Azulene, 1,2,3,5,6,7,8,8a-octahydro-1,4-dimethyl-7-(1-methylethenyl)-, [1S-(1α,7α,8aβ)]-
- Formula: C15H24
- Molecular weight: 204.3511
- IUPAC Standard InChIKey: YHAJBLWYOIUHHM-IKCIUXDWSA-N
- CAS Registry Number: 3691-11-0
- Chemical structure:
This structure is also available as a 2d Mol file or as a computed 3d SD file
The 3d structure may be viewed using Java or Javascript. - Stereoisomers:
- Other names: (3S,3aS,5R)-3,8-Dimethyl-5-(prop-1-en-2-yl)-1,2,3,3a,4,5,6,7-octahydroazulene; Azulene, 1,2,3,5,6,7,8,8a-octahydro-1,4-dimethyl-7-(1-methylethenyl)-, (1S,7R,8aS)-; Guaia-1(10),11-diene; α-Bulnesene; δ-Guaiene; 5-Isopropenyl-3,8-dimethyl-1,2,3,3a,4,5,6,7-octahydroazulene-, [1S-(1α,7α,8aβ)]-; δ-Guaiene (α-bulnesene); δ-Guaiene (= α-bulnesene); δ-Guaijene
- Permanent link for this species. Use this link for bookmarking this species for future reference.
- Information on this page:
- Other data available:
- Options:
Normal alkane RI, non-polar column, temperature ramp
Go To: Top, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director
Column type | Capillary | Capillary | Capillary | Capillary | Capillary |
---|---|---|---|---|---|
Active phase | DB-5 MS | HP-5 MS | DB-5 MS | DB-1 | HP-5 |
Column length (m) | 60. | 30. | 30. | 30. | 25. |
Carrier gas | Helium | Helium | Helium | Helium | Helium |
Substrate | |||||
Column diameter (mm) | 0.25 | 0.25 | 0.25 | 0.25 | 0.20 |
Phase thickness (μm) | 0.25 | 0.25 | 0.25 | 0.25 | 0.33 |
Tstart (C) | 40. | 60. | 60. | 50. | 60. |
Tend (C) | 250. | 220. | 240. | 220. | 240. |
Heat rate (K/min) | 5. | 5. | 3. | 4. | 3. |
Initial hold (min) | 15. | 10. | 2. | ||
Final hold (min) | 15. | 2. | 7. | ||
I | 1509. | 1506. | 1502. | 1513. | 1508. |
Reference | Mesa-Arango, Betancur-Galvis, et al., 2010 | Ogunwande, Flamini, et al., 2010 | Silva, Pott, et al., 2010 | Xu, Tang, et al., 2010 | Maridass, 2009 |
Comment | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI |
Column type | Capillary | Capillary | Capillary | Capillary | Capillary |
---|---|---|---|---|---|
Active phase | HP-1 | HP-1 | HP-5 | HP-5 | CP-Sil 5 CB |
Column length (m) | 25. | 25. | 60. | 30. | 25. |
Carrier gas | He | He | Hydrogen | ||
Substrate | |||||
Column diameter (mm) | 0.32 | 0.32 | 0.25 | 0.25 | 0.25 |
Phase thickness (μm) | 0.17 | 0.17 | 0.25 | 0.25 | 0.15 |
Tstart (C) | 50. | 50. | 60. | 50. | 50. |
Tend (C) | 260. | 260. | 250. | 300. | 230. |
Heat rate (K/min) | 1. | 1. | 3. | 5. | 3. |
Initial hold (min) | 5. | 5. | 5. | ||
Final hold (min) | 5. | 5. | 5. | ||
I | 1504. | 1500. | 1515. | 1500. | 1509. |
Reference | Wetwiayaklung, Thavanapong, et al., 2009 | Wetwiayaklung, Thavanapong, et al., 2009 | Bertrand, Comte, et al., 2006 | Figuérédo, Cabassu, et al., 2006 | Olawore, Usman, et al., 2006 |
Comment | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI |
Column type | Capillary | Capillary | Capillary | Capillary | Capillary |
---|---|---|---|---|---|
Active phase | DB-5 | DB-1 | CP Sil 5 CB | DB-5 | HP-5MS |
Column length (m) | 30. | 50. | 25. | 30. | 30. |
Carrier gas | Hydrogen | N2 | He | He | |
Substrate | |||||
Column diameter (mm) | 0.25 | 0.25 | 0.25 | 0.32 | 0.25 |
Phase thickness (μm) | 0.25 | 0.25 | 0.25 | 0.25 | |
Tstart (C) | 70. | 95. | 50. | 60. | 60. |
Tend (C) | 280. | 240. | 230. | 280. | 280. |
Heat rate (K/min) | 4. | 4. | 3. | 3. | 3. |
Initial hold (min) | 4. | ||||
Final hold (min) | |||||
I | 1505. | 1498. | 1517. | 1470. | 1503. |
Reference | Pino, Marbot, et al., 2006 | Pala-Paul, Perez-Alonso, et al., 2005 | Tesso, König, et al., 2005 | Tzakou and Constantinidis, 2005 | Couladis, Özcan, et al., 2003 |
Comment | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI |
Column type | Capillary | Capillary | Capillary | Capillary | Capillary |
---|---|---|---|---|---|
Active phase | HP-1 | DB-5 | DB-5 | DB-5MS | DB-5MS |
Column length (m) | 50. | 30. | 30. | 30. | 30. |
Carrier gas | He | He | He | He | He |
Substrate | |||||
Column diameter (mm) | 0.2 | 0.25 | 0.25 | 0.25 | 0.25 |
Phase thickness (μm) | 0.5 | 0.25 | 0.25 | 0.25 | 0.25 |
Tstart (C) | 60. | 60. | 60. | 60. | 60. |
Tend (C) | 220. | 240. | 280. | 240. | 270. |
Heat rate (K/min) | 2. | 3. | 3. | 3. | 3. |
Initial hold (min) | |||||
Final hold (min) | 45. | 30. | |||
I | 1502. | 1504. | 1493. | 1507. | 1504. |
Reference | Fernandez, Lizzani-Cuvelier, et al., 2003 | Zoghbi, Andrade, et al., 2003 | Caredda, Marongiu, et al., 2002 | Maia, Zoghbi, et al., 2002 | Zoghbi, Andrade, et al., 2002 |
Comment | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI |
Column type | Capillary | Capillary | Capillary | Capillary | Capillary |
---|---|---|---|---|---|
Active phase | DB-1 | HP-5 | DB-5MS | SE-30 | CP Sil 5 CB |
Column length (m) | 30. | 30. | 30. | 25. | 25. |
Carrier gas | He | He | He | N2 | |
Substrate | |||||
Column diameter (mm) | 0.32 | 0.25 | 0.25 | 0.2 | 0.32 |
Phase thickness (μm) | 0.25 | 0.25 | 0.25 | 0.25 | |
Tstart (C) | 45. | 40. | 60. | 60. | 50. |
Tend (C) | 300. | 240. | 240. | 180. | 290. |
Heat rate (K/min) | 15. | 3. | 3. | 3. | 4. |
Initial hold (min) | 2. | 5. | 10. | ||
Final hold (min) | 5. | ||||
I | 1490. | 1515. | 1503. | 1455. | 1489. |
Reference | Hedin, McKibben, et al., 2000 | Novak, Novak, et al., 2000 | Zoghbi, Andrade, et al., 1999 | Jantan, Ahmad, et al., 1998 | Bos, Woerdenbag, et al., 1997 |
Comment | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI |
Column type | Capillary | Capillary | Capillary | Capillary | Capillary |
---|---|---|---|---|---|
Active phase | CP Sil 5 CB | CP Sil 5 CB | DB-5 | DB-5 | Methyl Silicone |
Column length (m) | 25. | 25. | 30. | 30. | 50. |
Carrier gas | N2 | He | He | He | N2 |
Substrate | |||||
Column diameter (mm) | 0.32 | 0.25 | 0.25 | 0.25 | 0.25 |
Phase thickness (μm) | 0.25 | 0.25 | 0.25 | 0.25 | 0.17 |
Tstart (C) | 50. | 60. | 65. | 65. | 80. |
Tend (C) | 290. | 300. | 300. | 300. | 200. |
Heat rate (K/min) | 4. | 6. | 4. | 4. | 2. |
Initial hold (min) | 2. | 2. | |||
Final hold (min) | |||||
I | 1489. | 1489. | 1489. | 1504. | 1502. |
Reference | Bos, Woerdenbag, et al., 1997 | Bos, Woerdenbag, et al., 1997, 2 | Elias, Simoneit, et al., 1997 | Elias, Simoneit, et al., 1997 | Gopalakrishnan, Menon, et al., 1993 |
Comment | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI |
Column type | Capillary | Capillary | Capillary | Capillary | Capillary |
---|---|---|---|---|---|
Active phase | Methyl Silicone | SE-54 | OV-101 | OV-101 | SE-30 |
Column length (m) | 50. | 30. | 50. | 50. | 30. |
Carrier gas | N2 | Hydrogen | N2 | N2 | |
Substrate | |||||
Column diameter (mm) | 0.25 | 0.25 | 0.25 | 0.25 | |
Phase thickness (μm) | 0.17 | 0.25 | |||
Tstart (C) | 80. | 60. | 80. | 80. | 50. |
Tend (C) | 200. | 250. | 200. | 200. | 240. |
Heat rate (K/min) | 3. | 2. | 2. | 2. | 4. |
Initial hold (min) | 5. | 2. | |||
Final hold (min) | 2. | 10. | |||
I | 1515. | 1498. | 1501. | 1503. | 1502. |
Reference | Gopalakrishnan, Menon, et al., 1993 | Kollmannsberger, Nitz, et al., 1992 | Sugisawa, Yang, et al., 1989 | Sugisawa, Yang, et al., 1989 | Ramaswami, Briscese, et al., 1988 |
Comment | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI |
Column type | Capillary |
---|---|
Active phase | SE-30 |
Column length (m) | 30. |
Carrier gas | |
Substrate | |
Column diameter (mm) | |
Phase thickness (μm) | |
Tstart (C) | 50. |
Tend (C) | 240. |
Heat rate (K/min) | 4. |
Initial hold (min) | 2. |
Final hold (min) | 10. |
I | 1502. |
Reference | Ramaswami, Briscese, et al., 1986 |
Comment | MSDC-RI |
References
Go To: Top, Normal alkane RI, non-polar column, temperature ramp, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Mesa-Arango, Betancur-Galvis, et al., 2010
Mesa-Arango, A.C.; Betancur-Galvis, L.; Montiel, J.; Bueno, J.G.; Baena, A.; Duran, D.C.; Martinez, J.R.; Stashenko, E.E.,
Antifungal activity and chemical composition of the essential oils of Lippia alba (Miller) N.E. Brown grown in different regions of Colombia,
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Aromatic plants growing in Nigeria: essential oil constituents of Cassia alata (Linn.) Roxb. and Helianthus annuus L.,
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Silva, Pott, et al., 2010
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Analyses of the headspace volatile constituents of aerial parts (leaves and stems), flowers and fruits of Bidens gardneri Bak. and Bidens sulphurea (Cav.) Sch. Bip. using solid-phase microextraction,
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Comparative analysis of plant essential oils by GC-MS coupled with integrated chemometric resolution methods,
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Solid-phase microextraction of volatile compounds from flowers of two Brunfelsia species,
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Studies of Mediterranean oregano populations. VIII. Chemical composition of essential oils of oreganos of various origins,
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Olawore, N.O.; Usman, L.A.; Ogunwande, I.A.; Adeleke, K.A.,
Constituents of rhizome essential oils of two types of Cyperus articulatus L. grown in Nigeria,
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Aromatic Plants from Western Cuba VII. Composition of the Leaf Oil of Psidium wrightii KRug et Urb., Lantana involucrata L., Cinnamonum montanum (Sw.) Berchtold et J. Persl. and Caesalpinia violacea (Mill.) Standley,
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Essential oil composition of the different parts of Eryngium bourgatii Gouan from Spain,
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Chemotaxonomic significance of volatile compounds in Thymus samius and its related species Thymus atticus and Thymus parnassicus,
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Couladis, Özcan, et al., 2003
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Comparative essential oil composition of various parts of the turpentine tree (Pistacia terebinthus L) growing wild in Turkey,
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Volatile constituents of benzoin gums: Siam and Sumatra. Part 1.,
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Zoghbi, Andrade, et al., 2003
Zoghbi, M.G.B.; Andrade, E.H.A.; da Silva, M.H.; Carreira, L.M.M.; Maia, J.G.S.,
Essential oils from three Myrcia species,
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Caredda, Marongiu, et al., 2002
Caredda, A.; Marongiu, B.; Porcedda, S.; Soro, C.,
Supercritical carbon dioxide extraction and characterization of Laurus nobilis essential oil,
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Maia, Zoghbi, et al., 2002
Maia, J.G.S.; Zoghbi, M.G.B.; Andrade, E.H.A.; da Silva, M.H.L.; Luz, A.I.R.; da Silva, J.D.,
Essential oils composition of Eupatorium species growing wild in the Amazon,
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Zoghbi, Andrade, et al., 2002
Zoghbi, M.G.B.; Andrade, E.H.A.; da Silva, M.H.L.; Maia, J.G.S.,
Volatile constituents of Lippia lupulina Cham.,
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Hedin, McKibben, et al., 2000
Hedin, P.A.; McKibben, G.H.; Dollar, D.A.,
Role of ground trash volatiles in the selection of hibernation sites by boll weevils,
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Novak, Novak, et al., 2000
Novak, J.; Novak, S.; Bitsch, C.; Franz, C.M.,
Essential oil composition of underground parts of Valeriana celtica ssp. from Austria and Italy,
Flavour Fragr. J., 2000, 15, 1, 40-42, https://doi.org/10.1002/(SICI)1099-1026(200001/02)15:1<40::AID-FFJ863>3.0.CO;2-B
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Zoghbi, Andrade, et al., 1999
Zoghbi, M.G.B.; Andrade, E.H.A.; Maia, J.G.S.,
Volatile constituents from leaves and flowers of Alpinia speciosa K. Schum. and A. purpurata (Viell.) Schum.,
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Jantan, Ahmad, et al., 1998
Jantan, I.; Ahmad, A.S.; Bakar, S.A.A.; Ahmad, A.R.; Trockenbrodt, M.; Chak, C.V.,
Constituents of the essential oil of Baeckea frutescens L. from Malaysia,
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Bos, Woerdenbag, et al., 1997
Bos, R.; Woerdenbag, H.J.; Hendriks, H.; Smit, H.F.; Wikström, H.V.; Scheffer, J.J.C.,
Composition of the essential oil from roots and rhizomes of Valeriana wallichii DC,
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Bos, Woerdenbag, et al., 1997, 2
Bos, R.; Woerdenbag, H.J.; Hendriks, H.; Scheffer, J.J.C.,
Composition of the essential oils from underground parts of Valeriana officinalis L. s.l. and several closely related taxa,
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Elias, Simoneit, et al., 1997
Elias, V.O.; Simoneit, B.R.T.; Cardoso, J.N.,
Analysis of volatile sesquiterpenoids in environmental and geological samples,
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Gopalakrishnan, Menon, et al., 1993
Gopalakrishnan, M.; Menon, N.; Padmakumari, K.P.; Jayalekshmy, A.; Narayanan, C.S.,
GC Analysis and Odor Profiles of Four New Indian Genotypes of Piper nigrum L.,
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Kollmannsberger, Nitz, et al., 1992
Kollmannsberger, H.; Nitz, S.; Drawert, F.,
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Sugisawa, H.; Yang, R.H.; Kawabata, C.; Tamura, H.,
Volatile constituents in the peel oil of sudachi (Citrus sudachi),
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Ramaswami, Briscese, et al., 1988
Ramaswami, S.K.; Briscese, P.; Gargiullo, R.J.; von Geldern, T.,
Sesquiterpene hydrocarbons: from mass confusion to orderly line-up
in Flavors and Fragrances: A World Perspective. Proceedings of the 10th International Congress of Essential Oils, Fragrances and Flavors, Lawrence,B.M.; Mookherjee,B.D.; Willis,B.J., ed(s)., Elsevier, New York, 1988, 951-980. [all data]
Ramaswami, Briscese, et al., 1986
Ramaswami, S.K.; Briscese, P.; Gargiullo, R.J.; von Geldern, T.,
Sesquiterpene hydrocarbons: from mass confusion to orderly line-up
in Flavors and Fragrances: A World Perspective, Lawrence,B.M.; Mookherjee,B.D.; Willis,B.J., ed(s)., Proceedings of the 10th International Congress of Essential Oils, Fragrances, and Flavors, Washington, DC, 1986, 951-959. [all data]
Notes
Go To: Top, Normal alkane RI, non-polar column, temperature ramp, References
- Symbols used in this document:
Tend Final temperature Tstart Initial temperature - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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