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Benzene, (fluoromethyl)-

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Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
BS - R.L. Brown and S.E. Stein
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, M. Frenkel director
AC - W.E. Acree, Jr., J.S. Chickos
ALS - H.Y. Afeefy, J.F. Liebman, and S.E. Stein

Quantity Value Units Method Reference Comment
Tboil412.KN/APCR Inc., 1990BS
Tboil413.KN/AAmerican Tokyo Kasei, 1988BS
Quantity Value Units Method Reference Comment
Tfus210.7KN/AMeva'a and Lichanot, 1990Uncertainty assigned by TRC = 0.3 K; TRC
Quantity Value Units Method Reference Comment
Deltavap46.2 ± 0.3kJ/molGSKrasnykh, Vasiltsova, et al., 2002Based on data from 278. - 318. K.; AC
Deltavap46.5kJ/molCGCKrasnykh, Vasiltsova, et al., 2002AC
Deltavap46.32 ± 0.26kJ/molVSchaffer, Verevkin, et al., 1997ALS
Deltavap46.3 ± 0.3kJ/molGSSchaffer, Verevkin, et al., 1997Based on data from 278. - 318. K.; AC
Deltavap44.5 ± 0.4kJ/molN/AAshcroft, 1976AC

Reduced pressure boiling point

Tboil (K) Pressure (bar) Reference Comment
413.01.00Weast and Grasselli, 1989BS
313.20.019Weast and Grasselli, 1989BS

Enthalpy of vaporization

DeltavapH (kJ/mol) Temperature (K) Method Reference Comment
43.7312.AStephenson and Malanowski, 1987Based on data from 297. - 410. K.; AC
44.3312.IAshcroft, 1976Based on data from 298. - 356. K.; AC

In addition to the Thermodynamics Research Center (TRC) data available from this site, much more physical and chemical property data is available from the following TRC products:


References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

PCR Inc., 1990
PCR Inc., Research Chemicals Catalog 1990-1991, PCR Inc., Gainesville, FL, 1990, 1. [all data]

American Tokyo Kasei, 1988
American Tokyo Kasei, TCI American Organic Chemical 88/89 Catalog, American Tokyo Kasei, Portland, OR, 1988, 1610. [all data]

Meva'a and Lichanot, 1990
Meva'a, L.M.; Lichanot, A., Thermodynamic properties in condensed phase of ortho, meta and para fluorotoluene, cresol and toluidine, Thermochim. Acta, 1990, 158, 335. [all data]

Krasnykh, Vasiltsova, et al., 2002
Krasnykh, Eugen L.; Vasiltsova, Tatiana V.; Verevkin, Sergey P.; Heintz, Andreas, Vapor Pressures and Enthalpies of Vaporization of Benzyl Halides and Benzyl Ethers, J. Chem. Eng. Data, 2002, 47, 6, 1372-1378, https://doi.org/10.1021/je020034h . [all data]

Schaffer, Verevkin, et al., 1997
Schaffer, F.; Verevkin, S.P.; Rieger, H.J.; Beckhaus, H.D.; Ruchardt, C., Enthalpies of formation of a series of fluorinated hydrocarbons and strain-free group increments to assess polar and anomeric stabilization and strain, Liebigs Ann., 1997, 1333-1344. [all data]

Ashcroft, 1976
Ashcroft, Stanley J., Vapor pressures and enthalpies of vaporization of benzyl halides, J. Chem. Eng. Data, 1976, 21, 4, 397-398, https://doi.org/10.1021/je60071a009 . [all data]

Weast and Grasselli, 1989
CRC Handbook of Data on Organic Compounds, 2nd Editon, Weast,R.C and Grasselli, J.G., ed(s)., CRC Press, Inc., Boca Raton, FL, 1989, 1. [all data]

Stephenson and Malanowski, 1987
Stephenson, Richard M.; Malanowski, Stanislaw, Handbook of the Thermodynamics of Organic Compounds, 1987, https://doi.org/10.1007/978-94-009-3173-2 . [all data]


Notes

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