Stannane, ethyltrimethyl-
- Formula: C5H14Sn
- Molecular weight: 192.875
- IUPAC Standard InChIKey: VDYIOWXZMNKCHN-UHFFFAOYSA-N
- CAS Registry Number: 3531-44-0
- Chemical structure:
This structure is also available as a 2d Mol file or as a computed 3d SD file
The 3d structure may be viewed using Java or Javascript. - Other names: Ethyltrimethyltin; Ethyltrimethylstannane; Trimethylethyltin; (CH3)3SnC2H5
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Gas phase thermochemistry data
Go To: Top, Phase change data, Mass spectrum (electron ionization), Gas Chromatography, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: José A. Martinho Simões
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔfH°gas | -26.3 ± 2.9 | kJ/mol | Review | Martinho Simões | Selected data |
ΔfH°gas | -182. ± 21. | kJ/mol | Review | Martinho Simões |
Phase change data
Go To: Top, Gas phase thermochemistry data, Mass spectrum (electron ionization), Gas Chromatography, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
MS - José A. Martinho Simões
AC - William E. Acree, Jr., James S. Chickos
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔvapH° | 37.7 ± 1.7 | kJ/mol | CC-SB | Bullard and Haussmann, 1930 | MS |
Enthalpy of vaporization
ΔvapH (kJ/mol) | Temperature (K) | Method | Reference | Comment |
---|---|---|---|---|
38.4 | 258. | N/A | Stull, 1947 | Based on data from 243. to 381. K.; AC |
37.0 | 304. | I | Bullard and Haussmann, 1929 | Based on data from 273. to 336. K.; AC |
34.9 | 360. | I | Bullard and Haussmann, 1929 | Based on data from 336. to 384. K.; AC |
Antoine Equation Parameters
log10(P) = A − (B / (T + C))
P = vapor pressure (bar)
T = temperature (K)
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Temperature (K) | A | B | C | Reference | Comment |
---|---|---|---|---|---|
243. to 382.0 | 4.39229 | 1532.512 | -32.327 | Stull, 1947 | Coefficents calculated by NIST from author's data. |
Mass spectrum (electron ionization)
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director
Spectrum
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Additional Data
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Due to licensing restrictions, this spectrum cannot be downloaded.
Owner | NIST Mass Spectrometry Data Center Collection (C) 2014 copyright by the U.S. Secretary of Commerce on behalf of the United States of America. All rights reserved. |
---|---|
Origin | Chemical Concepts |
NIST MS number | 152514 |
Gas Chromatography
Go To: Top, Gas phase thermochemistry data, Phase change data, Mass spectrum (electron ionization), References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director
Kovats' RI, non-polar column, isothermal
Column type | Active phase | Temperature (C) | I | Reference | Comment |
---|---|---|---|---|---|
Packed | Apiezon L | 190. | 728. | Putnam and Pu, 1965 | Celite; Column length: 1. m |
Van Den Dool and Kratz RI, non-polar column, temperature ramp
Column type | Active phase | I | Reference | Comment |
---|---|---|---|---|
Packed | Apiezon L | 714. | Putnam and Pu, 1965, 2 | Celite, 10. K/min; Column length: 3. m; Tstart: 60. C |
Packed | Apiezon L | 713. | Putnam and Pu, 1965, 2 | Celite, 15. K/min; Column length: 3. m; Tstart: 60. C |
Packed | Apiezon L | 713. | Putnam and Pu, 1965, 2 | Celite, 6. K/min; Column length: 3. m; Tstart: 60. C |
References
Go To: Top, Gas phase thermochemistry data, Phase change data, Mass spectrum (electron ionization), Gas Chromatography, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Martinho Simões
Martinho Simões, J.A.,
Private communication (see http://webbook.nist.gov/chemistry/om/). [all data]
Bullard and Haussmann, 1930
Bullard, R.H.; Haussmann, A.C.,
J. Phys. Chem., 1930, 34, 743. [all data]
Stull, 1947
Stull, Daniel R.,
Vapor Pressure of Pure Substances. Organic and Inorganic Compounds,
Ind. Eng. Chem., 1947, 39, 4, 517-540, https://doi.org/10.1021/ie50448a022
. [all data]
Bullard and Haussmann, 1929
Bullard, R.H.; Haussmann, A.C.,
The Vapor Pressure of Some Stannanes,
J. Phys. Chem., 1929, 34, 4, 743-747, https://doi.org/10.1021/j150310a006
. [all data]
Putnam and Pu, 1965
Putnam, R.C.; Pu, H.,
Retention indices of organotins,
J. Gas Chromatogr., 1965, 3, 5, 160-164, https://doi.org/10.1093/chromsci/3.5.160
. [all data]
Putnam and Pu, 1965, 2
Putnam, R.C.; Pu, H.,
Retention indices of organotins (II),
J. Gas Chromatogr., 1965, 3, 9, 289-293, https://doi.org/10.1093/chromsci/3.9.289
. [all data]
Notes
Go To: Top, Gas phase thermochemistry data, Phase change data, Mass spectrum (electron ionization), Gas Chromatography, References
- Symbols used in this document:
ΔfH°gas Enthalpy of formation of gas at standard conditions ΔvapH Enthalpy of vaporization ΔvapH° Enthalpy of vaporization at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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