellardi, et al., 2001	de Lacy Costello, Evans, et al., 2001
Comment	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI

Column type	Capillary	Capillary	Capillary	Capillary	Capillary
Active phase	DB-5	CP Sil 5 CB	BP-1	HP-5MS	HP-5MS
Column length (m)	30.	50.	50.	30.	30.
Carrier gas	H2	He		He	He
Substrate
Column diameter (mm)	0.25	0.32	0.22	0.25	0.25
Phase thickness (μm)	0.25	0.4	0.25	0.25	0.25
T_start (C)	60.	60.	60.	50.	60.
T_end (C)	240.	280.	220.	250.	280.
Heat rate (K/min)	3.	3.	2.	3.	4.
Initial hold (min)		10.			5.
Final hold (min)		60.	20.
I	1377.	1374.	1379.	1377.	1375.
Reference	Nogueira, Bittrich, et al., 2001	Pino, Marbot, et al., 2001	Rezzi, Cavaleiro, et al., 2001	Salido, Altarejos, et al., 2001	Skaltsa, Mavrommati, et al., 2001
Comment	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI

Column type	Capillary	Capillary	Capillary	Capillary	Capillary
Active phase	DB-5	DB-5	HP-5	HP-5	DB-5
Column length (m)	60.	30.	30.	30.	30.
Carrier gas	He	He	He	He	He
Substrate
Column diameter (mm)	0.25	0.25	0.25	0.25	0.25
Phase thickness (μm)	0.25	0.25	0.25	0.25	0.25
T_start (C)	40.	60.	40.	50.	60.
T_end (C)	290.	300.	200.	280.	240.
Heat rate (K/min)	4.	5.	2.	4.	3.
Initial hold (min)	2.	3.	5.	5.	2.
Final hold (min)	5.		20.
I	1363.	1380.	1370.	1371.	1374.
Reference	Bartley and Jacobs, 2000	Bortolomeazzi, Pizzale, et al., 2000	Kim, Thuy, et al., 2000	Lazari, Skaltsa, et al., 2000	Maia, de Paula, et al., 2000
Comment	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI

Column type	Capillary	Capillary	Capillary	Capillary	Capillary
Active phase	DB-5	OV-101	CP Sil 5 CB	HP-5	HP-5
Column length (m)	30.	25.	50.	30.	30.
Carrier gas	He	N2	H2	He	He
Substrate
Column diameter (mm)	0.25	0.25	0.22	0.25	0.25
Phase thickness (μm)	0.25		0.13	0.25	0.25
T_start (C)	60.	50.	40.	50.	70.
T_end (C)	240.	200.	300.	280.	230.
Heat rate (K/min)	3.	5.	4.	4.	2.
Initial hold (min)	2.			5.
Final hold (min)			10.
I	1374.	1378.	1383.	1376.	1374.
Reference	Maia, de Paula, et al., 2000	Menut, Bessiere, et al., 2000	Pfeifhofer, 2000	Skaltsa, Lazari, et al., 2000	Song, Sawamura, et al., 2000
Comment	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI

Column type	Capillary	Capillary	Capillary	Capillary	Capillary
Active phase	Mega 5MS	CBP-1	CP Sil 8 CB	HP-5	DB-1
Column length (m)	30.	30.	50.	30.	60.
Carrier gas	He	He		He	He
Substrate
Column diameter (mm)	0.25	0.25	0.32	0.25	0.25
Phase thickness (μm)	0.25			0.25	0.25
T_start (C)	40.	60.	60.	50.	50.
T_end (C)	240.	240.	220.	280.	220.
Heat rate (K/min)	3.	4.	4.	4.	4.
Initial hold (min)	2.		5.	5.
Final hold (min)			30.
I	1364.	1376.	1382.	1371.	1387.
Reference	Verzera, Trozzi, et al., 2000	Zunino, Lopez, et al., 2000	Chevance and Farmer, 1999	Lazari, Skaltsa, et al., 1999	Mirza and Sefidkon, 1999
Comment	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI

Column type	Capillary	Capillary	Capillary	Capillary	Capillary
Active phase	DB-1	HP-1	Methyl Silicone	CP Sil 5 CB	OV-1
Column length (m)	30.	60.	50.	25.	25.
Carrier gas		He	N2	He
Substrate
Column diameter (mm)	0.25	0.25	0.25	0.25	0.25
Phase thickness (μm)	0.25	0.25	0.17		0.3
T_start (C)	50.	50.	80.	60.	50.
T_end (C)	220.	250.	200.	260.	200.
Heat rate (K/min)	3.	2.5	2.	5.	3.
Initial hold (min)	3.	5.			1.
Final hold (min)					20.
I	1363.	1368.	1392.	1376.	1362.
Reference	Muselli, Hoi, et al., 1999	Stashenko, Cervantes, et al., 1999	Sumathykutty, Rao, et al., 1999	Weyerstahl, Marschall, et al., 1999	Bicchi, Rubiolo, et al., 1998
Comment	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI

Column type	Capillary	Capillary	Capillary	Capillary	Capillary
Active phase	DB-5	HP-5	BP-1	BP-1	BP-1
Column length (m)	30.		25.	25.	50.
Carrier gas	H2	He	He	He	He
Substrate
Column diameter (mm)	0.25	0.26	0.32	0.32	0.22
Phase thickness (μm)	0.25	0.25			0.25
T_start (C)	60.	60.	5.	5.	60.
T_end (C)	240.	240.	250.	250.	220.
Heat rate (K/min)	3.	3.	5.	5.	2.
Initial hold (min)			5.	5.
Final hold (min)			30.	30.	20.
I	1377.	1375.	1384.	1383.	1383.
Reference	Nogueira, Marsaioli, et al., 1998	Oprean, Tamas, et al., 1998	Sinyinda and Gramshaw, 1998	Sinyinda and Gramshaw, 1998	Tam, An, et al., 1998
Comment	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI

Column type	Capillary	Capillary	Capillary	Capillary	Capillary
Active phase	OV-1	BP-1	BP-1	DB-5	DB-5
Column length (m)	25.	50.	50.	30.	60.
Carrier gas	H2	He	He	He	He
Substrate
Column diameter (mm)	0.25	0.22	0.22	0.26	0.24
Phase thickness (μm)	0.3	0.25	0.25	0.25
T_start (C)	50.	60.	60.	50.	50.
T_end (C)	200.	230.	230.	225.	280.
Heat rate (K/min)	3.	2.	2.	2.	5.
Initial hold (min)	1.				3.
Final hold (min)	20.	35.	35.	20.
I	1360.	1379.	1373.	1371.	1374.
Reference	Bicchi, Fresia, et al., 1997	Mariotti, Costa, et al., 1997	Mariotti, Tomi, et al., 1997	Sagrero-Nieves, Bartley, et al., 1997	Tzakou, Roussis, et al., 1997
Comment	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI

Column type	Capillary	Capillary	Capillary	Capillary	Capillary
Active phase	DB-1	Methyl Silicone	DB-1	HP-101	OV-101
Column length (m)	60.	25.	30.	50.	50.
Carrier gas	He	He	He	N2	N2
Substrate
Column diameter (mm)	0.25	0.2	0.20	0.25	0.25
Phase thickness (μm)	0.25	0.3	0.20
T_start (C)	50.	40.	70.	70.	80.
T_end (C)	250.	200.	200.	200.	200.
Heat rate (K/min)	3.5	2.	4.	3.	2.
Initial hold (min)	5.		5.
Final hold (min)
I	1379.	1397.	1385.	1389.	1380.
Reference	Stashenko, Prada, et al., 1996	Píry, Príbela, et al., 1995	Stashenko, Wiame, et al., 1995	Chung, Eiserich, et al., 1993	Yang, Sugisawa, et al., 1992
Comment	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI

Column type	Capillary	Capillary	Capillary	Capillary	Capillary
Active phase	OV-101	DB-1	DB-5	OV-101	OV-1
Column length (m)	50.	60.	60.	50.	30.
Carrier gas	N2	He	He	H2	He
Substrate
Column diameter (mm)	0.25	0.25	0.32	0.32	0.5
Phase thickness (μm)		0.25	1.		0.8
T_start (C)	80.	40.	40.	50.	40.
T_end (C)	200.	280.	220.	200.	220.
Heat rate (K/min)	2.	2.	3.	2.	2.
Initial hold (min)		3.
Final hold (min)		10.
I	1380.	1353.	1392.	1359.	1363.
Reference	Yang, Sugisawa, et al., 1992	Adedeji, Hartman, et al., 1991	Le Quere and Latrasse, 1990	Pieribattesti, Smadja, et al., 1988	De Pooter, Omar, et al., 1985
Comment	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI	MSDC-RI

Column type	Capillary
Active phase	OV-1
Column length (m)	30.
Carrier gas	He
Substrate
Column diameter (mm)	0.5
Phase thickness (μm)	0.8
T_start (C)	40.
T_end (C)	220.
Heat rate (K/min)	2.
Initial hold (min)
Final hold (min)
I	1373.
Reference	De Pooter, Omar, et al., 1985
Comment	MSDC-RI

References

Go To: Top, Van Den Dool and Kratz RI, non-polar column, temperature ramp, Notes

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Su, Ho, et al., 2006
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Su, Ho, et al., 2006, 2
Su, Y.-C.; Ho, C.-L.; Wang, E.I.-C.; Chang, S.-T., Antifungal activities and chemical compositions of essential oils from leaves of four eucalypts, Taiwan J. For. Sci., 2006, 21, 1, 49-61. [all data]

Vujisic L., Vuckovic I., et al., 2006
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Vundac, Pfeifhofer, et al., 2006
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Zhao C.X., Li, et al., 2006
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Ziegenbein, Hanssen, et al., 2006
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Agnaniet, Makani, et al., 2005
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Shellie and Marriott, 2003
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Bartley and Jacobs, 2000
Bartley, J.P.; Jacobs, A.L., Effects of drying on flavour compounds in Australian-grown ginger (Zingiber officinale), J. Sci. Food Agric., 2000, 80, 2, 209-215, https://doi.org/10.1002/(SICI)1097-0010(20000115)80:2<209::AID-JSFA516>3.0.CO;2-8 . [all data]

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Maia, de Paula, et al., 2000
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Pfeifhofer, 2000
Pfeifhofer, H.W., Composition of the essential oil of Pinus canariensis Sweet ex Sprengel, Flavour Fragr. J., 2000, 15, 4, 266-270, https://doi.org/10.1002/1099-1026(200007/08)15:4<266::AID-FFJ908>3.0.CO;2-E . [all data]

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Chevance and Farmer, 1999
Chevance, F.F.V.; Farmer, L.J., Identification of major volatile odor compounds in frankfurters, J. Agric. Food Chem., 1999, 47, 12, 5151-5160, https://doi.org/10.1021/jf990515d . [all data]

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Mirza and Sefidkon, 1999
Mirza, M.; Sefidkon, F., Essential oil composition of two Salvia species from Iran, Salvia nemorosa L. and Salvia reuterana Boiss., Flavour Fragr. J., 1999, 14, 4, 230-232, https://doi.org/10.1002/(SICI)1099-1026(199907/08)14:4<230::AID-FFJ816>3.0.CO;2-L . [all data]

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Notes

Go To: Top, Van Den Dool and Kratz RI, non-polar column, temperature ramp, References

Symbols used in this document:

T_end Final temperature

T_start Initial temperature
Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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