Trifluoroacetyl fluoride

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Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
BS - Robert L. Brown and Stephen E. Stein
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny director
DH - Eugene S. Domalski and Elizabeth D. Hearing
AC - William E. Acree, Jr., James S. Chickos

Quantity Value Units Method Reference Comment
Tboil214.KN/APCR Inc., 1990BS
Tboil233.KN/AAnonymous, 1957Uncertainty assigned by TRC = 5. K; TRC
Quantity Value Units Method Reference Comment
Ttriple113.69KN/APace and Hodge, 1972Uncertainty assigned by TRC = 0.02 K; TRC
Ttriple113.69KN/AHodge, 1971Uncertainty assigned by TRC = 0.05 K; TRC

Enthalpy of vaporization

ΔvapH (kJ/mol) Temperature (K) Method Reference Comment
19.207214.10N/APace and Hodge, 1972, 2P = 101.325 kPa; DH
19.267214.10N/AHodge, 1971, 2DH
20.9200.AStephenson and Malanowski, 1987Based on data from 161. to 215. K. See also Pace and Hodge, 1972, 2.; AC

Entropy of vaporization

ΔvapS (J/mol*K) Temperature (K) Reference Comment
89.99214.10Pace and Hodge, 1972, 2P; DH
89.99214.10Hodge, 1971, 2DH

Antoine Equation Parameters

log10(P) = A − (B / (T + C))
    P = vapor pressure (bar)
    T = temperature (K)

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Temperature (K) A B C Reference Comment
161.94 to 214.274.21705765.587-32.284Pace and Hodge, 1972, 2Coefficents calculated by NIST from author's data.

Enthalpy of fusion

ΔfusH (kJ/mol) Temperature (K) Reference Comment
4.870113.69Pace and Hodge, 1972, 2DH
4.869113.69Hodge, 1971, 2DH

Entropy of fusion

ΔfusS (J/mol*K) Temperature (K) Reference Comment
42.84113.69Pace and Hodge, 1972, 2DH
42.83113.69Hodge, 1971, 2DH

In addition to the Thermodynamics Research Center (TRC) data available from this site, much more physical and chemical property data is available from the following TRC products:


References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

PCR Inc., 1990
PCR Inc., Research Chemicals Catalog 1990-1991, PCR Inc., Gainesville, FL, 1990, 1. [all data]

Anonymous, 1957
Anonymous, P., , 1957. [all data]

Pace and Hodge, 1972
Pace, E.L.; Hodge, P.E., Thermocynamic Properties of Trifluoroacetyl Fluoride from 14 K to its Boiling Temperature, J. Chem. Thermodyn., 1972, 4, 441-7. [all data]

Hodge, 1971
Hodge, P.E., The thermodynamic properties of trifluoroacetyl fluoride from 14 K to its boiling point and the thermodynamic properties of oxalyl fluoride from 130K to its normal boiling point. molecular data, Ph.D. Dissertation, Case Western Reserve University, Cleve- land, OH, 1971. [all data]

Pace and Hodge, 1972, 2
Pace, E.L.; Hodge, P.E., Thermodynamic properties of trifluoroacetyl fluoride from 14 K to its boiling temperature, J. Chem. Thermodynam., 1972, 4, 441-447. [all data]

Hodge, 1971, 2
Hodge, P.E., The thermodynamic properties of trifluoroacetyl fluoride from 14 K to its normal boiling point and the thermodynamic properties of oxalyl fluoride from 130K to its normal boiling point. The entropies from spectroscopic and molecular data, Diss. Abstr., 1971, 32, 1482-1483. [all data]

Stephenson and Malanowski, 1987
Stephenson, Richard M.; Malanowski, Stanislaw, Handbook of the Thermodynamics of Organic Compounds, 1987, https://doi.org/10.1007/978-94-009-3173-2 . [all data]


Notes

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