Ethane, pentafluoro-

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Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

De-protonation reactions

C2F5- + Hydrogen cation = Ethane, pentafluoro-

By formula: C2F5- + H+ = C2HF5

Quantity Value Units Method Reference Comment
Δr1567. ± 14.kJ/molG+TSSullivan and Beauchamp, 1976gas phase; Between tBuOH and HF; value altered from reference due to change in acidity scale
Quantity Value Units Method Reference Comment
Δr1535. ± 13.kJ/molIMRBSullivan and Beauchamp, 1976gas phase; Between tBuOH and HF; value altered from reference due to change in acidity scale

Mass spectrum (electron ionization)

Go To: Top, Gas phase ion energetics data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Spectrum

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Owner NIST Mass Spectrometry Data Center
Collection (C) 2014 copyright by the U.S. Secretary of Commerce
on behalf of the United States of America. All rights reserved.
Origin T.J. Bruno, Cent. Chem. Technol., NIST, Boulder, CO 80303, USA
NIST MS number 142366

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References

Go To: Top, Gas phase ion energetics data, Mass spectrum (electron ionization), Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Sullivan and Beauchamp, 1976
Sullivan, S.A.; Beauchamp, J.L., Competition between proton transfer and elimination in the reactions of strong bases with fluoroethanes in the gas phase. Influence of base strength on reactivity, J. Am. Chem. Soc., 1976, 98, 1160. [all data]


Notes

Go To: Top, Gas phase ion energetics data, Mass spectrum (electron ionization), References