α-d-Galactopyranose


Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Quantity Value Units Method Reference Comment
Δfsolid-1286.3 ± 0.54kJ/molCcbClarke and Stegeman, 1939Reanalyzed by Cox and Pilcher, 1970, Original value = -1285.9 kJ/mol
Quantity Value Units Method Reference Comment
Δcsolid-2789.7 ± 0.42kJ/molCcbClarke and Stegeman, 1939Corresponding Δfsolid = -1286.3 kJ/mol (simple calculation by NIST; no Washburn corrections)

Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

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Individual Reactions

β-D-Glucopyranose, 4-O-β-D-galactopyranosyl- + Water = α-D-Glucopyranose + α-d-Galactopyranose

By formula: C12H22O11 + H2O = C6H12O6 + C6H12O6

Quantity Value Units Method Reference Comment
Δr0.44 ± 0.11kJ/molEqkGoldberg and Tewari, 1989liquid phase; solvent: Aqueous; HPLC

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Clarke and Stegeman, 1939
Clarke, T.H.; Stegeman, G., Heats of combustion of some mono- and disaccharides, J. Am. Chem. Soc., 1939, 61, 1726-1730. [all data]

Cox and Pilcher, 1970
Cox, J.D.; Pilcher, G., Thermochemistry of Organic and Organometallic Compounds, Academic Press, New York, 1970, 1-636. [all data]

Goldberg and Tewari, 1989
Goldberg, R.N.; Tewari, Y.B., A calorimetric and equilibrium investigatino of the hydrolysis of lactose, J. Biol. Chem., 1989, 264, 9897-9900. [all data]


Notes

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