Galactaric acid, 6TMS derivative

• Formula: C₂₄H₅₈O₈Si₆
• Molecular weight: 643.2255
• IUPAC Standard InChI: InChI=1S/C24H58O8Si6/c1-33(2,3)27-19(21(29-35(7,8)9)23(25)31-37(13,14)15)20(28-34(4,5)6)22(30-36(10,11)12)24(26)32-38(16,17)18/h19-22H,1-18H3/t19-,20-,21-,22+/m0/s1 Copy

  
• IUPAC Standard InChIKey: AFNUGMFTFWKGLV-MYGLTJDJSA-N Copy
• CAS Registry Number: 38165-96-7
• Chemical structure:
  This structure is also available as a 2d Mol file or as a computed 3d SD file
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• Stereoisomers:
  • Galactaric acid, (R,S,R,S)-, 6TMS derivative
  • Allaric acid, TMS
  • Altraric acid, TMS
  • Idaric acid, TMS
  • Mannaric acid, TMS
  • Mucic acid, TMS # 1
  • Mucic acid, TMS # 2
  • Mucic acid, TMS # 3
  • Mucic acid, TMS # 4
  • Saccharic acid, TMS # 1
  • Saccharic acid, TMS # 2
  • Saccharic acid, TMS # 3
  • Saccharic acid, TMS # 4
  • Saccharic acid, TMS # 5
  • SACCHARIC ACID (6TMS)
• Other names: Glucaric acid, 2,3,4,5-tetrakis-O-(trimethylsilyl)-, bis(trimethylsilyl) ester; Hexakis(trimethysilyl)glucaric acid; 1,6-Bis(trimethylsilyl) 2,3,4,5-tetrakis-O-(trimethylsilyl)glucarate; Glucaric acid, hexakis-TMS; Glucaric acid, (6TMS)-; Glucaric acid, TMS
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• Information on this page:
  • Mass spectrum (electron ionization)
  • Gas Chromatography
  • References
  • Notes
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Mass spectrum (electron ionization)

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Spectrum

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Additional Data

Gas Chromatography

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Kovats' RI, non-polar column, isothermal

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Van Den Dool and Kratz RI, non-polar column, temperature ramp

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Normal alkane RI, non-polar column, temperature ramp

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Normal alkane RI, non-polar column, custom temperature program

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References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Petersson, 1977
Petersson, G., Retention Data in GLC Analysis; Carbohydrate-Related Hydroxy Carboxylic and Dicarboxylic Acids as Trimethylsilyl Derivatives, J. Chromatogr. Sci., 1977, 15, 7, 245-255, https://doi.org/10.1093/chromsci/15.7.245 . [all data]

Wagner, Sefkow, et al., 2003
Wagner, C.; Sefkow, M.; Kopka, J., Construction and application of a mass spectral and retention time index database generated from plant GC/EI-TOF-MS metabolite profiles, Phytochemistry, 2003, 62, 6, 887-900, https://doi.org/10.1016/S0031-9422(02)00703-3 . [all data]

Tuchman, Bowers, et al., 1984
Tuchman, M.; Bowers, L.D.; Fregien, K.D.; Crippin, P.J.; Krivit, W., Capillary Gas Chromatographic Separation of Urinary Organic Acids. Retention Indices of 101 Urinary Acids on a 5% Phenylmethyl Silicone Capillary Column, J. Chromatogr. Sci., 1984, 22, 5, 198-202, https://doi.org/10.1093/chromsci/22.5.198 . [all data]

Isidorov, Lech, et al., 2008
Isidorov, V.A.; Lech, P.; Zolciak, A.; Rusak, N.; Szczepaniak, L., Gas Chromatographic - nass spectrometric investigation of metabolites from the needles and roots of pine seedlings at early stages of pathogenic fungi Armillaria ostoyae attack, Trees, 2008, 22, 4, 531-542, https://doi.org/10.1007/s00468-008-0213-z . [all data]

Notes

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• Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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