Ethane, pentafluoro-
- Formula: C2HF5
- Molecular weight: 120.0214
- IUPAC Standard InChIKey: GTLACDSXYULKMZ-UHFFFAOYSA-N
- CAS Registry Number: 354-33-6
- Chemical structure:
This structure is also available as a 2d Mol file or as a computed 3d SD file
The 3d structure may be viewed using Java or Javascript. - Other names: C2F5H; Pentafluoroethane; 1,1,1,2,2-Pentafluoroethane; Fc-125; Genetron HFC 125; R-125
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Phase change data
Go To: Top, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
BS - Robert L. Brown and Stephen E. Stein
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny director
AC - William E. Acree, Jr., James S. Chickos
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
Tboil | 227. ± 6. | K | AVG | N/A | Average of 11 values; Individual data points |
Quantity | Value | Units | Method | Reference | Comment |
Tfus | 170. | K | N/A | Young, Fukuhara, et al., 1940 | Uncertainty assigned by TRC = 3. K; TRC |
Quantity | Value | Units | Method | Reference | Comment |
Tc | 339.22 | K | N/A | Yata, Hori, et al., 1996 | Uncertainty assigned by TRC = 0.3 K; TRC |
Tc | 339.160 | K | N/A | Kuwabara, Aoyama, et al., 1995 | Uncertainty assigned by TRC = 0.04 K; TRC |
Tc | 339.17 | K | N/A | Higashi, 1994 | Uncertainty assigned by TRC = 0.03 K; TRC |
Tc | 339.4 | K | N/A | Wilson, Wilding, et al., 1992 | Uncertainty assigned by TRC = 0.7 K; TRC |
Quantity | Value | Units | Method | Reference | Comment |
Pc | 35.82 | atm | N/A | Tsvetkov, Kletskii, et al., 1995 | Uncertainty assigned by TRC = 0.06 atm; by extrapolation of obs. vapor pressure to selected Tc; TRC |
Pc | 35.726 | atm | N/A | Ye, Sato, et al., 1995 | Uncertainty assigned by TRC = 0.03 atm; calc. from vapor pressure equation fit to data at selected Tc(339.165 K); TRC |
Pc | 35.73 | atm | N/A | Higashi, 1994 | Uncertainty assigned by TRC = 0.07 atm; TRC |
Pc | 35.72 | atm | N/A | Sagawa, Sato, et al., 1994 | Uncertainty assigned by TRC = 0.05 atm; Calculated from vapor pressure curve for Tc = 339.165 K; TRC |
Pc | 34.73 | atm | N/A | Wilson, Wilding, et al., 1992 | Uncertainty assigned by TRC = 1.48 atm; by extrapoltion of vapor pressure equation to Tc; TRC |
Quantity | Value | Units | Method | Reference | Comment |
ρc | 4.73 | mol/l | N/A | Kuwabara, Aoyama, et al., 1995 | Uncertainty assigned by TRC = 0.02 mol/l; TRC |
ρc | 4.7658 | mol/l | N/A | Higashi, 1994 | Uncertainty assigned by TRC = 0.05 mol/l; TRC |
ρc | 4.757 | mol/l | N/A | Wilson, Wilding, et al., 1992 | Uncertainty assigned by TRC = 0.07 mol/l; TRC |
Enthalpy of vaporization
ΔvapH (kcal/mol) | Temperature (K) | Method | Reference | Comment |
---|---|---|---|---|
5.45 | 175. | C | Weber, 1999 | AC |
5.23 | 190. | C | Weber, 1999 | AC |
5.00 | 205. | C | Weber, 1999 | AC |
4.85 | 215. | C | Weber, 1999 | AC |
Enthalpy of fusion
ΔfusH (kcal/mol) | Temperature (K) | Reference | Comment |
---|---|---|---|
0.538 | 172.6 | L«65533»ddecke and Magee, 1996 | AC |
References
Go To: Top, Phase change data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Young, Fukuhara, et al., 1940
Young, D.W.S.; Fukuhara, N.; Bigelow, L.A.,
The Action of Elementary Fluorine Upon Organic Compounds VIII. The Influence of Dilution on the Vapor Phase Fluorination of Ethane,
J. Am. Chem. Soc., 1940, 62, 1171. [all data]
Yata, Hori, et al., 1996
Yata, J.; Hori, M.; Kawakatsu, H.; Minamiyama, T.,
Measurements of refractive index of alternative refrigerants,
Int. J. Thermophys., 1996, 17, 65-74. [all data]
Kuwabara, Aoyama, et al., 1995
Kuwabara, S.; Aoyama, H.; Sato, H.; Watanabe, K.,
Vapor-liquid coexistence curves in the critical region and the critical temperatures and densities of difluoromethane and pentafluoroehtane,
J. Chem. Eng. Data, 1995, 40, 112-116. [all data]
Higashi, 1994
Higashi, Y.,
Critical parameters for HFC134a, HFC32 and HFC125,
Int. J. Refrig., 1994, 17, 524-531. [all data]
Wilson, Wilding, et al., 1992
Wilson, L.C.; Wilding, W.V.; Wilson, G.M.; Rowley, R.L.; Felix, V.M.; Chisolm-Carter, T.,
Thermophysical properties of HFC-125,
Fluid Phase Equilib., 1992, 80, 167-77. [all data]
Tsvetkov, Kletskii, et al., 1995
Tsvetkov, O.B.; Kletskii, A.V.; Laptev, Yu.A.; Asambaev, A.J.; Zausaev, I.A.,
Thermal conductivity and PVT measurements of pentafluoroethane ( refrigerant HFC-125),
Int. J. Thermophys., 1995, 16, 1185-92. [all data]
Ye, Sato, et al., 1995
Ye, F.; Sato, H.; Watanabe, K.,
Gas-phase PVT properties and vapor pressure of pentafluoroethane (HFC-125) determined according to the burnett method,
J. Chem. Eng. Data, 1995, 40, 148-152. [all data]
Sagawa, Sato, et al., 1994
Sagawa, T.; Sato, H.; Watanabe, K.,
Thermodynamic properties of HFC-125 based on (p,V,T) measurements,
High Temp. - High Pressures, 1994, 26, 193-201. [all data]
Weber, 1999
Weber, F.,
Measurement of the specific enthalpy of vaporization of the alternative refrigerant pentafluoroethane in the temperature range from 175 K to 220 K,
PTB-Mitteilungen, 1999, 109, 6, 469. [all data]
L«65533»ddecke and Magee, 1996
L«65533»ddecke, T.O.; Magee, J.W.,
Molar heat capacity at constant volume of difluoromethane (R32) and pentafluoroethane (R125) from the triple-point temperature to 345 K at pressures to 35 MPa,
Int J Thermophys, 1996, 17, 4, 823-849, https://doi.org/10.1007/BF01439192
. [all data]
Notes
Go To: Top, Phase change data, References
- Symbols used in this document:
Pc Critical pressure Tboil Boiling point Tc Critical temperature Tfus Fusion (melting) point ΔfusH Enthalpy of fusion ΔvapH Enthalpy of vaporization ρc Critical density - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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