Trifluorophenylsilane


Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
AC - William E. Acree, Jr., James S. Chickos

Enthalpy of vaporization

ΔvapH (kJ/mol) Temperature (K) Reference Comment
40.1257.Stull, 1947Based on data from 242. to 371. K.; AC

Antoine Equation Parameters

log10(P) = A − (B / (T + C))
    P = vapor pressure (bar)
    T = temperature (K)

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Temperature (K) A B C Reference Comment
242. to 371.54.577951525.598-37.521Stull, 1947Coefficents calculated by NIST from author's data.

Ion clustering data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

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Clustering reactions

CH3O- + Trifluorophenylsilane = C7H8F3OSi-

By formula: CH3O- + C6H5F3Si = C7H8F3OSi-

Quantity Value Units Method Reference Comment
Δr320. ± 25.kJ/molCIDTKrouse, Lardin, et al., 2003gas phase

Fluorine anion + Trifluorophenylsilane = C6H5F4Si-

By formula: F- + C6H5F3Si = C6H5F4Si-

Quantity Value Units Method Reference Comment
Δr332. ± 14.kJ/molCIDTKrouse, Lardin, et al., 2003gas phase

Hydrogen anion + Trifluorophenylsilane = C6H6F3Si-

By formula: H- + C6H5F3Si = C6H6F3Si-

Quantity Value Units Method Reference Comment
Δr268. ± 13.kJ/molCIDTKrouse, Lardin, et al., 2003gas phase

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Stull, 1947
Stull, Daniel R., Vapor Pressure of Pure Substances. Organic and Inorganic Compounds, Ind. Eng. Chem., 1947, 39, 4, 517-540, https://doi.org/10.1021/ie50448a022 . [all data]

Krouse, Lardin, et al., 2003
Krouse, I.H.; Lardin, H.A.; Wenthold, P.G., Gas-phase ion chemistry and ion thermochemistry of phenyltrifluorosilane, Int. J. Mass Spectrom., 2003, 227, 3, 303-314, https://doi.org/10.1016/S1387-3806(03)00080-0 . [all data]


Notes

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