CHFO2


Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

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Individual Reactions

CFO2- + Hydrogen cation = CHFO2

By formula: CFO2- + H+ = CHFO2

Quantity Value Units Method Reference Comment
Δr1380. ± 33.kJ/molD-EAArnold, Bradforth, et al., 1995gas phase
Δr1374.4kJ/molAcidLarson and McMahon, 1985gas phase
Quantity Value Units Method Reference Comment
Δr1350. ± 33.kJ/molH-TSArnold, Bradforth, et al., 1995gas phase

Gas phase ion energetics data

Go To: Top, Reaction thermochemistry data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

De-protonation reactions

CFO2- + Hydrogen cation = CHFO2

By formula: CFO2- + H+ = CHFO2

Quantity Value Units Method Reference Comment
Δr1380. ± 33.kJ/molD-EAArnold, Bradforth, et al., 1995gas phase
Δr1374.4kJ/molAcidLarson and McMahon, 1985gas phase
Quantity Value Units Method Reference Comment
Δr1350. ± 33.kJ/molH-TSArnold, Bradforth, et al., 1995gas phase

References

Go To: Top, Reaction thermochemistry data, Gas phase ion energetics data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Arnold, Bradforth, et al., 1995
Arnold, D.W.; Bradforth, S.E.; Kim, E.H.; Neumark, D.M., Study of halogen carbon dioxide clusters and the fluoroformyloxyl radical by photodetachment of X(-)(CO2) (X=I,Cl,Br) and FCO2-, J. Chem. Phys., 1995, 102, 9, 3493, https://doi.org/10.1063/1.468575 . [all data]

Larson and McMahon, 1985
Larson, J.W.; McMahon, T.B., Fluoride and chloride affinities of the main group oxides, fluorides, oxofluorides, and alkyls. Quantitative scales of lewis acidities from ICR halide exchange equilibria, J. Am. Chem. Soc., 1985, 107, 766. [all data]


Notes

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