α-Copaene


Normal alkane RI, non-polar column, temperature ramp

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase HP-5 MSRTX-1RTX-1HP-5 MSHP-5
Column length (m) 60.60.60.30.25.
Carrier gas HeliumHeliumHeliumHeliumHydrogen
Substrate      
Column diameter (mm) 0.250.220.220.250.32
Phase thickness (μm) 0.250.250.250.250.52
Tstart (C) 40.60.60.35.40.
Tend (C) 250.230.230.300.280.
Heat rate (K/min) 3.2.2.3.4.
Initial hold (min) 1.  5. 
Final hold (min) 20.5.5.15.10.
I 1348.1379.1379.1370.1370.
ReferenceSardashti, Valizadeh, et al., 2013Bendiabdellah, El Amine Dib, et al., 2012Bendiabdellah, El Amine Dib, et al., 2012Kotowska, Zalikowski, et al., 2012Velickovic, Ristic, et al., 2012
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase HP-5HP-5HP-5 MSCP-Sil 5 CBDB-5 MS
Column length (m) 25.25.30.25.30.
Carrier gas HydrogenHydrogenHeliumHeliumHelium
Substrate      
Column diameter (mm) 0.320.320.250.250.25
Phase thickness (μm) 0.520.520.250.150.25
Tstart (C) 40.40.50.50.60.
Tend (C) 280.280.250.220.270.
Heat rate (K/min) 4.4.7. 3.
Initial hold (min)   1.  
Final hold (min) 10.10.5.  
I 1370.1370.1378.1375.1370.
ReferenceVelickovic, Ristic, et al., 2012Velickovic, Ristic, et al., 2012Zouari, Ayadi, et al., 2012Ameen, Usman, et al., 2011Cui, Yang, et al., 2011
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase HP-5 MSHP-5 MSDB-5VF-5 MSVF-5 MS
Column length (m) 30.30.30.60.60.
Carrier gas HeliumHeliumHeliumHeliumHelium
Substrate      
Column diameter (mm) 0.250.250.250.320.32
Phase thickness (μm) 0.250.250.250.250.25
Tstart (C) 60.50.60.30.30.
Tend (C) 220.180.240.260.260.
Heat rate (K/min) 4.2.3.2.2.
Initial hold (min) 20.    
Final hold (min) 20.  28.28.
I 1387.1366.1376.1377.1378.
ReferenceFeizbakhsh and Naeemy, 2011Hammami, Kamoun, et al., 2011Karimi, Farmani, et al., 2011Leffingwell and Alford, 2011Leffingwell and Alford, 2011
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase CP-Sil 5 CBMethylsiloxane + 5 % Ph-groupsDB-5ZB-5DB-5
Column length (m) 30.30.30.30.30.
Carrier gas NitrogenHeliumHeliumNitrogenNitrogen
Substrate      
Column diameter (mm) 0.250.250.320.250.25
Phase thickness (μm) 0.260.250.250.25 
Tstart (C) 45.60.50.40.60.
Tend (C) 280.230.300.200.250.
Heat rate (K/min) 3.7.4.5.4.
Initial hold (min)  2.4.5.1.
Final hold (min) 22.20.5.5.10.
I 1379.1379.1380.1395.1385.
ReferenceMothana, Hasson, et al., 2011Nadim, Malik, et al., 2011Osorio, Carriazo, et al., 2011Vazquez, Demmel, et al., 2011Yousefzadi, Heidari, et al., 2011
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase HP-5 MSHP-5HP-5RTX-1DB-5
Column length (m) 30.30.30.60.30.
Carrier gas HeliumHydrogenHeliumHeliumHelium
Substrate      
Column diameter (mm) 0.250.250.2520.220.25
Phase thickness (μm) 0.250.250.250.250.25
Tstart (C) 30.50.60.60.50.
Tend (C) 250.250.240.230.250.
Heat rate (K/min) 5.5.3.2.2.
Initial hold (min) 3.5.   
Final hold (min) 10.5. 30. 
I 1419.1377.1373.1379.1377.
ReferenceZarai, Kadri, et al., 2011Abderrahim, Belhamel, et al., 2010Cavar, Maksimovic, et al., 2010Dib, Djabou, et al., 2010Ho, Wang, et al., 2010
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase HP-5DB-5DB-5 MSDB-1BP-1
Column length (m) 30.30.60.25. 
Carrier gas HeliumHeliumHeliumNitrogenNitrogen
Substrate      
Column diameter (mm) 0.320.250.250.25 
Phase thickness (μm) 0.250.250.250.25 
Tstart (C) 60.60.40.60.60.
Tend (C) 240.240.250.250.220.
Heat rate (K/min) 3.3.5.4.5.
Initial hold (min) 2. 15.1.10.
Final hold (min)   15.10.30.
I 1376.1375.1381.1385.1379.
ReferenceKahriman, Tosun, et al., 2010Magalhaes, Lima, et al., 2010Mesa-Arango, Betancur-Galvis, et al., 2010Mirjalili, Salehi, et al., 2010Mishra, Chaudhary, et al., 2010
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase HP-5HP-5HP-5HP-5 MSHP-5
Column length (m) 30.30.30.30.30.
Carrier gas HeliumHeliumHeliumHeliumHydrogen
Substrate      
Column diameter (mm) 0.250.250.250.250.25
Phase thickness (μm) 0.250.250.250.250.25
Tstart (C) 40.40.50.60.70.
Tend (C) 260.260.240.220.290.
Heat rate (K/min) 4.4.3.5.5.
Initial hold (min)   5.10. 
Final hold (min) 5.5.   
I 1380.1381.1377.1377.1383.
ReferenceMiyazawa, Kawauchi, et al., 2010Miyazawa, Kawauchi, et al., 2010Monsef-Esfahani, Miri, et al., 2010Ogunwande, Flamini, et al., 2010Radulovic, Dordevic, et al., 2010
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase HP-5 MSSLB-5 MSDB-5DB-5 MSDB-1-MS
Column length (m) 30.10.30.30.60.
Carrier gas HeliumHeliumHeliumHeliumHelium
Substrate      
Column diameter (mm) 0.250.100.250.250.25
Phase thickness (μm) 0.250.100.250.250.25
Tstart (C) 70.50.60.60.30.
Tend (C) 290.250.240.240.200.
Heat rate (K/min) 5.10.3.3.2.
Initial hold (min)     4.
Final hold (min) 10.   35.
I 1379.1378.1377.1372.1368.
ReferenceRadulovic, Dordevic, et al., 2010, 2Scandinaro, Tranchida, et al., 2010Scherer, Wagner, et al., 2010Silva, Pott, et al., 2010Takeoka, Hobbs, et al., 2010
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase DB-1DB-5OV-101SE-54DB-5
Column length (m) 30.30.50.30.30.
Carrier gas HeliumHeliumHeliumHeliumHelium
Substrate      
Column diameter (mm) 0.250.250.250.250.25
Phase thickness (μm) 0.250.250.250.250.25
Tstart (C) 50.40.70.60.35.
Tend (C) 220.250.220.260.220.
Heat rate (K/min) 4.10.2.2.3.
Initial hold (min) 2.1. 5. 
Final hold (min) 2.3. 999.40.
I 1372.1377.1380.1371.1376.
ReferenceXu, Tang, et al., 2010Yang, Zhang, et al., 2010Benites, Moiteiro, et al., 2009Dayisoylu and Alma, 2009El-Massry, El-Ghorab, et al., 2009
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase SPB-5DB-5HP-5 MSDB-5HP-5 MS
Column length (m) 30.30.30.50.30.
Carrier gas NitrogenHeliumHydrogenNitrogenHelium
Substrate      
Column diameter (mm) 0.530.250.250.200.25
Phase thickness (μm) 0.500.250.250.320.25
Tstart (C) 50.50.30.60.35.
Tend (C) 210.250.230.220.195.
Heat rate (K/min) 3.5.8.5.2.
Initial hold (min) 5.2.5.3.5.
Final hold (min) 45. 10. 30.
I 1389.1377.1390.1376.1370.
ReferenceGilani, Shah, et al., 2009Ho, Wang, et al., 2009Karlsson, Birgersson, et al., 2009Kazemi and Akhavani, 2009Kim and Chung, 2009
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase DB-5RTX-1RTX-1DB-55 % Phenyl methyl siloxane
Column length (m) 30.60.60.30.60.
Carrier gas HeliumHeliumHeliumNitrogenHelium
Substrate      
Column diameter (mm) 0.250.220.220.250.25
Phase thickness (μm) 0.250.250.250.250.25
Tstart (C) 70.60.60.40.90.
Tend (C) 240.230.230.250.225.
Heat rate (K/min) 5.2.2.3.3.
Initial hold (min)    1. 
Final hold (min)  30.30.10.3.
I 1379.1374.1379.1383.1379.
ReferenceLawal and Oyedelji, 2009Museli, Pau, et al., 2009Museli, Pau, et al., 2009Rahimi-Nasrabadi, Gholivand, et al., 2009Retta, Gattuso, et al., 2009
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase DB-5 MSHP-5 MSHP-5HP-5 MSDB-5
Column length (m) 30.30.30.30.25.
Carrier gas HeliumHeliumHelium Nitrogen
Substrate      
Column diameter (mm) 0.250.250.250.250.22
Phase thickness (μm) 0.250.250.25 0.25
Tstart (C) 50.50.50.60.50.
Tend (C) 220.280.280.280.300.
Heat rate (K/min) 3.4.9.3.6.5
Initial hold (min) 2. 3. 2.
Final hold (min) 70. 3. 7.
I 1371.1377.1377.1375.1377.
ReferenceShimizu, Imayoshi, et al., 2009Zhao, Zeng, et al., 2009Aicha, Ines, et al., 2008Baziou, Couladis, et al., 2008Chieng, Assim, et al., 2008
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase SE-52HP-5DB-5SLB-5 MSZB-1
Column length (m) 50.30.30.30.30.
Carrier gas HeliumN2HeliumHeliumNitrogen
Substrate      
Column diameter (mm) 0.250.250.250.250.25
Phase thickness (μm) 0.250.250.250.250.25
Tstart (C) 60.60.100.50.45.
Tend (C) 280.220.300.250.230.
Heat rate (K/min) 3.5.20.3.3.
Initial hold (min)  10.2.2. 
Final hold (min) 20. 10.10. 
I 1381.1377.1364.1378.1374.
ReferenceDjarri, Medjroubi, et al., 2008Flamini, Tebano, et al., 2008Khokra, Prakash, et al., 2008Lo Presti, Sciarrone, et al., 2008Mierendorff, Stahl-Biskup, et al., 2008
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase DB-5 MSRTX-1SLB-5MSHP-5BPX-5
Column length (m) 30.60.10.30.7.5
Carrier gas HeliumHeHeliumNitrogenHelium
Substrate      
Column diameter (mm) 0.250.220.180.250.10
Phase thickness (μm) 0.250.250.180.2510.
Tstart (C) 50.60.40.50.60.
Tend (C) 300.230.295.280.240.
Heat rate (K/min) 5.2.10.5.3.
Initial hold (min) 5. 1.51. 
Final hold (min) 5.35. 1. 
I 1377.1377.1377.1375.1378.
ReferenceNoudogbessi, Yedomonhan, et al., 2008Paolini, Tomi, et al., 2008Risticevic, Carasek, et al., 2008Saidana, Mahjoub, et al., 2008Shellie, 2008
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase RTX-5HP-55 % Phenyl methyl siloxaneHP-5 MSSE-54
Column length (m) 20.30.30.30.30.
Carrier gas HeliumHelium HeliumHelium
Substrate      
Column diameter (mm) 0.180.250.250.250.25
Phase thickness (μm) 0.200.320.250.250.25
Tstart (C) 50.60.50.50.60.
Tend (C) 280.250.250.230.260.
Heat rate (K/min) 4.5.3.3.2.
Initial hold (min) 1.30. 10.5.
Final hold (min)    10.20.
I 1388.1374.1375.1376.1372.
ReferenceSkalicka-Wozniak, Los, et al., 2008Yassa and Akhani, 2008Zellner, Bicchi, et al., 2008Adams, Beauchamp, et al., 2007Alma, Ertas, et al., 2007
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase DB-5DB-5MSHP-5MSCP Sil 5 CBHP-5MS
Column length (m) 50.30.30.30.30.
Carrier gas NitrogenHeHeN2He
Substrate      
Column diameter (mm) 0.200.250.250.320.25
Phase thickness (μm) 0.320.250.250.250.25
Tstart (C) 60.60.60.60.60.
Tend (C) 220.240.240.300.280.
Heat rate (K/min) 5.3.3.4.3.
Initial hold (min) 3.    
Final hold (min) 5.    
I 1372.1376.1370.1374.1369.
ReferenceAmiri, 2007Andrade, Oliveira, et al., 2007Argyropoulou, Daferera, et al., 2007Baran, von Reuss, et al., 2007Basta, Pavlovic, et al., 2007
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase DB-5HP-5 MSHP-5DB-5MSHP-1
Column length (m) 30.30.30.30.30.
Carrier gas HeHeliumN2HeHelium
Substrate      
Column diameter (mm) 0.260.320.250.250.25
Phase thickness (μm) 0.250.250.250.250.25
Tstart (C) 60.60.50.60.70.
Tend (C) 240.280.240.240.200.
Heat rate (K/min) 3.4.5.3.10.
Initial hold (min)  5.1.  
Final hold (min)   4.  
I 1372.1375.1376.1377.1388.
ReferenceBos, Woerdenbag, et al., 2007Capetanos, Saroglou, et al., 2007Cheraif, Ben Jannet, et al., 2007Da Silva J.K.R., Sousa P.J.C., et al., 2007Dongmo, Tatsadjieu, et al., 2007
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase DB-5HP-5ZP-5DB-1Col-Elite 5MS
Column length (m) 30.30.60.60.30.
Carrier gas HeliumHeliumHeNitrogenHe
Substrate      
Column diameter (mm) 0.260.250.250.250.25
Phase thickness (μm) 0.250.260.250.250.25
Tstart (C) 60.60.40.60.30.
Tend (C) 290.240.260.250.246.
Heat rate (K/min) 3.4.6.4.3.
Initial hold (min)  2.7.1. 
Final hold (min)  20.1.10. 
I 1372.1376.1397.1383.1393.
ReferenceElfami, Bos, et al., 2007Farsam, Amanlou, et al., 2007Füssel, Dötterl, et al., 2007Ghasempour, Shirinpour, et al., 2007Gudaityte and Venskutonis R.P., 2007
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase HP-1SE-30HP-5DB-5MSZB-5
Column length (m) 30.30.30.30.30.
Carrier gas HeHeHeHe 
Substrate      
Column diameter (mm) 0.250.250.250.250.25
Phase thickness (μm) 0.250.250.250.250.25
Tstart (C) 60.40.40.60.60.
Tend (C) 240.250.250.280.220.
Heat rate (K/min) 2.5.5.3.4.
Initial hold (min)  5.5. 5.
Final hold (min) 20.10.10.30.20.
I 1365.1377.1375.1349.1376.
ReferenceHachicha, Skanji, et al., 2007Loizzo, Tundis, et al., 2007Loizzo, Tundis, et al., 2007Marongiu B., Piras A., et al., 2007Mohottalage, Tabacchi, et al., 2007
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase DB-5DB-5DB-5HP-5 MSSPB-1
Column length (m) 30.30.30.25.30.
Carrier gas HeliumHeliumHeHeliumHe
Substrate      
Column diameter (mm) 0.250.250.250.250.2
Phase thickness (μm) 0.250.250.320.250.2
Tstart (C) 60.60.50.100.70.
Tend (C) 300.220.250.280.220.
Heat rate (K/min) 3.4.5.4.3.
Initial hold (min)    3. 
Final hold (min)    5.15.
I 1344.1353.1361.1382.1369.
ReferenceMoreno, Lima, et al., 2007Morteza-Semnani, Saeedi, et al., 2007Nori-Shargh, Raftari, et al., 2007Phutdhawong, Kawaree, et al., 2007Pinto, Salgueiro, et al., 2007
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase DB-5SPB-5BPX-5BPX-5DB-1
Column length (m) 30.30.50.50.60.
Carrier gas HydrogenHeHeHeNitrogen
Substrate      
Column diameter (mm) 0.250.250.220.220.25
Phase thickness (μm) 0.250.25 1.0.25
Tstart (C) 50.50.50.50.60.
Tend (C) 250.250.300.300.250.
Heat rate (K/min) 4.2.4.4.4.
Initial hold (min)   1.1.1.
Final hold (min)   10.10.10.
I 1374.1375.1413.1412.1383.
ReferencePontes, de Olivera, et al., 2007Raal, Orav, et al., 2007Rali, Wossa, et al., 2007Rali, Wossa, et al., 2007, 2Reza, Ebrahim, et al., 2007
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase HP-5 MSDB-5DB-1DB-5Elite-5MS
Column length (m) 60.30.60.30.30.
Carrier gas HydrogenHeNitrogen He
Substrate      
Column diameter (mm) 0.250.250.250.250.32
Phase thickness (μm) 0.250.250.250.250.5
Tstart (C) 60.50.60.40.40.
Tend (C) 260.240.250.210.280.
Heat rate (K/min) 4.4.5.2.4.
Initial hold (min)     5.
Final hold (min) 20. 10.33.10.
I 1378.1377.1380.1375.1379.
ReferenceRojas, Velasco, et al., 2007Sefidkon, Abbasi, et al., 2007Sonboli, Kanani, et al., 2007Sylvestre, Longtin, et al., 2007Tava, Pecetti, et al., 2007
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase HP-5MSHP-5 MSHP-5MSHP-5DB-5
Column length (m) 30.30.30.30.30.
Carrier gas HeHeliumHeHeHe
Substrate      
Column diameter (mm) 0.250.250.250.250.25
Phase thickness (μm) 0.250.250.250.320.25
Tstart (C) 60.60.40.60.60.
Tend (C) 280.280.250.250.300.
Heat rate (K/min) 3.3.3.5.3.
Initial hold (min)   5.30. 
Final hold (min)   10.  
I 1335.1377.1362.1374.1366.
ReferenceTzakou, Bazos, et al., 2007Vagionas, Graikou, et al., 2007Vichi, Riu-Aumatell, et al., 2007Yassa and Akhani, 2007Apel, Sobral, et al., 2006
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase DB-5DB-5CP Sil 5 CBDB-5HP-5
Column length (m) 30.30.25.30.60.
Carrier gas  HeHeHeHe
Substrate      
Column diameter (mm) 0.250.25 0.250.25
Phase thickness (μm) 0.250.25 0.250.25
Tstart (C) 60.40.80.50.60.
Tend (C) 300.260.270.265.250.
Heat rate (K/min) 3.4.10.2.53.
Initial hold (min)  5. 1. 
Final hold (min)    20. 
I 1369.1370.1374.1378.1382.
ReferenceApel, Sobral, et al., 2006, 2Askari and Sefidkon, 2006Ayoub, Al-Azizi, et al., 2006Bazargani, Almasirad, et al., 2006Bertrand, Comte, et al., 2006
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase AT-5BP-1HP-5MSHP-1HP-1
Column length (m) 60.50.30.50.50.
Carrier gas He HeHeHe
Substrate      
Column diameter (mm) 0.250.220.250.20.2
Phase thickness (μm) 0.250.250.250.330.33
Tstart (C) 60.60.60.60.60.
Tend (C) 200.220.280.250.250.
Heat rate (K/min) 4.2.3.2.2.
Initial hold (min)    4.4.
Final hold (min) 20.20. 30.30.
I 1379.1378.1375.1375.1371.
ReferenceBorges, Rojas, et al., 2006Boti, Yao, et al., 2006Bozin, Mimicá-Dukic, et al., 2006Castel, Fernandez, et al., 2006Castel, Fernandez, et al., 2006
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase HP-1HP-1HP-1SPB-1DB-1
Column length (m) 50.50.50.30.60.
Carrier gas HeHeHeHeliumNitrogen
Substrate      
Column diameter (mm) 0.20.20.20.200.25
Phase thickness (μm) 0.330.50.330.20 
Tstart (C) 60.60.60.70.40.
Tend (C) 250.250.250.220.200.
Heat rate (K/min) 2.2.2.3.2.
Initial hold (min) 4. 4. 1.
Final hold (min) 30.120.30.15.9.
I 1377.1379.1379.1369.1371.
ReferenceCastel, Fernandez, et al., 2006Castel, Fernandez, et al., 2006, 2Castel, Fernandez, et al., 2006, 2Cavaleiro, Pinto, et al., 2006Chen, Sheu, et al., 2006
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase DB-5HP-5DB-5HP-5MSDB-5
Column length (m) 30.30.30.30.30.
Carrier gas N2He  Helium
Substrate      
Column diameter (mm) 0.250.320.320.250.26
Phase thickness (μm) 0.250.250.250.250.25
Tstart (C) 70.60.60.60.60.
Tend (C) 230.246.230.280.290.
Heat rate (K/min) 2.3.3.4.3.
Initial hold (min) 2.    
Final hold (min) 20. 15.  
I 1376.1375.1374.1373.1372.
ReferenceChoi, 2006Coronel, Cerda-Garcia-Rojas, et al., 2006Damjanovic, Skala, et al., 2006Ebrahim Sajjadi and Mehregan, 2006Elfami, Komar, et al., 2006
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase HP-5MSHP-1HP-5HP-1DB-5
Column length (m) 30.50.30.50.30.
Carrier gas HeHeHeHe 
Substrate      
Column diameter (mm) 0.250.20.250.20.25
Phase thickness (μm) 0.250.330.250.330.25
Tstart (C) 50.60.50.60.40.
Tend (C) 250.250.300.250.210.
Heat rate (K/min) 2.2.5.2.2.
Initial hold (min)   5. 2.
Final hold (min)  60.5.40.33.
I 1376.1384.1376.1372.1375.
ReferenceFarah, Afifi, et al., 2006Fernandez, Pintaric, et al., 2006Figuérédo, Cabassu, et al., 2006Filippi, Lanfranchi, et al., 2006Garneau F.X., Collin G., et al., 2006
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase DB-1DB-5DB-1DB-5DB-5
Column length (m) 60.30.60.30.30.
Carrier gas HeHeHeHeHe
Substrate      
Column diameter (mm) 0.250.250.250.250.25
Phase thickness (μm) 0.250.250.250.250.25
Tstart (C) 60.60.60.60.50.
Tend (C) 240.240.240.240.250.
Heat rate (K/min) 5.5.5.5.3.
Initial hold (min) 2.2.2.2. 
Final hold (min)     10.
I 1378.1376.1378.1376.1375.
ReferenceGohari, Hadjiakhoondi, et al., 2006Gohari, Hadjiakhoondi, et al., 2006Gohari A.R., Hadjiakhoondi A., et al., 2006Gohari A.R., Hadjiakhoondi A., et al., 2006Havlik, Kokoska, et al., 2006
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase CP Sil 5 CBDB-1DB-5HP-5HP-5
Column length (m) 30.30.30.30.30.
Carrier gas  HeHeliumHeliumHe
Substrate      
Column diameter (mm) 0.250.250.250.320.25
Phase thickness (μm) 0.250.250.250.250.25
Tstart (C) 40.50.60.60.100.
Tend (C) 220.265.260.260.240.
Heat rate (K/min) 3.2.53.5.5.
Initial hold (min)  1. 2.2.
Final hold (min) 3.20. 13.5.
I 1377.1364.1373.1378.1376.
ReferenceHymete, Rohloff, et al., 2006Iranshahi, Amin, et al., 2006Javidnia, Miri, et al., 2006Kucuk, Gulec, et al., 2006Lago, Soares, et al., 2006
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase DB-1BP-1CP Sil 5 CBCP Sil 5 CB5 % Phenyl methyl siloxane
Column length (m) 60.50.30.30.30.
Carrier gas  HeN2N2Helium
Substrate      
Column diameter (mm) 0.250.220.320.250.25
Phase thickness (μm) 0.250.250.250.250.25
Tstart (C) 70.60.50.50.60.
Tend (C) 230.220.300.200.280.
Heat rate (K/min) 2.2.4.5.3.
Initial hold (min) 2.    
Final hold (min) 20.20.  30.
I 1375.1376.1369.1379.1349.
ReferenceLan Phi N.T., Nishiyama C., et al., 2006Lesueur, Ban, et al., 2006Lis and Milczarek, 2006Martin, Joseph, et al., 2006Marongiu, Piras, et al., 2006
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase BP-1DB-5DB-5DB-5CP-Sil 5 CB
Column length (m) 25.30.30.30.25.
Carrier gas HeHeHeHeHydrogen
Substrate      
Column diameter (mm) 0.30.250.250.250.25
Phase thickness (μm)  0.250.250.250.15
Tstart (C) 70.60.60.50.50.
Tend (C) 220.220.220.250.230.
Heat rate (K/min) 4.4.4.4.3.
Initial hold (min) 2. 5.  
Final hold (min) 10.    
I 1372.1379.1380.1380.1381.
ReferenceMoody, Gundidza, et al., 2006Morteza-Semnani, Akbarzadeh, et al., 2006Morteza-Semnani K., Saeedi M., et al., 2006Najafpour Navaei, Mirza, et al., 2006Olawore, Usman, et al., 2006
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase NB-30DB-5DB-1HP-5MSHP-5
Column length (m) 30.25.50.30.30.
Carrier gas HeN2N2HeHe
Substrate      
Column diameter (mm) 0.20.250.250.250.25
Phase thickness (μm) 0.250.150.250.250.25
Tstart (C) 50.50.95.40.60.
Tend (C) 250.200.240.260.220.
Heat rate (K/min) 2.4.4.4.5.
Initial hold (min)  3.  10.
Final hold (min)      
I 1373.1385.1377.1380.1366.
ReferenceOrav, Raal, et al., 2006Ouamba, Ouabonzi, et al., 2006Pala-Paul J., Perez-Alonso M.J., et al., 2006Petrovic, Ristic, et al., 2006Pintore G., Chessa M., et al., 2006
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase DB-5DB-5DB-5HP-5MSHP-5MS
Column length (m) 30.30.30.30.30.
Carrier gas HydrogenHydrogenHydrogenHe 
Substrate      
Column diameter (mm) 0.250.250.250.250.25
Phase thickness (μm) 0.250.250.250.250.25
Tstart (C) 70.70.70.60.50.
Tend (C) 280.280.280.280.250.
Heat rate (K/min) 4.4.4.3.10.
Initial hold (min) 4.4.4. 5.
Final hold (min)      
I 1375.1376.1376.1340.1382.
ReferencePino, Marbot, et al., 2006Pino, Marbot, et al., 2006Pino, Marbot, et al., 2006Pitarokili, Tzakou, et al., 2006Robinson, 2006
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase DB-5DB-5DB-5HP-5DB-5
Column length (m) 30.30.30.25.30.
Carrier gas HeHeHeN2He
Substrate      
Column diameter (mm) 0.250.250.250.20.25
Phase thickness (μm) 0.250.250.250.330.25
Tstart (C) 60.60.40.30.40.
Tend (C) 200.260.260.280.250.
Heat rate (K/min) 2.5.2.3.4.
Initial hold (min)   5. 2.
Final hold (min) 60. 20. 10.
I 1375.1384.1372.1385.1367.
ReferenceRout, Naik, et al., 2006Sabulal, Dan, et al., 2006Senatore, Landolfi, et al., 2006Shafi, Jose, et al., 2006Shen X., Gao Y., et al., 2006
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase CP Sil 5 CBMethyl SiliconeSPB-5DB-1SPB-1
Column length (m) 25.25.60.50.50.
Carrier gas H2N2HeN2He
Substrate      
Column diameter (mm) 0.250.30.320.250.2
Phase thickness (μm)  0.151.0.250.33
Tstart (C) 50.50.40.90.50.
Tend (C) 230.210.230.240.220.
Heat rate (K/min) 3.2.3.4.4.
Initial hold (min)  5.5. 1.
Final hold (min)   2. 10.
I 1381.1384.1405.1360.1371.
ReferenceTesso, König, et al., 2006Tonzibo, Coffy, et al., 2006Tornambe, Cornu, et al., 2006Velasco-Negueruela, Pérez-Alonso, et al., 2006Wong, Lim, et al., 2006
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase HP-5MSHP-1DB-5DB-5DB-5
Column length (m) 30.50.50.25.30.
Carrier gas HeHe  He
Substrate      
Column diameter (mm) 0.250.20.30.250.25
Phase thickness (μm) 0.250.50.250.150.25
Tstart (C) 60.60.60.40.60.
Tend (C) 275.250.240.220.240.
Heat rate (K/min) 4.2.2.3.3.
Initial hold (min)    5. 
Final hold (min)  60.   
I 1375.1375.1378.1374.1380.
ReferenceAsadipour, Mehrabani, et al., 2005Bendimerad and Bendiab, 2005Chagonda and Chalchat, 2005Chagonda and Chalchat, 2005, 2Chaverri and Cicció, 2005
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase DB-5SPB-5BPX-5Polymethylsiloxane, (PMS-20000)HP-5
Column length (m) 30.60.25.25.25.
Carrier gas HeHeHeHeHe
Substrate      
Column diameter (mm) 0.250.320.220.200.2
Phase thickness (μm) 0.251.0.25 0.33
Tstart (C) 60.40.50.50.60.
Tend (C) 240.230.320.250.240.
Heat rate (K/min) 3.3.5.3.3.
Initial hold (min)  5.5.3. 
Final hold (min)     7.
I 1377.1405.1381.1367.1370.
ReferenceChaverri and Cicció, 2005Cornu, Kondjoyan, et al., 2005Dickschat, Martens, et al., 2005Dohou, Yamni, et al., 2005Duarte, Figueira, et al., 2005
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase CP Sil 8 CBDB-1DB-5HP-1HP-5
Column length (m) 30.60.30.50.30.
Carrier gas HeN2He He
Substrate      
Column diameter (mm) 0.250.250.250.20.25
Phase thickness (μm) 0.250.250.250.250.25
Tstart (C) 80.60.60.60.60.
Tend (C) 200.250.300.250.30.
Heat rate (K/min) 3.5.3.2.4.
Initial hold (min) 5. 3.60.3.
Final hold (min) 5.10.  15.
I 1375.1385.1363.1375.1377.
ReferenceFacey, Porter, et al., 2005Fakhari A.R., Sonboli A., et al., 2005Ferraz, Limberger, et al., 2005Fernandez, Lizzani-Cuvelier, et al., 2005Ferretti, Maggi, et al., 2005
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase HP-5HP-5MSHP-5MSHP-5MSCP Sil 5 CB
Column length (m) 30.30.25.30.30.
Carrier gas HeHeHeHeN2
Substrate      
Column diameter (mm) 0.250.250.250.250.25
Phase thickness (μm) 0.250.25 0.250.25
Tstart (C) 50.60.50.60.60.
Tend (C) 300.200.250.300.250.
Heat rate (K/min) 5.4.3.3.5.
Initial hold (min) 5.30.3.  
Final hold (min) 5. 10. 10.
I 1376.1368.1374.1373.1386.
ReferenceFiguérédo, Cabassu, et al., 2005Gauvin and Smadja, 2005Ghasemi Y., Faridi P., et al., 2005Grombone-Guaratini, Silva-Brandão, et al., 2005Jassbi, Mehrdad, et al., 2005
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase CP Sil 5 CBHP-5DB-1DB-1DB-5
Column length (m) 30.25.30.30.30.
Carrier gas N2H2HeHe 
Substrate      
Column diameter (mm) 0.250.320.250.250.25
Phase thickness (μm) 0.250.520.250.250.25
Tstart (C) 60.40.50.50.35.
Tend (C) 250.240.265.265.280.
Heat rate (K/min) 5.4.2.52.54.
Initial hold (min)   1.1.2.
Final hold (min) 10. 20.30. 
I 1387.1372.1359.1364.1379.
ReferenceJassbi, Mehrdad, et al., 2005Jovanovic, Kitic, et al., 2005Khanavi, Ghasemian, et al., 2005Khalighi-Sigaroodi, Hadijiakhoondi, et al., 2005Kowalski and Wolski, 2005
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase DB-5DB-5DB-5MSDB-5MSDB-5
Column length (m) 30.30.30.30.30.
Carrier gas HeliumHeHeHeHe
Substrate      
Column diameter (mm) 0.250.250.250.250.25
Phase thickness (μm) 0.250.250.250.250.25
Tstart (C) 35.60.60.60.60.
Tend (C) 280.230.280.280.220.
Heat rate (K/min) 4.3.3.3.4.
Initial hold (min) 2. 30.30.5.
Final hold (min)      
I 1380.1360.1353.1354.1377.
ReferenceKowalski, 2005Limberger, Sobral, et al., 2005Marongiu, Piras, et al., 2005Marongiu, Piras, et al., 2005Morteza-Semnani, Akbarzadeh, et al., 2005
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase DB-5DB-5CP Sil 5 CBHP-5DB-5
Column length (m) 30.30.25.30.30.
Carrier gas HeHe HeHe
Substrate      
Column diameter (mm) 0.250.250.250.250.32
Phase thickness (μm) 0.250.250.150.250.25
Tstart (C) 60.60.50.70.40.
Tend (C) 220.220.230.240.250.
Heat rate (K/min) 4.4.3.5.5.
Initial hold (min) 4.4.  0.5
Final hold (min)     2.
I 1377.1379.1380.1382.1377.
ReferenceMorteza-Semnani and Saeedi, 2005Morteza-Semnani and Saeedi, 2005, 2Olawore, Ogunwande, et al., 2005Oyedeji, Yani, et al., 2005Özel, Gögüs, et al., 2005
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase DB-1RTX-5 MSHP-5MSCP Sil 5 CBCP Sil 5 CB
Column length (m) 50.30.30.30.30.
Carrier gas N2He HeHe
Substrate      
Column diameter (mm) 0.250.250.20.250.25
Phase thickness (μm) 0.250.25 0.250.25
Tstart (C) 95.50.60.40.40.
Tend (C) 240.280.280.220.220.
Heat rate (K/min) 4.8.3.4.4.
Initial hold (min)  2. 1.1.
Final hold (min)  2.   
I 1366.1385.1377.1377.1377.
ReferencePala-Paul, Perez-Alonso, et al., 2005Pellati, Benvenuti, et al., 2005Petrakis, Roussis, et al., 2005Rohloff and Bones, 2005Rohloff and Bones, 2005
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase HP-5HP-5MSHP-5MSHP-5MSDB-5
Column length (m) 30.30.30.30.30.
Carrier gas HeHeHeHeHe
Substrate      
Column diameter (mm) 0.250.250.250.250.25
Phase thickness (μm)  0.250.250.250.25
Tstart (C) 60.60.60.60.60.
Tend (C) 240.280.275.280.220.
Heat rate (K/min) 5.4.4.4.3.
Initial hold (min)     4.
Final hold (min)      
I 1376.1374.1378.1372.1377.
ReferenceSaeidnia, Gohari, et al., 2005Sajjadi S.E. and Eskandari B., 2005Sajjadi and Ghannadi, 2005Sajjadi, 2005Salehi, Sefidkon, et al., 2005
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase DB-1DB-5DB-5HP-5MSDB-5
Column length (m) 30.30.30.30.30.
Carrier gas HeHeHeHeHe
Substrate      
Column diameter (mm) 0.250.250.250.250.25
Phase thickness (μm) 0.25 0.250.250.25
Tstart (C) 50.40.40.60.60.
Tend (C) 265.240.260.280.300.
Heat rate (K/min) 2.54.2.3.3.
Initial hold (min) 1. 5.5. 
Final hold (min) 20. 20.  
I 1362.1375.1371.1375.1370.
ReferenceSarkhail, Amin, et al., 2005Sefidkon and Jamzad, 2005Senatore, Apostolides Arnold, et al., 2005Setzer, Noletto, et al., 2005Simoes-Pires C.A., Debenedetti S., et al., 2005
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase DB-5HP-5MSRTX-1RTX-1DB-1
Column length (m) 30.30.60.60.60.
Carrier gas HeHeHeHeHe
Substrate      
Column diameter (mm) 0.250.250.250.250.25
Phase thickness (μm) 0.250.250.250.250.25
Tstart (C) 60.60.60.60.60.
Tend (C) 230.280.250.25.250.
Heat rate (K/min) 3.3.5.5.5.
Initial hold (min)      
Final hold (min) 20. 10.10.10.
I 1377.1373.1383.1382.1380.
ReferenceSkoula and Grayer, 2005Slavkovska, Couladis, et al., 2005Sonboli A., Fakhari A.R., et al., 2005Sonboli, Salehi, et al., 2005Sonboli, Salehi, et al., 2005, 2
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase BP-1RTX-5HP-5 MSHP-5MSDB-5
Column length (m) 30.30.30.30.30.
Carrier gas N2 HeHeHe
Substrate      
Column diameter (mm) 0.320.250.250.250.32
Phase thickness (μm) 0.250.250.500.250.25
Tstart (C) 60.60.60.60.60.
Tend (C) 220.220.260.280.280.
Heat rate (K/min) 5.3.3.3.3.
Initial hold (min)      
Final hold (min) 15. 20.  
I 1402.1375.1375.1340.1344.
ReferenceSrivastava, Srivastava, et al., 2005Szafranek, Chrapkowska, et al., 2005Topçu, Barla, et al., 2005Tzakou, Bazos, et al., 2005Tzakou and Constantinidis, 2005
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase DB-1DB-1HP-5MSHP-5DB-5
Column length (m) 50.50.30.30.30.
Carrier gas N2  HeH2
Substrate      
Column diameter (mm) 0.250.250.250.320.25
Phase thickness (μm) 0.250.250.250.250.25
Tstart (C) 90.60.40.60.50.
Tend (C) 240.240.220.260.290.
Heat rate (K/min) 4.3.3.5.4.
Initial hold (min)   5.2. 
Final hold (min)   10.13. 
I 1360.1357.1362.1378.1370.
ReferenceVelasco-Negueruela, Pérez-Alonso, et al., 2005Velasco-Negueruela, Pérez-Alonso, et al., 2005, 2Vichi, Riu-Aumatell, et al., 2005Yayli, Yasar, et al., 2005Abreu, Reis, et al., 2004
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase CP Sil 5 CBBP-1DB-5DB-1SPB-5
Column length (m) 30.50.30.30.60.
Carrier gas N2 HeN2He
Substrate      
Column diameter (mm) 0.250.220.250.250.32
Phase thickness (μm) 0.250.250.250.251.
Tstart (C) 50.60.60.50.60.
Tend (C) 200.220.240.200.200.
Heat rate (K/min) 5.2.2.5.4.
Initial hold (min)      
Final hold (min)  20.  30.
I 1374.1378.1377.1380.1391.
ReferenceAgnaniet, Menut, et al., 2004Blanc, Muselli, et al., 2004Cicció, 2004Fekam Boyom, Fotio, et al., 2004Gauvin, Ravaomanarivo, et al., 2004
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase DB-5ZB-5RTX-1SE-54DB-5
Column length (m) 25.60.30.30.30.
Carrier gas NitrogenHeN2HeHe
Substrate      
Column diameter (mm) 0.250.250.250.250.25
Phase thickness (μm) 0.250.250.250.250.25
Tstart (C) 60.40.60.60.60.
Tend (C) 240.260.300.260.300.
Heat rate (K/min) 3.6.4.2.3.
Initial hold (min)  4.6 5. 
Final hold (min)  1.   
I 1378.1399.1379.1371.1362.
ReferenceJAvidnia, Mojab, et al., 2004Jürgens and Dötterl, 2004Kalemba and Thiem, 2004Kilic, Hafizoglu, et al., 2004Lago, de Ávila, et al., 2004
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase DB-5MSDB-5RTX-1DB-5HP-5MS
Column length (m) 30.30.30.30.30.
Carrier gas HeHeN2 He
Substrate      
Column diameter (mm) 0.250.250.320.250.25
Phase thickness (μm) 0.250.250.250.250.25
Tstart (C) 60.60.60.40.60.
Tend (C) 240.300.300.210.280.
Heat rate (K/min) 3.3.4.2.3.
Initial hold (min)    2. 
Final hold (min)    33. 
I 1377.1370.1375.1368.1374.
Referencepaz Lima, Silva, et al., 2004Limberger, Sobral, et al., 2004Lis, Boczek, et al., 2004Lopez Arze, Collin, et al., 2004Malencic, Couladis, et al., 2004
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase HP-5MSDB-5MSHP-5MSDB-5HP-5MS
Column length (m) 30.30.30.30.30.
Carrier gas HeHeHe He
Substrate      
Column diameter (mm) 0.250.250.250.250.25
Phase thickness (μm) 0.250.250.250.150.25
Tstart (C) 60.60.60.60.60.
Tend (C) 280.280.275.220.280.
Heat rate (K/min) 3.3.4.3.3.
Initial hold (min)    3. 
Final hold (min)  30.   
I 1372.1345.1378.1373.1375.
ReferenceMalencic, Couladis, et al., 2004Marongiu, Porcedda, et al., 2004Mehrabani, Asadipour, et al., 2004Mevy, Bessiere, et al., 2004Mimica-Dukic, Bozin, et al., 2004
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase DB-1NB-30NB-30NB-30HP-5MS
Column length (m) 60.50.50.50.30.
Carrier gas HeHeHeHeHe
Substrate      
Column diameter (mm) 0.250.20.20.200.25
Phase thickness (μm) 0.250.250.250.250.25
Tstart (C) 50.50.50.50.60.
Tend (C) 270.250.250.250.280.
Heat rate (K/min) 4.2.2.2.4.
Initial hold (min)      
Final hold (min)      
I 1377.1375.1375.1373.1375.
ReferenceNik, Mirza, et al., 2004Orav, Stulova, et al., 2004Orav, Stulova, et al., 2004Raal, Paaver, et al., 2004Sajjadi and Shahpiri, 2004
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase DB-1DB-5HP-5DB-5CP Sil 5 CB
Column length (m) 30.30.25.30.20.
Carrier gas HeHeH2HeHe
Substrate      
Column diameter (mm) 0.250.250.320.250.25
Phase thickness (μm) 0.250.250.520.250.25
Tstart (C) 50.40.40.60.100.
Tend (C) 265.250.240.240.270.
Heat rate (K/min) 2.52.4.3.8.
Initial hold (min) 1.5.  2.
Final hold (min) 20.20.   
I 1362.1374.1377.1373.1370.
ReferenceSarkhail, Amin, et al., 2004Senatore, Rigano, et al., 2004Simic, Sokovic, et al., 2004Tellez, Khan, et al., 2004Thappa, Bakshi, et al., 2004
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase DB-5BPX-5CP Sil 8 CBHP-5HP-5
Column length (m) 30.25.30.30.30.
Carrier gas HeHe N2He
Substrate      
Column diameter (mm) 0.250.220.320.250.32
Phase thickness (μm) 0.251.0.250.250.25
Tstart (C) 60.60.50.60.100.
Tend (C) 300.250.200.220.240.
Heat rate (K/min) 3.3.5.5.5.
Initial hold (min)  5.5.10.2.
Final hold (min)  10.  5.
I 1377.1392.1383.1370.1376.
ReferenceTirillini, Pellegrino, et al., 2004Vilaseca, Guy, et al., 2004Wang, Guo, et al., 2004Bertoli, Menichini, et al., 2003Chaves, Lago, et al., 2003
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase DB-1HP-5MSHP-5MSHP-1DB-1
Column length (m) 60.30.30.30.30.
Carrier gas HeHeHeHeN2
Substrate      
Column diameter (mm) 0.250.250.250.250.25
Phase thickness (μm) 0.250.250.250.250.25
Tstart (C) 70.60.60.70.50.
Tend (C) 230.280.220.200.200.
Heat rate (K/min) 2.3.5.10.5.
Initial hold (min) 2. 20.  
Final hold (min) 20. 20.  
I 1387.1373.1384.1380.1361.
ReferenceChoi, 2003Couladis, Özcan, et al., 2003Feizbaksh, Saber Tehrani, et al., 2003Fekam Boyom, Amvam Zollo, et al., 2003Fekam Boyom, Ngouana, et al., 2003
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase HP-1HP-5MSHP-5MSMethyl SiliconeRSL-200
Column length (m) 50.30.30.30.30.
Carrier gas HeHeHeHeH2
Substrate      
Column diameter (mm) 0.20.250.250.320.32
Phase thickness (μm) 0.50.250.250.250.25
Tstart (C) 60.60.60.60.40.
Tend (C) 220.275.280.250.280.
Heat rate (K/min) 2.4.4.2.6.
Initial hold (min)    2.5.
Final hold (min) 45.  5.5.
I 1385.1375.1376.1378.1377.
ReferenceFernandez, Lizzani-Cuvelier, et al., 2003Ghannadi, Aghazari, et al., 2003Ghasemi, Asghari, et al., 2003Jayaprakasha, Rao, et al., 2003Jirovetz, Buchbauer, et al., 2003
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase RSL-200DB-5CP Sil 5 CBCP Sil 5 CBDB-5
Column length (m) 30.50.25.25.30.
Carrier gas H2HeHeHeHe
Substrate      
Column diameter (mm) 0.320.20.250.250.25
Phase thickness (μm) 0.250.250.250.390.25
Tstart (C) 40.50.35.60.60.
Tend (C) 280.220.280.220.250.
Heat rate (K/min) 6.3.5.5.3.
Initial hold (min) 5.2.2.5  
Final hold (min) 5.10.   
I 1378.1382.1370.1379.1371.
ReferenceJirovetz, Buchbauer, et al., 2003, 2Juteau, Jerkovic, et al., 2003Kanjilal, Kotoky, et al., 2003Khanavi, Hadjiakhoondi, et al., 2003Limberger, Simões-Pires, et al., 2003
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase DB-5MSDB-5DB-5DB-5CP Sil 5 CB
Column length (m) 30.30.30.50.25.
Carrier gas HeHeHeHe 
Substrate      
Column diameter (mm) 0.250.250.250.20.25
Phase thickness (μm) 0.250.250.250.250.39
Tstart (C) 60.60.60.50.60.
Tend (C) 240.280.280.220.220.
Heat rate (K/min) 3.3.3.3.5.
Initial hold (min)    2. 
Final hold (min)  30.30.  
I 1378.1370.1367.1382.1376.
ReferenceMaia, Taveira, et al., 2003Marongiu, Porcedda, et al., 2003Marongiu, Porcedda, et al., 2003Masotti, Juteau, et al., 2003Mazloomifar, Saber-Tehrani, et al., 2003
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase ZB-1DB-1DB-1HP-5CP Sil 5 CB
Column length (m) 30.60.60.30.25.
Carrier gas N2HeHeHeliumH2
Substrate      
Column diameter (mm) 0.250.250.250.320.25
Phase thickness (μm) 0.250.250.25 0.15
Tstart (C) 45.50.50.70.50.
Tend (C) 230.270.270.210.230.
Heat rate (K/min) 3.4.4.2.3.
Initial hold (min)      
Final hold (min)    60. 
I 1374.1372.1377.1370.1363.
ReferenceMierendorff, Stahl-Biskup, et al., 2003Mirza and Nik, 2003Mirza, Nik, et al., 2003Mookdasanit, Tamura, et al., 2003Oyedeji, Ekundayo, et al., 2003
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase DB-1DB-5HP-5DB-1DB-5
Column length (m) 50.30.30.60.30.
Carrier gas N2H2HeHeHe
Substrate      
Column diameter (mm) 0.250.250.250.250.2
Phase thickness (μm) 0.250.250.250.250.25
Tstart (C) 95.60.60.50.75.
Tend (C) 240.280.280.250.220.
Heat rate (K/min) 4.4.3.4.3.
Initial hold (min)  10.  4.
Final hold (min)  40.   
I 1365.1376.1357.1371.1370.
ReferencePerez-Alonso, Velasco-Negueruela, et al., 2003Pino, Marbot, et al., 2003Pitarokili, Tzakou, et al., 2003Pourmortazavi, Sefidkon, et al., 2003Priestap, van Baren, et al., 2003
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase HP-5Methyl SiliconeSPB-5DB-5HP-5
Column length (m) 30. 60.30.60.
Carrier gas HeHeHeliumHe 
Substrate      
Column diameter (mm) 0.25 0.320.250.25
Phase thickness (μm) 0.25 1.00.250.25
Tstart (C) 60.35.30.60.40.
Tend (C) 280.180.230.240.250.
Heat rate (K/min) 4.4.3.3.5.
Initial hold (min)     15.
Final hold (min)      
I 1373.1372.1404.1378.1388.
ReferenceSajjadi and Mehregan, 2003Santos and Cordeiro, 2003Sebastian, Viallon-Fernandez, et al., 2003da Silva, Luz, et al., 2003Stashenko, Jaramillo, et al., 2003
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase HP-5DB-5MSDB-1Cross-Linked MethylsiliconeHP-5
Column length (m) 60.30.50.25.25.
Carrier gas  HeN2HeH2
Substrate      
Column diameter (mm) 0.250.250.250.20.32
Phase thickness (μm) 0.250.250.250.330.53
Tstart (C) 40.60.90.70.40.
Tend (C) 250.240.240.250.280.
Heat rate (K/min) 5.3.4.4.4.
Initial hold (min) 15.    
Final hold (min)      
I 1388.1375.1339.1360.1371.
ReferenceStashenko, Jaramillo, et al., 2003Taveira, de Lima, et al., 2003Velasco-Negueruela, Pérez-Alonso, et al., 2003Velasco-Negueruela, Pérez-Alonso, et al., 2003, 2Velickovic, Randjelovic, et al., 2003
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase HP-5HP-5HP-5HP-5HP-5
Column length (m) 25.25.25.25.25.
Carrier gas H2HeliumHeliumHeliumHelium
Substrate      
Column diameter (mm) 0.320.320.320.320.32
Phase thickness (μm) 0.530.530.530.530.53
Tstart (C) 40.40.40.40.40.
Tend (C) 280.280.280.280.280.
Heat rate (K/min) 4.4.4.4.4.
Initial hold (min)      
Final hold (min)      
I 1377.1372.1372.1374.1377.
ReferenceVelickovic, Randjelovic, et al., 2003Velickovic, Ristic, et al., 2003Velickovic, Ristic, et al., 2003Velickovic, Ristic, et al., 2003Velickovic, Ristic, et al., 2003
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase SPB-1SPB-1SPB-1HP-5DB-5
Column length (m) 30.30.30.30.30.
Carrier gas HeHeHeHeHe
Substrate      
Column diameter (mm) 0.250.250.250.250.25
Phase thickness (μm) 0.250.250.250.320.25
Tstart (C) 40.40.40.60.60.
Tend (C) 200.200.200.250.240.
Heat rate (K/min) 3.3.3.5.3.
Initial hold (min) 10.10.10.30. 
Final hold (min)      
I 1367.1368.1390.1380.1378.
ReferenceVichi, Castellote, et al., 2003Vichi, Pizzale, et al., 2003Vichi, Pizzale, et al., 2003, 2Yassa, Akhani, et al., 2003Zoghbi, Andrade, et al., 2003
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase DB-5DB-1OV-101DB-5HP-1
Column length (m) 25.60.25.30.30.
Carrier gas N2He HeHe
Substrate      
Column diameter (mm) 0.250.250.320.250.25
Phase thickness (μm) 0.250.25 0.250.25
Tstart (C) 50.50.50.60.70.
Tend (C) 250.280.200.280.220.
Heat rate (K/min) 4.4.5.3.3.
Initial hold (min)      
Final hold (min) 10.  30.15.
I 1377.1373.1384.1370.1369.
ReferenceZrira, Elamrani, et al., 2003Ahmadi, Mirza, et al., 2002Boyom, Keumedjio, et al., 2002Caredda, Marongiu, et al., 2002Cavaleiro, Salgueiro, et al., 2002
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase 5 % Phenyl methyl siloxaneDB-5MSDB-5MSBP-1BPX-5
Column length (m) 30.30.30.25. 
Carrier gas HeHeHeN2 
Substrate      
Column diameter (mm) 0.250.250.250.50 
Phase thickness (μm) 0.250.250.250.25 
Tstart (C) 75.60.60.60.40.
Tend (C) 200.280.280.220.260.
Heat rate (K/min) 3.3.3.5.5.
Initial hold (min) 4.    
Final hold (min) 8.  10. 
I 1377.1378.1378.1380.1376.
ReferenceCicció and Gómez-Laurito, 2002Congiu, Falconieri, et al., 2002Congiu, Falconieri, et al., 2002Das, Ram, et al., 2002Diaz and Kite, 2002
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase DB-5PTE-5SE-30RSL-200RSL-200
Column length (m) 30.60.50.30.30.
Carrier gas HeH2HeH2H2
Substrate      
Column diameter (mm) 0.250.320.250.320.32
Phase thickness (μm) 0.250.300.250.250.25
Tstart (C) 60.60.70.40.50.
Tend (C) 240.285.240.280.280.
Heat rate (K/min) 3.4.34.6.6.
Initial hold (min)    5.5.
Final hold (min)    5.5.
I 1378.1376.1378.1377.1379.
ReferenceFlamini, Ertugrul, et al., 2002Gudzic, Djokovic, et al., 2002Iñigo, Palá-Paúl, et al., 2002Jirovetz, Buchbauer, et al., 2002Jirovetz, Ngassoum, et al., 2002
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase CP Sil 8 CBDB-1DB-5RTX-5DB-5
Column length (m) 30.25.30.30.30.
Carrier gas HeHeHeHeHe
Substrate      
Column diameter (mm) 0.250.230.250.250.25
Phase thickness (μm) 0.250.200.250.250.25
Tstart (C) 50.50.60.60.35.
Tend (C) 220.200.240.150.280.
Heat rate (K/min) 3.3.3.1.3.
Initial hold (min) 2.3. 3.2.
Final hold (min)  30.  15.
I 1384.1381.1375.1366.1379.
ReferenceJuteau, Masotti, et al., 2002Khallouki, Younos, et al., 2002Kobaisy, Tellez, et al., 2002Kovacevic and Kac, 2002Krauze-Baranowska, Mardarowicz, et al., 2002
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase OV-101HP-5DB-5HP-5DB-5
Column length (m) 25.30.30.30.25.
Carrier gas He He N2
Substrate      
Column diameter (mm) 0.320.320.250.250.23
Phase thickness (μm)  0.250.250.250.15
Tstart (C) 50.100.60.60.50.
Tend (C) 200.240.250.275.250.
Heat rate (K/min) 5.5.3.4.3.
Initial hold (min)  2. 4. 
Final hold (min)  5.   
I 1384.1362.1360.1375.1372.
ReferenceKuiate, Bessière, et al., 2002Lago, Reis, et al., 2002Limberger, Simões-Pires, et al., 2002Lockwood, Asghari, et al., 2002Mahmout, Bessière, et al., 2002
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase DB-5DB-5MSOV-101HP-1DB-5
Column length (m) 30.30.25.50.25.
Carrier gas HeHeHeN2He
Substrate      
Column diameter (mm) 0.250.250.320.250.2
Phase thickness (μm) 0.250.25 0.25 
Tstart (C) 60.60.50.90.60.
Tend (C) 240.240.200.220.220.
Heat rate (K/min) 3.3.5.3.3.
Initial hold (min)      
Final hold (min)      
I 1376.1378.1377.1371.1379.
ReferenceMaia, da Silva, et al., 2002Maia, Zoghbi, et al., 2002Menut, Bessière, et al., 2002Priestap, van Baren, et al., 2002Schwob, Bessière, et al., 2002
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase DB-1DB-1DB-1HP-5DB-1
Column length (m) 60.60.50.30.60.
Carrier gas HeHeN2H2He
Substrate      
Column diameter (mm) 0.250.250.250.250.25
Phase thickness (μm)  0.250.250.250.25
Tstart (C) 40.40.60.40.50.
Tend (C) 250.280.240.280.250.
Heat rate (K/min) 4.4.3.4.4.
Initial hold (min)  5.  5.
Final hold (min)      
I 1369.1372.1339.1376.1372.
ReferenceSefidkon, Dabiri, et al., 2002Sefidkon, 2002Velasco-Negueruela, Pérez-Alonso, et al., 2002Velickovic, Randjelovic, et al., 2002Yamini, Sefidkon, et al., 2002
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase DB-5MSDB-5SPB-5DB-1DB-1
Column length (m) 30.30.60.60.60.
Carrier gas HeHeHeHeHe
Substrate      
Column diameter (mm) 0.250.250.320.250.25
Phase thickness (μm) 0.250.25 0.250.25
Tstart (C) 60.60.40.40.40.
Tend (C) 270.240.220.280.280.
Heat rate (K/min) 3.3.3.4.4.
Initial hold (min)   5.5.5.
Final hold (min)   15.  
I 1377.1378.1377.1365.1371.
ReferenceZoghbi, Andrade, et al., 2002Zoghbi, Andrade, et al., 2002, 2Cornu, Carnat, et al., 2001Dabiri and Sefidkon, 2001Dabiri and Sefidkon, 2001
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase HP-5OV-1HP-5BP-1Optima-5
Column length (m) 30.30.30.30.30.
Carrier gas N2H2N2N2He
Substrate      
Column diameter (mm) 0.250.320.250.250.2
Phase thickness (μm) 0.250.30.250.25 
Tstart (C) 60.50.60.60.50.
Tend (C) 220.250.220.220.250.
Heat rate (K/min) 5.3.5.5.3.
Initial hold (min) 10.1.10. 3.
Final hold (min)  20.   
I 1377.1360.1377.1380.1387.
ReferenceFlamini, Cioni, et al., 2001Gallori, Bilia, et al., 2001Gallori, Flamini, et al., 2001Gupta, Mallavarapu, et al., 2001Jacquemond-Collet, Bessière, et al., 2001
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase RSL-200RTX-1CBP-1DB-1OV-101
Column length (m) 30.30.25.60.50.
Carrier gas H2N2NitrogenHeHe
Substrate      
Column diameter (mm) 0.320.250.250.250.2
Phase thickness (μm) 0.250.250.250.25 
Tstart (C) 40.60.50.50.50.
Tend (C) 280.300.210.270.250.
Heat rate (K/min) 6.4.3.4.2.
Initial hold (min) 5. 2.  
Final hold (min) 5.    
I 1374.1379.1369.1371.1369.
ReferenceJirovetz L., Buchbauer G., et al., 2001Kalemba, Marschall, et al., 2001Ly, Yamauchi, et al., 2001Mirza, Ahmadi, et al., 2001Orav and Kann, 2001
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase DB-5DB-1DB-1DB-5OV-101
Column length (m) 30.30.30.30.50.
Carrier gas HeN2HeHeN2
Substrate      
Column diameter (mm) 0.250.250.20.250.25
Phase thickness (μm) 0.250.25 0.25 
Tstart (C) 60.80.60.60.80.
Tend (C) 270.225.240.240.200.
Heat rate (K/min) 3.4.3.3.2.
Initial hold (min)      
Final hold (min)      
I 1378.1364.1372.01376.1380.
ReferencePalmeira, Conserva, et al., 2001Palá-Paúl, Pérez-Alonso, et al., 2001Santos, Moreira, et al., 2001Tellez M., Estell R., et al., 2001Yang, 2001
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase OV-101RSL-200DB-1HP-1DB-5
Column length (m) 50.60.25.60.30.
Carrier gas N2H2NitrogenHeN2
Substrate      
Column diameter (mm) 0.250.320.500.250.22
Phase thickness (μm)  0.250.250.250.25
Tstart (C) 80.40.60.60.70.
Tend (C) 200.250.220.200.230.
Heat rate (K/min) 2.6.5.4.4.
Initial hold (min)    5.2.
Final hold (min)    25.20.
I 1380.1374.1378.1384.1370.
ReferenceYang, 2001, 2Jirovetz, Puschmann, et al., 2000Mallavarapu, Rao, et al., 2000Meccia, Rojas, et al., 2000Mitiku, Sawamura, et al., 2000
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase OV-101DB-5CP Sil 5 CBOV-101SPB-1
Column length (m) 50.30.25.25.50.
Carrier gas NitrogenHeH2N2 
Substrate      
Column diameter (mm) 0.250.250.250.250.2
Phase thickness (μm)  0.250.15 0.33
Tstart (C) 40.60.50.50.60.
Tend (C) 200.240.320.200.260.
Heat rate (K/min) 2.3.3.5.4.
Initial hold (min) 10.    
Final hold (min)      
I 1380.1377.1368.1378.1375.
ReferenceTamura, Boonbumrung, et al., 2000Tellez, Dayan, et al., 2000Asekun and Ekundayo, 1999Ayedoun, Adéoti, et al., 1999Choo, Wong, et al., 1999
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase RTX-1Ultra-2OV-101HP-1DB-1
Column length (m) 30.50.25.25.50.
Carrier gas N2  H2He
Substrate      
Column diameter (mm) 0.250.320.320.320.25
Phase thickness (μm) 0.25  0.170.25
Tstart (C) 60.32.50.40.70.
Tend (C) 300.250.200.260.240.
Heat rate (K/min) 4.4.5.3.4.
Initial hold (min)  5. 5. 
Final hold (min)      
I 1381.1371.1384.1365.1363.
ReferenceKalemba, 1999Khalilov L.M., Khalilova A.Z., et al., 1999Kuiate, Zollo, et al., 1999Lopes, Koketsu, et al., 1999Palá-Paúl, Pérez-Alonso, et al., 1999
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase Ultra-2CP Sil 5 CBDB-5DB-5DB-5
Column length (m) 25.25.30.30.30.
Carrier gas  HeHeH2He
Substrate      
Column diameter (mm) 0.20.250.250.320.25
Phase thickness (μm)  0.390.25 0.25
Tstart (C) 40.60.40.32.60.
Tend (C) 300.220.220.260.240.
Heat rate (K/min) 5.5.4.7.3.
Initial hold (min) 4.5.5.5. 
Final hold (min)  20. 5. 
I 1386.1380.1372.1418.1376.
ReferenceQuiroz, Fuentes-Contreras, et al., 1999Rustaiyan, Masoudi, et al., 1999Sefidkon and Khajavi, 1999Sun and Petracek, 1999Tellez, Canel, et al., 1999
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase SPB-5DB-5MSOV-101SPB-5DB-5
Column length (m) 60.30.50.50.30.
Carrier gas HeHeHeHeHe
Substrate      
Column diameter (mm) 0.320.250.220.320.25
Phase thickness (μm) 1.0.251.0.250.25
Tstart (C) 40.60.100.60.60.
Tend (C) 200.240.220.240.240.
Heat rate (K/min) 3.3.1.3.3.
Initial hold (min) 5. 1.  
Final hold (min) 2.  20. 
I 1403.1375.1363.1383.1374.
ReferenceViallon C., Verdier-Metz I., et al., 1999Zoghbi, Andrade, et al., 1999Camciuc, Bessière, et al., 1998Doneanu and Anitescu, 1998El-Sakhawy, El-Tantawy, et al., 1998
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase OV-1DB-5HP-5DB-5HP-1
Column length (m) 50.30.25.30.60.
Carrier gas HeHeHeHeliumHe
Substrate      
Column diameter (mm) 0.320.250.20.250.25
Phase thickness (μm) 0.250.250.330.250.25
Tstart (C) 50.60.70.60.50.
Tend (C) 250.240.290.240.280.
Heat rate (K/min) 10.3.3.3.4.
Initial hold (min) 5. 8. 5.
Final hold (min) 20. 20.  
I 1376.1376.1379.1376.1368.
ReferenceKökdil, Kurucu, et al., 1998Maia, Zohhbi, et al., 1998Poiana, Sicari, et al., 1998Santos, Andrade, et al., 1998Stashenko, Cervantes, et al., 1998
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase OV-101CP Sil 5 CBDB-5OV-1OV-1
Column length (m) 25.25.30.30.30.
Carrier gas  HeHeHe 
Substrate      
Column diameter (mm) 0.320.250.250.320.32
Phase thickness (μm)  0.250.250.250.25
Tstart (C) 50.60.65.40.40.
Tend (C) 200.300.300.270.270.
Heat rate (K/min) 5.6.4.2.2.
Initial hold (min)   2.4.4.
Final hold (min)      
I 1378.1366.1382.1360.1359.
ReferenceZollo, Biyiti, et al., 1998Bos, Woerdenbag, et al., 1997Elias, Simoneit, et al., 1997Kökdil, Kurucu, et al., 1997Kökdil, Tanker, et al., 1997
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase DB-1DB-5DB-5CBP-1HP-1
Column length (m)  30.30.25.23.
Carrier gas  HeliumHeHeHe
Substrate      
Column diameter (mm)  0.250.250.220.32
Phase thickness (μm)  0.25  0.17
Tstart (C) 80.60.60.60.60.
Tend (C) 220.240.240.240.250.
Heat rate (K/min) 6.3.4.5.5.
Initial hold (min)     3.
Final hold (min)     30.
I 1375.1376.1375.1376.1371.
ReferenceSalgueiro, Vila, et al., 1997Tellez, Estell, et al., 1997Zunino, Novillo-Newton, et al., 1997Zygadlo, Ariza-Espinar, et al., 1997Ayedoun, Adeoti, et al., 1996
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase OV-101DB-5OV-101DB-1HP-1
Column length (m) 50.30.50.60.25.
Carrier gas N2 HeHeHelium
Substrate      
Column diameter (mm) 0.250.250.250.250.32
Phase thickness (μm) 0.170.25 0.250.25
Tstart (C) 50.60.50.50.60.
Tend (C) 220.300.250.250.220.
Heat rate (K/min) 5.4.2.2.54.
Initial hold (min)  2. 5.2.
Final hold (min)  5.  20.
I 1391.1375.41370.1373.1370.
ReferenceChacko, Jayalekshmy, et al., 1996Gawdzik, Mardarowicz, et al., 1996Orav, Kailas, et al., 1996Stashenko, Puertas, et al., 1996Thanh, Dung, et al., 1996
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase OV-101HP-5DB-1DB-1HP-5
Column length (m) 52. 60.60. 
Carrier gas He He  
Substrate      
Column diameter (mm) 0.26 0.250.32 
Phase thickness (μm)   0.250.50 
Tstart (C) 50.35.50.50.40.
Tend (C) 220.200.250.225.210.
Heat rate (K/min) 3.6.3.52.2.
Initial hold (min)  2.5.  
Final hold (min)      
I 1374.1402.1368.1387.1375.
ReferenceDzumayev, Tsibulskaya, et al., 1995Larsen and Frisvad, 1995Stashenko, Torres, et al., 1995Sagrero-Nieves, Bartley, et al., 1994Collin, Deslauriers, et al., 1993
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase HP-5HP-101Methyl SiliconeMethyl SiliconeMethyl Silicone
Column length (m)  50.50.50.25.
Carrier gas  H2N2N2 
Substrate      
Column diameter (mm)  0.320.250.250.50
Phase thickness (μm)  0.30.170.17 
Tstart (C) 40.65.80.80.60.
Tend (C) 210.300.200.200.220.
Heat rate (K/min) 2.2.2.3.5.
Initial hold (min)  5.   
Final hold (min)      
I 1376.1360.1398.1384.1370.
ReferenceCollin, Deslauriers, et al., 1993Demarne and van der Walt, 1993Gopalakrishnan, Menon, et al., 1993Gopalakrishnan, Menon, et al., 1993Mallavarapu, Ramesh, et al., 1993
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase SE-54DB-1DB-1DB-1DB-1
Column length (m) 30.30.60. 60.
Carrier gas HydrogenN2   
Substrate      
Column diameter (mm) 0.25 0.32 0.32
Phase thickness (μm) 0.25    
Tstart (C) 60.80.50.50.50.
Tend (C) 250.220.230.230.230.
Heat rate (K/min) 2.4.4.4.4.
Initial hold (min) 5.    
Final hold (min) 2. 10.10.10.
I 1369.1381.1373.1373.1373.
ReferenceKollmannsberger, Nitz, et al., 1992Velasco-Negueruela, Pérez Alonso, et al., 1991Binder, Benson, et al., 1990Binder, Turner, et al., 1990Binder, Turner, et al., 1990, 2
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase CP Sil 8 CBBP-1OV-101OV-101DB-1
Column length (m) 25.25.50.50.60.
Carrier gas   N2N2 
Substrate      
Column diameter (mm) 0.200.330.250.250.32
Phase thickness (μm)      
Tstart (C) 60.45.80.80.50.
Tend (C) 230.180.200.200.250.
Heat rate (K/min) 3.3.2.2.4.
Initial hold (min) 10.3.  0.1
Final hold (min)     5.
I 1381.1372.1379.1380.1373.
ReferenceJantan and Goh, 1990Wyllie, Brophy, et al., 1990Yang and Sugisawa, 1990Yang and Sugisawa, 1990Binder and Flath, 1989
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase BP-1SE-30OV-101OV-101OV-101
Column length (m) 50.40.50.50.50.
Carrier gas H2HeN2N2N2
Substrate      
Column diameter (mm) 0.300.500.250.250.25
Phase thickness (μm)  0.75   
Tstart (C) 40.30.80.80.80.
Tend (C) 250.220.200.200.200.
Heat rate (K/min) 10.3.2.2.2.
Initial hold (min) 1.    
Final hold (min)      
I 1379.1371.1380.1380.1380.
ReferenceBrophy, Davies, et al., 1989de Pooter, de Buyck, et al., 1989Sugisawa, Yamamoto, et al., 1989Sugisawa, Yang, et al., 1989Sugisawa, Yang, et al., 1989
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase DB-1DB-1SE-54OV-1SE-30
Column length (m) 60.60.25.50.30.
Carrier gas HeHeN2He 
Substrate      
Column diameter (mm) 0.320.320.250.20 
Phase thickness (μm)    0.20 
Tstart (C) 30.30.60.30.50.
Tend (C) 210.210.260.220.240.
Heat rate (K/min) 2.2.6.2.4.
Initial hold (min) 4.4.2. 2.
Final hold (min)     10.
I 1370.1370.1379.1372.1369.
ReferenceTakeoka and Butter, 1989Takeoka and Butter, 1989Bestmann, Classen, et al., 1988de Pooter, Nicolai, et al., 1988Ramaswami, Briscese, et al., 1988
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase OV-101DB-1OV-101SE-30OV-3
Column length (m) 50.10.30.30.150.
Carrier gas  H2He  
Substrate      
Column diameter (mm) 0.300.250.5 0.66
Phase thickness (μm)  0.250.8  
Tstart (C) 40.50.40.50.20.
Tend (C) 230.250.220.240.170.
Heat rate (K/min) 3.55.2.4.1.
Initial hold (min) 5.  2. 
Final hold (min)    10. 
I 1374.1375.1372.1369.1390.
ReferenceNykanen, 1986Perry, Baxter, et al., 1986De Pooter and Schamp, 1986Ramaswami, Briscese, et al., 1986Buttery, Xu, et al., 1985
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI

References

Go To: Top, Normal alkane RI, non-polar column, temperature ramp, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

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Gilani, Shah, et al., 2009
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Ho, Wang, et al., 2009
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Karlsson, Birgersson, et al., 2009
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Kim and Chung, 2009
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Lawal and Oyedelji, 2009
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Museli, Pau, et al., 2009
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Rahimi-Nasrabadi, Gholivand, et al., 2009
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Retta, Gattuso, et al., 2009
Retta, D.; Gattuso, M.; Gattuso, S.; Lira, P. Di Leo; van Baren, C.; Ferraro, G.; Bandoni A., Essential oil composition of Achyrocline flaccida (Weinm.) DC. (Asteraceae) from different locations of Argentina, Biochem. Systematics Ecol., 2009, 36, 12, 877-881, https://doi.org/10.1016/j.bse.2008.11.001 . [all data]

Shimizu, Imayoshi, et al., 2009
Shimizu, Y.; Imayoshi, Y.; Kato, M.; Maeda, K.; Iwabuchi, H.; Shimomura, K., Volatiles from leaves of field-grown plants and shoot cultures of Gynura bicolor DC, Flavour Fragr. J., 2009, 24, 5, 251-258, https://doi.org/10.1002/ffj.1938 . [all data]

Zhao, Zeng, et al., 2009
Zhao, C.; Zeng, Y.; Wan, M.; Li, R.; Liang, Y.; Li, C.; Zeng, Z.; Chau, F.-T., Comparative analysis of essential oils from eight herbal medicines with pungent flavor and cool nature by GC-MS and chemometric resolution methods, J. Sep. Sci., 2009, 32, 4, 660-670, https://doi.org/10.1002/jssc.200800484 . [all data]

Aicha, Ines, et al., 2008
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Diaz and Kite, 2002
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Kovacevic and Kac, 2002
Kovacevic, N.; Kac, M., Analytical, nutritional, and clinical methods section. Determination and verification of hop varieties by analysis of essential oils, Food Chem., 2002, 77, 4, 489-494, https://doi.org/10.1016/S0308-8146(02)00114-0 . [all data]

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Maia, J.G.S.; da Silva, M.H.L.; Andrade, E.H.A.; Zoghbi, M.G.B.; Carreira, L.M.M., Essential oils from Astronium urundeuva (Allemao) Engl. and A. fraxinifolium Schott ex Spreng., Flavour Fragr. J., 2002, 17, 1, 72-74, https://doi.org/10.1002/ffj.1046 . [all data]

Maia, Zoghbi, et al., 2002
Maia, J.G.S.; Zoghbi, M.G.B.; Andrade, E.H.A.; da Silva, M.H.L.; Luz, A.I.R.; da Silva, J.D., Essential oils composition of Eupatorium species growing wild in the Amazon, Biochem. Syst. Ecol., 2002, 30, 11, 1071-1077, https://doi.org/10.1016/S0305-1978(02)00059-5 . [all data]

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Sefidkon, F.; Dabiri, M.; Alamshahi, A., Analysis of the essential oil of Nepeta fissa C.A. Mey from Iran, Flavour Fragr. J., 2002, 17, 2, 89-90, https://doi.org/10.1002/ffj.1045 . [all data]

Sefidkon, 2002
Sefidkon, F., Essential oil of Lantana camara L. occurring in Iran, Flavour Fragr. J., 2002, 17, 1, 78-80, https://doi.org/10.1002/ffj.1048 . [all data]

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Yamini, Y.; Sefidkon, F.; Pourmortazavi, S.M., Comparison of essential oil composition of Iranian fennel (Foeniculum vulgare) obtained by supercritical carbon dioxide extraction and hydrodistillation methods, Flavour Fragr. J., 2002, 17, 5, 345-348, https://doi.org/10.1002/ffj.1117 . [all data]

Zoghbi, Andrade, et al., 2002
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Cornu, A.; Carnat, A.-P.; Martin, B.; Coulon, J.-B.; Lamaison, J.-L.; Berdagué, J.-L., Solid-phase microextraction of volatile components from natural grassland plants, J. Agric. Food Chem., 2001, 49, 1, 203-209, https://doi.org/10.1021/jf0008341 . [all data]

Dabiri and Sefidkon, 2001
Dabiri, M.; Sefidkon, F., Analysis of the essential oil from aerial parts of Perovskia atriplicifolia Benth. at different stages of plant growth, Flavour Fragr. J., 2001, 16, 6, 435-438, https://doi.org/10.1002/ffj.988 . [all data]

Flamini, Cioni, et al., 2001
Flamini, G.; Cioni, P.L.; Morelli, I.; Maccioni, S.; Monti, G., Composition of the essential oil of Teucrium fruticans L. from the Maremma Regional Park (Tuscany, Italy), Flavour Fragr. J., 2001, 16, 5, 367-369, https://doi.org/10.1002/ffj.1014 . [all data]

Gallori, Bilia, et al., 2001
Gallori, S.; Bilia, A.R.; Mulinacci, N.; Bicchi, C.; Rubiolo, P.; Vincieri, F.F., Identification of volatile constituents of Tambourissa leptophylla, Planta Medica, 2001, 67, 3, 290-292, https://doi.org/10.1055/s-2001-12001 . [all data]

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Gupta, Mallavarapu, et al., 2001
Gupta, R.; Mallavarapu, G.R.; Banerjee, S.; Kumar, S., Characteristics of an isomenthone-rich somaclonal mutant isolated in a geraniol-rich rose-scented geranium accession of Pelargonium graveolens, Flavour Fragr. J., 2001, 16, 5, 319-324, https://doi.org/10.1002/ffj.1002 . [all data]

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Jirovetz L.; Buchbauer G.; Shafi P.M.; Rosamma M.K.; Geissler M., Analysis of the composition and aroma of the essential leaf oil of Syzygium travancoricum from South India by GC-FID, GC-MS, and olfactometry. Seasonal changes of composition, Chromatographia Sup., 2001, 53, S1, s372-s374, https://doi.org/10.1007/BF02490359 . [all data]

Kalemba, Marschall, et al., 2001
Kalemba, D.; Marschall, H.; Bradesi, P., Constituents of the essential oil of Solidago gigantea Ait. (giant goldenrod), Flavour Fragr. J., 2001, 16, 1, 19-26, https://doi.org/10.1002/1099-1026(200101/02)16:1<19::AID-FFJ940>3.0.CO;2-U . [all data]

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Ly, T.N.; Yamauchi, R.; KAto, K., Volatile components of the essential oils in Galanga (Alpina officinarum Hance) from Vietnam, Food Sci. Technol. Res., 2001, 7, 4, 303-306, https://doi.org/10.3136/fstr.7.303 . [all data]

Mirza, Ahmadi, et al., 2001
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Orav and Kann, 2001
Orav, A.; Kann, J., Determination of peppermint and orange aroma compounds in food and beverages, Proc. Est. Acad. Sci. Chem., 2001, 50, 4, 217-225. [all data]

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Notes

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