Diethylhydroxylamine

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Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Quantity Value Units Method Reference Comment
Δfgas-121.77 ± 0.73kJ/molCcrSteele, Chirico, et al., 1990 

Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DH - Eugene S. Domalski and Elizabeth D. Hearing

Quantity Value Units Method Reference Comment
Δfliquid-174.75 ± 0.72kJ/molCcrSteele, Chirico, et al., 1990ALS
Quantity Value Units Method Reference Comment
Δcliquid-2971.35 ± 0.66kJ/molCcrSteele, Chirico, et al., 1990ALS

Constant pressure heat capacity of liquid

Cp,liquid (J/mol*K) Temperature (K) Reference Comment
370.8298.15Steele, Chirico, et al., 1990DH

Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
BS - Robert L. Brown and Stephen E. Stein
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Quantity Value Units Method Reference Comment
Tboil400.7KN/AAldrich Chemical Company Inc., 1990BS
Tboil406.2KN/AWeast and Grasselli, 1989BS
Quantity Value Units Method Reference Comment
Δvap52.98 ± 0.12kJ/molVSteele, Chirico, et al., 1990ALS

Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

C4H10NO- + Hydrogen cation = Diethylhydroxylamine

By formula: C4H10NO- + H+ = C4H11NO

Quantity Value Units Method Reference Comment
Δr1551. ± 8.8kJ/molG+TSBartmess, Basso, et al., 1983gas phase; See also Mahoney, Mendenhall, et al., 1973, Bordwell and Liu, 1996 for supporting DH values
Quantity Value Units Method Reference Comment
Δr1523. ± 8.4kJ/molIMREBartmess, Basso, et al., 1983gas phase; See also Mahoney, Mendenhall, et al., 1973, Bordwell and Liu, 1996 for supporting DH values

IR Spectrum

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Coblentz Society, Inc.

Spectrum

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IR spectrum
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Notice: Except where noted, spectra from this collection were measured on dispersive instruments, often in carefully selected solvents, and hence may differ in detail from measurements on FTIR instruments or in other chemical environments. More information on the manner in which spectra in this collection were collected can be found here.

Notice: Concentration information is not available for this spectrum and, therefore, molar absorptivity values cannot be derived.

Additional Data

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Owner Copyright (C) 1987 by the Coblentz Society
Collection (C) 2018 copyright by the U.S. Secretary of Commerce
on behalf of the United States of America. All rights reserved.
Origin WESTERN REGIONAL RES. USDA
Source reference COBLENTZ NO. 9886
Date 1967/04/19
Name(s) N,N-diethylhydroxylamine
1-[ethyl(hydroxy)amino]ethane
Instrument CARY 90 (GRATING)
Instrument parameters GRATING CHANGES: 3000, 2000, 1200 CM-1
Path length CAPILLARY
Resolution LIQUID (NEAT)
Sampling procedure TRANSMISSION
Data processing DIGITIZED BY COBLENTZ SOCIETY (BATCH II) FROM HARD COPY

This IR spectrum is from the Coblentz Society's evaluated infrared reference spectra collection.


Mass spectrum (electron ionization)

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Spectrum

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Mass spectrum
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Additional Data

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Due to licensing restrictions, this spectrum cannot be downloaded.

Owner NIST Mass Spectrometry Data Center
Collection (C) 2014 copyright by the U.S. Secretary of Commerce
on behalf of the United States of America. All rights reserved.
Origin James Little,Eastman Chem.Co.,Kingsport,TN
NIST MS number 288357

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References

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Reaction thermochemistry data, IR Spectrum, Mass spectrum (electron ionization), Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Steele, Chirico, et al., 1990
Steele, W.V.; Chirico, R.D.; Nguyen, A.; Hossenlopp, I.A.; Smith, N.K., Determination of ideal-gas enthalpies of formation for key compounds, Am. Inst. Chem. Eng. Symp. Ser. (AIChE Symp. Ser.), 1990, 138-154. [all data]

Aldrich Chemical Company Inc., 1990
Aldrich Chemical Company Inc., Catalog Handbook of Fine Chemicals, Aldrich Chemical Company, Inc., Milwaukee WI, 1990, 1. [all data]

Weast and Grasselli, 1989
CRC Handbook of Data on Organic Compounds, 2nd Editon, Weast,R.C and Grasselli, J.G., ed(s)., CRC Press, Inc., Boca Raton, FL, 1989, 1. [all data]

Bartmess, Basso, et al., 1983
Bartmess, J.E.; Basso, T.; eorgiadis, R.M., The electron affinity of a nitroxide radical, J. Phys. Chem., 1983, 87, 912. [all data]

Mahoney, Mendenhall, et al., 1973
Mahoney, L.R.; Mendenhall, G.D.; Ingold, K.U., Calorimetric and Equilibrium Studies on Some Stable Nitroxide and Iminoxy Radicals. Approximate O-H BDEs in Hydroxylamines and Oximes., J. Am. Chem. Soc., 1973, 95, 26, 8610, https://doi.org/10.1021/ja00807a018 . [all data]

Bordwell and Liu, 1996
Bordwell, F.G.; Liu, W.-Z., Solvent Effects on Homolytic Bond Dissociation Energies of Hydroxylic Acids, J. Am. Chem. Soc., 1996, 118, 44, 10819-10823, https://doi.org/10.1021/ja961469q . [all data]


Notes

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